Back contact layer structure, preparation method thereof and CdTe thin-film solar cell comprising back contact layer structure

A solar cell, back contact technology, applied in coatings, circuits, photovoltaic power generation, etc., to achieve effective cost control, improve intensification, and avoid environmental pollution

Inactive Publication Date: 2012-11-14
UNIV OF SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to solve the problems existing in the application of existing CdTe thin film solar cells, the present invention has been formed

Method used

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  • Back contact layer structure, preparation method thereof and CdTe thin-film solar cell comprising back contact layer structure
  • Back contact layer structure, preparation method thereof and CdTe thin-film solar cell comprising back contact layer structure
  • Back contact layer structure, preparation method thereof and CdTe thin-film solar cell comprising back contact layer structure

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Experimental program
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Embodiment 1

[0045] A single growth chamber magnetron sputtering system is used to manufacture the back contact layer structure of the present invention. The advantages of using a single growth chamber magnetron sputtering system are simple equipment and diversified equipment functions. With the help of the single growth chamber magnetron sputtering system, the manufacturing process of the back contact layer structure is as follows:

[0046] First, perform the pretreatment of the surface of the CdTe film: open the gate of the growth chamber of the magnetron sputtering system, and the CdCl 2 The heat-treated CdTe film (supported on a glass substrate) sample is placed in the growth chamber of the magnetron sputtering system through a transfer rod, and the sample baffle is opened. The magnetron sputtering system has forward and reverse sputtering functions. A negative potential (1-3kV) is applied to the system substrate disk. The reverse sputtering function of the magnetron sputtering system is ...

Embodiment 2

[0051] A dual growth chamber magnetron sputtering system is used to manufacture the back contact layer structure of the present invention.

[0052] figure 2 It shows the structure diagram of the dual growth chamber DC magnetron sputtering system used for manufacturing the back contact layer structure according to the present invention. The dual DC magnetron sputtering growth chamber system includes: a magnetron sputtering first growth chamber 1, a first transition chamber 2, a magnetron sputtering second growth chamber 3, a second transition chamber 4, and a first growth chamber for sampling The gate 5, the first growth chamber sampling gate 6, the second growth chamber sampling gate 7, the second growth chamber sampling gate 8, the second transition chamber sampling gate 9 and the transfer rod 10. The advantage of using such a dual-growth-chamber DC magnetron sputtering system is that it can perform assembly line operation and improve production efficiency, and compared with Ex...

Embodiment 3

[0058] A dual growth chamber magnetron sputtering system is used to manufacture the back contact layer of the present invention. Compared with Example 2, the difference is that MoO 3 Target used as sputtering source to make MoO 3 Film (MoO 3 Buffer layer), therefore, only the formation of MoO is described below 3 The process of buffer layer, and omit the description of other same steps.

[0059] After the surface pretreatment of the CdTe thin film sample is optionally completed, the negative potential applied to the system substrate disk is removed, and the negative potential is applied to the MoO used for magnetron sputtering. 3 (5N purity) MoO is formed on the target by radio frequency sputtering 3 film. The atmosphere of magnetron sputtering is pure argon. The flow and pressure of argon are controlled and adjusted by the mass flowmeter of the magnetron sputtering system. The pressure is controlled at 0.45Pa, for an area of ​​100cm 2 For samples, the bombardment power is usually...

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Abstract

The invention relates to a novel CdTe thin-film solar cell, in particular to a novel back contact layer structure used for the CdTe thin-film solar cell. The novel back contact layer structure comprises a MoO3 back contact buffer layer and a metal back electrode layer which are sequentially arranged on the CdTe thin film. The invention also relates to a method for manufacturing the back contact layer structure film and a CdTe thin-film solar cell device by utilizing the back contact layer structure. The CdTe thin-film solar cell device which is high-efficiency, low in cost and high in long-term operating stability can be provided.

Description

Technical field [0001] The present invention relates generally to solar photovoltaic devices and semiconductor devices, and more specifically to cadmium telluride (CdTe) thin film solar cells. Background technique [0002] Cadmium telluride (CdTe) is a II-VI group compound P-type semiconductor. As a promising thin-film solar cell material, it has received widespread attention. This is mainly due to the following characteristics of CdTe: First, its band gap is about 1.45eV, the response to the solar spectrum is in the most ideal solar spectrum band. Single-junction thin-film solar cells with CdTe as the absorption layer can obtain higher photoelectric conversion efficiency, and their theoretical photoelectric conversion efficiency is as high as 30%. The highest photoelectric conversion efficiency reaches 16.5%; secondly, the absorption coefficient of CdTe in the visible light range is as high as 10 5 em -1 In sunlight, about 99% of the photons with energy higher than the band gap ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L31/0224H01L31/073C23C14/06C23C14/35
CPCY02E10/50Y02E10/543Y02P70/50
Inventor 王德亮白治中
Owner UNIV OF SCI & TECH OF CHINA
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