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310results about How to "Inhibition of hydration" patented technology

A low-cost precision casting method for titanium alloy and titanium-aluminum alloy

The invention relates to a method for precisely casting a titanium alloy and a titanium aluminum alloy with low cost, which relates to a method for precisely casting the titanium alloy and the titanium aluminum alloy, and solves the technical problem that cast pieces have low surface quality and internal quality in the conventional method for lowering the cost of precisely casting the titanium alloy and the titanium aluminum alloy by using electrically-fused alumina and silica sol. The method comprises the following steps of: preparing a surface layer binder from zirconium sol, silica sol, a wetting agent JFC, n-octyl alcohol, polyvinyl alcohol and latex; adding calcium carbonate, alumina, titanium dioxide and zirconia to prepare a surface layer coating; preparing a shell surface layer; preparing a shell back layer by a universal method for precisely casting the titanium alloy; dewaxing and sintering to obtain a shell; and casting the titanium alloy or the titanium aluminum alloy by using the shell so as to obtain a titanium alloy cast piece or a titanium aluminum alloy cast piece. Compared with a precise casting method by purely using a zirconium-based binder and a zirconia fireproof material, the method has the advantage that raw material cost is lowered by 30 to 70 percent and the method can be used for civil titanium alloy cast pieces and titanium aluminum alloy cast pieces for common aviation.
Owner:HARBIN SHITAI NEW MATERIAL TECH & DEV

Colloidal electrolyte of lead acid batteries

The invention discloses a lead-acid accumulator colloid electrolyte. The lead-acid accumulator colloid electrolyte comprises the following compositions in percentage by mass: 30 to 45 percent of sulphuric acid, 4 to 12 percent of nanometer silicon dioxide, 0.05 to 0.5 percent of macromolecular stabilizing agent, 0.1 to 0.5 percent of superfine glass fibre, 0.1 to 0.5 percent of boric acid, 0.1 to 1 percent of phosphoric acid, 0.3 to 2.5 percent of sodium sulfate and 50 to 57 percent of water. The electrolyte is added with the macromolecular stabilizing agent and the hydrophilic superfine glass fibre and sets up a strong network structure with the sulphuric acid and water molecules; the macromolecular stabilizing agent effectively prevents the delamination of various compositions and the hydration of the colloid electrolyte; the superfine glass fibre in the colloid electrolyte forms a reinforcing rib of the colloid electrolyte, effectively prevents the colloid electrolyte from seriously crazing, strengthens the tensile strength and vibration resistance performance of the colloid and has the strong liquid absorption capacity which improves the diffusing and transmitting speed of the electrolyte. The lead-acid accumulator colloid electrolyte improves the charging and receiving capacity, thereby increasing the cycle life of an accumulator.
Owner:CHAOWEI POWER CO LTD

Slow-release polycarboxylate superplasticizer and preparation method thereof

The invention discloses a slow-release polycarboxylate superplasticizer and a preparation method thereof. The preparation method comprises specific steps as follows: firstly, small unsaturated carboxylic acid monomers and diphenylphosphinyl chloride are subjected to a partial reaction, and small unsaturated monomers containing phosphate ester groups are obtained; then 2-phenylethylamine and phosphate ester groups are added to a reaction system and subjected to a reaction, and small unsaturated monomers containing amide groups are obtained; the small unsaturated monomers containing the amide groups are subjected to an oxidation-reduction free radical polymerization reaction with unsaturated polyether macromonomers under the action of an initiating agent, a reducing agent and a chain transfer agent, and a copolymerization product is obtained; pH value is adjusted to 6-7 after the reaction, water is added, and the polycarboxylate superplasticizer is obtained. The amide groups containing benzene rings are introduced to side chains of the prepared polycarboxylate superplasticizer, so that the dispersibility of the polycarboxylate superplasticizer for cement is improved, the polycarboxylate superplasticizer has good slump retaining performance on the premise of water reduction, and besides, the yield of the polycarboxylate superplasticizer containing the amide groups can reach 94% or higher.
Owner:JIANGSU CHINA RAILWAY ARIT NEW MATEIRALS CO LTD

Calcium oxide-based ceramic mold manufacturing method based on 3D (Three Dimensional) printing technology

The invention a calcium oxide-based ceramic mold manufacturing method based on a 3D (Three Dimensional) printing technology. The method comprises the following steps: after carrying out organic treatment on calcium oxide ceramic powder subjected to grain size gradation, adding a proper amount of an sintering auxiliary agent and enhanced short fibers and uniformly mixing to prepare calcium oxide-based ceramic powder for 3D printing; carrying out the 3D printing by utilizing a photo-cured adhesive and the calcium oxide-based ceramic powder subjected to the organic treatment, so as to form a calcium oxide-based ceramic mold green body; carrying out degreasing, reactive melt infiltration and high-temperature intensified sintering on the calcium oxide-based ceramic mold to finally obtain a high-strength calcium oxide-based ceramic mold; carrying out surface hydration-proof treatment on the prepared ceramic mold. By adopting the method, the hydration resistance of the calcium oxide-based ceramic mold is improved; the calcium oxide-based ceramic mold prepared by the method has a good high-temperature comprehensive performance and can meet casting requirements of an alloy with higher temperature and (B2) metal with active high-temprature chemical properties, and a mold core is easy to remove.
Owner:XI AN JIAOTONG UNIV

Non-water-based gel injection molding rapid-manufactured calcium oxide-based ceramic casting mold and preparation method thereof

The invention discloses a non-water based gel injection molding rapid-manufactured calcium oxide-based ceramic casting mold and a preparation method thereof, and belongs to the technical field of rapid precision casting. The method is characterized in that a mold required for 3D printing technology rapid manufacture is used, and simultaneously a non-water-based gel injection molding technology isapplied, so that the problem of hydration of calcium oxide powder during a casting mold preparation process is effectively solved, and the method can be successfully applied to the preparation of a mold core / mold shell integrated calcium oxide-based ceramic casting mold with complex internal structural parts and components. The manufactured calcium oxide-based ceramic casting mold has good overallperformance, and can meet the casting requirements of ultrahigh-temperature alloys such as a new generation of niobium-silicon-based high-temperature alloy and active light alloys such as titanium-aluminium alloy and magnesium-aluminium alloy, and the core removal performance is extremely excellent, so that the technical problems of difficult removal and high rejection rate of silicon oxide-basedand aluminium oxide-based mold cores are solved, therefore, the non-water based gel injection molding rapid-manufactured calcium oxide-based ceramic casting mold is a huge improvement on an existinginvestment mold precision casting and molding technology, and has broad market prospect and market value.
Owner:XI AN JIAOTONG UNIV

Injection molding method for nano aluminum nitride ceramics

The invention discloses an injection molding method for nano aluminum nitride ceramics and belongs to the field of powder metallurgy. The injection molding method comprises the following steps of batching according to nano aluminum nitride powder and a sintering additive, wherein the addition amount of the sintering additive is 2 to 8 weight percent; adding 5 weight percent of coating agent to be mixed with absolute ethanol to obtain slurry; performing spray drying and granulating to obtain a nano aluminum nitride powder granulation material; placing the granulation material and a binding agent according to the mixture ratio of 50g to 9g-50g to 12g on a roller type mixer for mixing; performing injection molding on the mixture to obtain a green aluminum nitride body; degreasing and sintering the green aluminum nitride body to obtain the aluminum nitride ceramics. According to the injection molding method disclosed by the invention, the nano aluminum nitride powder is granulated in advance, so that the flowability, the apparent density and the tap density of the powder are improved; meanwhile, a coating layer is formed on the surface of the powder, so that the phenomenon that the oxygen content is increased as the powder generates a hydration reaction is prevented; the granulation material and the binding agent are mixed to obtain a feedstock for injection molding of the nano aluminum nitride; the nano aluminum nitride is subjected to injection molding, degreasing and sintering techniques to obtain the aluminum nitride ceramics; the aluminum nitride ceramics have the characteristics of good conformality, low sintering temperature, high strength and the like.
Owner:UNIV OF SCI & TECH BEIJING
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