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Hydrotreating method for maximum production of middle distillates

A middle distillate, the largest amount of technology, used in hydrotreating process, petroleum industry, treatment of hydrocarbon oil, etc., can solve the problems of low reaction temperature, high activity of molecular sieve hydrocracking catalyst, and low yield of middle distillate oil. , to achieve the effect of improving yield, protecting activity and selectivity, and improving selectivity

Active Publication Date: 2015-04-29
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Compared with amorphous hydrocracking catalysts, molecular sieve hydrocracking catalysts have high activity and low initial reaction temperature, but the yield of middle distillates is relatively low

Method used

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  • Hydrotreating method for maximum production of middle distillates

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] When the reaction pressure is 14.5MPa, the reaction temperature in the hydrofinishing section is 380°C, the reaction temperature in the hydrocracking section is 375°C, and the volume space velocity (for fresh raw materials) in the hydrofinishing section is 1.8h -1 , the volumetric space velocity of the hydrocracking section (for all feeds in the hydrocracking section) is 1.3h -1 Under the reaction conditions, with the hydrocracking method that the present invention provides, adopt raw material A to carry out test. The volume ratio between RN-32V and RHC-140 loaded in the hydrofinishing reactor is 3:1; the volume ratio between the catalyst RHC-140 and RHC-131 loaded in the hydrocracking reactor is 1:3. The ratio of fresh raw oil entering the hydrofinishing reactor and the hydrocracking reactor is 6:1, and all tail oil fractions are recycled back to the hydrocracking reactor. H in the reaction atmosphere of the hydrocracking reactor 2 S partial pressure is 0.021MPa, NH ...

Embodiment 2

[0040] When the reaction pressure is 14.5MPa, the reaction temperature in the hydrofinishing section is 375°C, the reaction temperature in the hydrocracking section is 380°C, and the volume space velocity (for fresh raw materials) in the hydrofinishing section is 1.8h -1 , the volumetric space velocity of the hydrocracking section (for all feeds in the hydrocracking section) is 1.3h -1 Under the reaction conditions, with the hydrocracking method that the present invention provides, adopt raw material A to carry out test, the ratio of RN-32V and RHC-140 catalyst of hydrorefining reactor filling is 2:1; Hydrocracking reactor filling The volume ratio between catalyst RHC-140 and RHC-131 is 1:1. The ratio of fresh raw oil entering the hydrofinishing reactor and the hydrocracking reactor is 2:1, and all tail oil fractions are recycled back to the hydrocracking reactor. H in the reaction atmosphere of the hydrocracking reactor 2 S partial pressure is 0.074MPa, NH 3 The partial pr...

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Abstract

The invention relates to a hydrotreating method for maximum production of middle distillates. The method comprises the following steps that: fresh feedstock oils are simultaneously introduced into a hydrofining reactor and a hydrocracking reactor in a co-current flow way; the hydrofining reactor is sequentially filled with a hydrofining catalyst and an amorphous hydrocracking catalyst; the hydrocracking reactor is sequentially filled with an amorphous hydrocracking catalyst and a zeolite hydrocracking catalyst; and all or part of the tail oil fractions are introduced into the hydrocracking reactor, and a reaction effluent from the hydrocracking reactor and part of the feedstock oils are introduced into the hydrofining reactor together. According to the method provided by the invention, the heavy distillates can be treated, and the maximum production of the middle distillates can be realized. Only the tail oil fractions are introduced into the hydrocracking reactor, so that the selectivity of middle distillates is improved; and part of the feedstock oils is introduced into the hydrocracking reactor, so that the phenomenon that more middle distillates are cracked secondarily in an ammonia-free environment in the hydrocracking reactor is avoided, and thus the yield of the middle distillates is effectively improved.

Description

technical field [0001] The invention belongs to a hydrocracking method for obtaining low-boiling distillate hydrocarbon oil in the presence of hydrogen. Background technique [0002] With the deterioration of crude oil quality year by year and the increasingly stringent environmental protection requirements worldwide, the hydrocracking process, as one of the main means of crude oil secondary processing and heavy oil lightening, has strong raw material applicability, flexible production plan, liquid With high product yield and good product quality, it is playing an increasingly important role in the deep processing of sulfur-containing and high-sulfur crude oil to produce clean fuels, and its application range is becoming more and more extensive. [0003] In recent years, the market demand for various oil products, especially high-quality middle distillate products, has continued to grow, and the pressure on refineries to produce high-quality middle distillate products has al...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G67/00
Inventor 董建伟胡志海陈元君董松涛赵阳王子文龙湘云聂红
Owner CHINA PETROLEUM & CHEM CORP
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