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Method for synthesizing magnesium phosphate biological bone cement through self-covering controlled hydration reaction

A technology of hydration reaction and magnesium phosphate, which is used in the preparation of bio-cementing materials and the synthesis of magnesium phosphate biological bone cement by self-coating and controlled hydration reaction, can solve the problem of short curing time and high exothermic temperature of magnesium phosphate biological bone cement. , low clinical performance and other problems, to achieve the effect of excellent biocompatibility, simple and convenient process, and maintaining biocompatibility

Active Publication Date: 2012-12-05
长沙市大川防火材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The object of the present invention is to provide a method for synthesizing magnesium phosphate bio-bone cement by self-coating controlled hydration reaction, which solves the problem of low clinical performance caused by short curing time and high exothermic temperature in the preparation of magnesium phosphate bio-bone cement

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Step 1, self-coating treatment of magnesium oxide

[0027] First, commercially available medical grade MgO and KH 2 PO 4 Ball mill to powders with particle sizes of 6-10μm and 10-20μm respectively. A star-type ball mill was used for ball milling, the milling time was 3h and 4h respectively, the grinding balls were agate balls, the ball-to-material ratio was 1:1, and the speed of the ball mill was 400r / min.

[0028] Then, the ball-milled MgO and the ball-milled KH 2 PO 4 Mix the powder uniformly at a mass ratio of 5:1 to obtain mixture A; add 1ml of distilled water per gram to mixture A while stirring to obtain mixture B, and continue stirring until mixture B solidifies after adding.

[0029] Finally, the mixture B was placed in an environment with a temperature of 37°C and a relative humidity of 100% for 48 hours, and then crushed to a particle size of 15-25 μm using a ball mill, which was the self-coated MgO powder.

[0030] Step 2, reaction-controlled synthesis o...

Embodiment 2

[0033] Step 1, self-coating treatment of magnesium oxide

[0034] First for MgO and KH 2 PO 4 The powder is ball milled, and the specific ball milling conditions are the same as those in Example 1. Then the ball-milled MgO powder and the ball-milled KH 2 PO 4 The powder is mixed uniformly at a mass ratio of 10:1 to obtain a mixture A; and while stirring, add a dilute phosphoric acid solution with a volume concentration of 10% in an amount of 2ml per gram to the mixture A to obtain a mixture B, and continue stirring until Mixture B solidifies. Finally, the mixture B was placed in an environment with a temperature of 37°C and a relative humidity of 100% for 48 hours, and then crushed to a particle size of 15-25 μm using a ball mill, which was the self-coated MgO powder.

[0035] Step 2, reaction-controlled synthesis of magnesium phosphate biocement

[0036] The self-coated MgO powder obtained in step 1 and the KH after ball milling 2 PO 4 Mix the powder uniformly at a ma...

Embodiment 3

[0038] Step 1, self-coating treatment of magnesium oxide

[0039] First for MgO and KH 2 PO 4 The powder is ball milled, and the specific ball milling conditions are the same as those in Example 1. Then the ball-milled MgO powder and the ball-milled KH 2 PO 4Mix the powder uniformly at a mass ratio of 12:1 to obtain mixture A; add glucose solution with a mass concentration of 0.9% to mixture A at an amount of 1.5ml per gram while stirring to obtain mixture B, and continue stirring after the addition until mixture B solidifies. Finally, the mixture B was placed in an environment with a temperature of 37°C and a relative humidity of 100% for 48 hours, and then crushed to a particle size of 15-25 μm using a ball mill, which was the self-coated MgO powder.

[0040] Step 2, reaction-controlled synthesis of magnesium phosphate biocement

[0041] The self-coated MgO powder obtained in step 1 and the KH after ball milling 2 Mix PO4 powder uniformly at a mass ratio of 2:1 to obt...

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PUM

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Abstract

The invention discloses a method for synthesizing magnesium phosphate biological bone cement through self-covering controlled hydration reaction. The method comprises the following steps of: firstly mixing MgO with KH2PO4, preparing bone cement consisting of a great quantity of residual MgO and hydration reaction products MgKPO4.6H2O, and pulverizing the bone cement into powder to obtain self-covered MgO; then mixing the self-covered MgO with the KH2PO4, controlling hydration reaction by virtue of the blocking effect of an MgKPO4.6H2O self-covering layer to synthesize the magnesium phosphate biological bone cement. The method for synthesizing magnesium phosphate biological bone cement through self-covering controlled hydration reaction has the advantages that the hardening time can be prolonged to 6-17min after covering from 0.7-4min before covering, and the heat emitting temperature peak value is decreased to 32.6-38.3DEG C from 55.1-70.5DEG C; at the same time, the substance of the covering layer is one component of the bone cement, other substances are not introduced and the clinical use performance is obviously enhanced; and besides, the method does not rely on large equipment, the process is simple and convenient and the cost is saved.

Description

technical field [0001] The invention belongs to the technical field of material preparation, and relates to a preparation method of a biological gelling material, in particular to a method for synthesizing magnesium phosphate bio-bone cement by self-coating and controlling hydration reaction. Background technique [0002] Magnesium phosphate biocement (MPC) is a new type of biogelling material prepared by mixing magnesium oxide, phosphate and solid-phase blending solution. MPC is characterized by fast coagulation speed and high early strength; volume expansion occurs slightly during curing, and can form a high-strength interface with bone tissue; at the same time, the hydration product has good biocompatibility and has no toxic side effects. Therefore, MPC is widely used in the treatment of unstable fractures and adhesive fixation of artificial joint prosthesis. [0003] As a bone repair material, the curing time and reaction exotherm controlled by the hydration reaction ra...

Claims

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Application Information

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IPC IPC(8): C04B12/02A61L24/02
Inventor 李均明刘林涛王爱娟张姣
Owner 长沙市大川防火材料有限公司