Hydrotreating method for maximum production of middle distillates
A middle distillate, the largest amount of technology, used in hydrotreating process, petroleum industry, treatment of hydrocarbon oil, etc., can solve the problems of low reaction temperature, high activity of molecular sieve hydrocracking catalyst, and low yield of middle distillate oil. , to achieve the effect of improving yield, protecting activity and selectivity, and improving selectivity
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Embodiment 1
[0038] When the reaction pressure is 14.5MPa, the reaction temperature in the hydrofinishing section is 380°C, the reaction temperature in the hydrocracking section is 375°C, and the volume space velocity (for fresh raw materials) in the hydrofinishing section is 1.8h -1 , the volumetric space velocity of the hydrocracking section (for all feeds in the hydrocracking section) is 1.3h -1 Under the reaction conditions, with the hydrocracking method that the present invention provides, adopt raw material A to carry out test. The volume ratio between RN-32V and RHC-140 loaded in the hydrofinishing reactor is 3:1; the volume ratio between the catalyst RHC-140 and RHC-131 loaded in the hydrocracking reactor is 1:3. The ratio of fresh raw oil entering the hydrofinishing reactor and the hydrocracking reactor is 6:1, and all tail oil fractions are recycled back to the hydrocracking reactor. H in the reaction atmosphere of the hydrocracking reactor 2 S partial pressure is 0.021MPa, NH ...
Embodiment 2
[0040] When the reaction pressure is 14.5MPa, the reaction temperature in the hydrofinishing section is 375°C, the reaction temperature in the hydrocracking section is 380°C, and the volume space velocity (for fresh raw materials) in the hydrofinishing section is 1.8h -1 , the volumetric space velocity of the hydrocracking section (for all feeds in the hydrocracking section) is 1.3h -1 Under the reaction conditions, with the hydrocracking method that the present invention provides, adopt raw material A to carry out test, the ratio of RN-32V and RHC-140 catalyst of hydrorefining reactor filling is 2:1; Hydrocracking reactor filling The volume ratio between catalyst RHC-140 and RHC-131 is 1:1. The ratio of fresh raw oil entering the hydrofinishing reactor and the hydrocracking reactor is 2:1, and all tail oil fractions are recycled back to the hydrocracking reactor. H in the reaction atmosphere of the hydrocracking reactor 2 S partial pressure is 0.074MPa, NH 3 The partial pr...
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