Desiliconization process in zinc hydrometallurgy
A technology of hydro-method zinc smelting and desiliconization, which is applied in the direction of improving process efficiency, etc., can solve the problems that can not completely solve silica gel, hinder filtration, and the effect of desiliconization is not very obvious, so as to improve metal recovery rate, improve adaptability, good filtering speed
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[0030] The present invention realizes desiliconization through the control of specific parameters on the basis of the original process steps of "neutral leaching → acid leaching → pre-neutralization → sinking alum and iron removal" in hydrometallurgy, and the control process is as follows:
[0031] (1) pH control
[0032] Middle leaching pH control
[0033] In the neutral leaching step, the pH value of the leaching pulp is alternately controlled between 1.5~2.0 and 3.5~4.0 in the middle leaching chute. Specifically, after the pH value is controlled at 1.5~2.0 and reacted for 20~40 minutes, the pH value is immediately increased React to 3.5~4.0 for 20~40 minutes, then import the pulp in the leaching tank into the leaching tank for reaction, add the pulp to the leaching chute and adjust the pH value in the leaching chute to 1.5~2.0, and operate in a cycle. This alternate operation not only avoids the precipitation of silica gel in the pH range of 2.0-2.5, but also easily ensu...
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