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Purifying method for bifenthrin

A technology of bifenthrin and a purification method is applied in chemical instruments and methods, preparation of carboxylic acid esters, preparation of organic compounds, etc., can solve problems such as poor operating environment and large loss of organic solvents, and achieves low cost and product purity. High, improve the effect of the working environment

Active Publication Date: 2012-12-19
安徽新北卡化学有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Bifenthrin will produce dust during drying and granulation, the operating environment is poor, and the loss of organic solvents is large

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Add 500 kg of 96.5% bifenthrin crude oil, 1500 kg of water, and 250 kg of cyclohexane into the stirring tank, raise the temperature to 60°C while stirring, and cool down to 40°C after half an hour, and then cool down at 1000°C Cut for 1 hour at rpm. When the temperature dropped to 5°C, the shearing was stopped, the material was filtered out, and dried under floor heating to obtain 476.3 kg of bifenthrin with a content of 98.3%, and the specific gravity was between 0.65 and 0.75. The oil phase is separated and recycled separately.

Embodiment 2

[0023] Example 2 Take 500 kilograms of 91.42% bifenthrin crude oil, filter and stratify in Example 1, then add activated carbon to absorb and remove impurities to make up 1500 kilograms, add 250 kilograms of cyclohexane into the stirring tank and stir to raise the temperature to 70 ° C, half Cool down to 40°C in 1 hour, then cut at 1000 rpm for 1 hour while cooling down, stop shearing when the temperature drops to 5°C, filter and discharge, and dry under floor heating to obtain 450 kg of biphenyl with a content of 98.1% Pyrethrin crystal, the specific gravity is between 0.65 and 0.75.

[0024] Purification method of the present invention and existing purification method purification result comparison are shown in Table 1

[0025] Table 1

[0026] Product purity Whether there is dust in the environment current technology 96.2% Large dust, pollute the environment The method of the invention More than 98% No dust, good working environment

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PUM

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Abstract

The invention discloses a purifying method for bifenthrin. The method comprises the following steps of: putting bifenthrin crude oil, an organic solvent and water under a heating condition in a stirring kettle according to a certain proportion; fully dissolving the bifenthrin crude oil; cooling; and performing high-speed shearing, cooling, filtering, drying and purifying to obtain a high-purity bifenthrin particular crystal. In a purifying process, purification and pelletizing are integrated; and the purifying method has the characteristics of practicable process, low production cost, environment friendliness, sanitation and the like.

Description

technical field [0001] The invention relates to the field of fine chemicals, in particular to a method for purifying the agricultural insecticide bifenthrin. Background technique [0002] Bifenthrin is a pyrethroid agricultural insecticide. At present, the purification and granulation of bifenthrin crude oil are carried out separately, and the organic solvents used in the purification are mainly alcohols, and the water content is strictly required. Bifenthrin will generate dust during drying and granulation, the operating environment is poor, and the loss of organic solvent is large. However, the present invention avoids the above-mentioned disadvantages. Contents of the invention [0003] The invention discloses a purification method of bifenthrin. The purification method has the characteristics of saving auxiliary materials, low purification cost and no environmental pollution. [0004] The technical scheme that the present invention adopts for realizing the above ob...

Claims

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Application Information

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IPC IPC(8): C07C69/743C07C67/52
Inventor 陈前虎
Owner 安徽新北卡化学有限公司