Process and device for treating and recycling chromium-containing waste liquor

A waste liquid and process technology, applied in the field of chromium-containing waste liquid disposal and recovery process and its disposal and recovery device, can solve the problems of large investment, high operation and management cost, heavy pollution control burden of enterprises, etc., and achieve obvious economic and social benefits and save money. Equipment and operating costs to achieve the effect of cleaner production

Inactive Publication Date: 2012-08-01
武汉巍川环保科技有限责任公司
View PDF3 Cites 3 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For some small and medium-sized electroplating and tanning enterprises, due to their small scale, the amount of chromium-containing waste liquid produced is relatively small. Therefore, the construction of sewage treatment equipment requires relatively large investment, high operation and management costs, and the pollution control burden of enterprises is relatively large. Heavy

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Process and device for treating and recycling chromium-containing waste liquor
  • Process and device for treating and recycling chromium-containing waste liquor
  • Process and device for treating and recycling chromium-containing waste liquor

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Such as figure 1 As shown, the chromium-containing waste liquid disposal and recycling process includes the following steps:

[0042] 1) Using trialkyl tertiary amine (N235) as the extractant and kerosene as the solvent, prepare a N235-kerosene solution containing 30wt% of the extractant in the extractant recovery storage tank 5 for use;

[0043] 2) Prepare concentrated sulfuric acid or waste sulfuric acid with a concentration of 10% by weight or more in the acid mixing tank 9 to prepare dilute sulfuric acid with a sulfuric acid content of 10% by weight; then pump to the high-level acid storage tank 8 for standby;

[0044] 3) Put the industrial sodium hydroxide or potassium hydroxide in the alkali distributing tank 11 and add water to dissolve it to prepare a sodium hydroxide solution or potassium hydroxide solution with a concentration of 10wt%; then pump to the high-position alkali storage tank 10 for standby;

[0045] 4) Connect the chromium-containing waste liquid storage ta...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Bronsted acidityaaaaaaaaaa
Login to view more

Abstract

The invention discloses a process for treating and recycling chromium-containing waste liquor and belongs to the technical field of treatment of industrial sewage. The process comprises the following steps of: diluting organic amine (trialkyl tertiary amine) in a solvent, wherein the diluted organic amine is used as an extracting agent, adjusting the acidity of the pre-treated chromium-containing waste liquor to be appropriate, and performing counter-current extraction on a multi-stage mixing-clarification box type extraction tank; extracting chromium (VI) into an organic phase (an O phase), and after the content of chromium (VI) in raffinate (a water phase and an A phase) reaches the national wastewater discharge standard, namely the content of the chromium (VI) in raffinate is 0.2mg / L (which meets GB21900-2008 discharge limit requirement), discharging; and adjusting the phase ratio of the A phase to the O phase to ensure that the flow of the A phase is greater than that of the O phase so as to enrich the chromium (VI) in the organic phase in the extraction process, wherein the enrichment magnification can reach more than ten times. By the process, the chromium-containing waste liquor is treated and recycled. The environment-friendly problem that pollutant which does not reach the standard is discharged is solved for small and medium electroplating and tanning enterprises, equipment for treating waste liquid is eliminated, the running cost of the equipment is saved, and production cost is reduced, and clean production is realized.

Description

Technical field [0001] The invention belongs to the technical field of industrial sewage treatment, and specifically relates to a process for the disposal and recovery of waste liquid containing chromium (VI) and a disposal and recovery device thereof. Background technique [0002] Chromium (VI) is needed in industries such as cold-rolled sheet passivation, chemical electroplating, and leather tanning, which will produce a large amount of chromium (VI) waste liquid. Chromium (VI) is one of the highly toxic elements. Direct discharge can cause serious pollution to the environment. Human contact or ingestion can cause serious damage such as skin ulcers, respiratory inflammation, anemia, neuritis, etc. It is also one of the known carcinogens . [0003] At present, the harmless treatment of waste liquid containing chromium (VI) is mainly chemical reduction, sedimentation and then storage and landfill. If the treated waste slag containing chromium (III) is discharged or landfilled, in...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/04C02F101/22
Inventor 宋乐山张译吴明周勇
Owner 武汉巍川环保科技有限责任公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products