420 results about "Leaching (metallurgy)" patented technology

The invention discloses a deep learning and automatic control chemical reactor and a resource recovery method, and relates to the technical field of hydrometallurgy, and the deep learning and automatic control chemical reactor comprises a chemical reactor, a motor, a heating device, a monitoring device, a data center and a PLC control system. Based on a PLC control system, a Transform-LSTM time sequence prediction model is integrated, so that real-time monitoring of parameters such as mixed liquid temperature, reaction chamber pressure, mixed liquid viscosity, conductivity and the like in a wet leaching reaction process can be realized; and the heating power of the heating device, the rotating speed of the motor, the raw material adding amount of the feeding port, the mixed material discharging time of the discharging port and the air displacement of the air exhaust port can be automatically and accurately controlled. The problems that stirring efficiency is low, parameter regulation and control are lagged, and manual experience is relied on are solved, through a predictive control strategy, the real-time monitoring and dynamic regulation level is remarkably improved, the wet leaching process is optimized, energy consumption is reduced, the high-grade metal leaching efficiency is improved, and the method is suitable for various wet metallurgy processes.

The invention provides a method for recycling scandium, iron and aluminum from acid leachate through fractional precipitation, and belongs to the field of hydrometallurgy. The method comprises the following steps: adding a reducing agent into an acid leaching solution to obtain a first modified leaching solution; adding a stable complexing agent into the first modified leaching solution to obtain a second modified leaching solution; adding a pH regulator into the second modified leaching solution, and regulating the pH value of the second modified leaching solution to 3.5-4.5 to obtain a coarse scandium product and a scandium precipitation solution; an oxidizing agent is dropwise added into the scandium precipitation solution, and an iron product and an iron precipitation solution are obtained; and adding a pH regulator into the iron precipitation liquid to regulate the pH value of the iron precipitation liquid to be greater than or equal to 6.0, and carrying out ultrasonic enhanced aluminum ion precipitation to obtain an aluminum product and an aluminum precipitation liquid. Selective modification of metal ions is achieved by adding a reducing agent and a complexing agent, scandium is precipitated through pH regulation and control, iron is precipitated through oxidation regulation and control, and finally complexation and precipitation of aluminum are blocked, so that the separation efficiency of scandium, iron and aluminum in the acid leaching solution is improved at the same time.

The invention relates to the technical field of hydrometallurgy, in particular to a method for selectively leaching and separating cobalt and manganese from crude cobalt hydroxide leaching residues. The separation method provided by the invention comprises the following steps: S1, pre-reduction treatment; and S3, cobalt is leached through selective oxidation, and manganese is precipitated. According to the separation method, the synergistic effect of ORP and pH is regulated and controlled, proper reducing agents and oxidizing agents are selected, cobalt is selectively leached through step-by-step oxidation, dissolution of manganese is inhibited, manganese circularly entering a leaching and extraction system is reduced, the leaching and extraction operation cost is reduced, meanwhile, a selective complexing agent is introduced, impurity co-dissolution is reduced, the subsequent purification process is simplified, and the method is suitable for industrial production. The preparation method is simple to operate and easy for industrial production, and has a good application prospect.

The invention discloses an MHP short-process nickel-cobalt-manganese purification liquid preparation technology, and belongs to the technical field of hydrometallurgy. Comprising the following steps: drying a cobalt nickel hydroxide raw material; carrying out size mixing, reduction leaching and separation to obtain a primarily purified nickel-cobalt-manganese solution and manganese-containing slag; carrying out acidification leaching on the manganese-containing slag, and separating to obtain manganese-silicon slag and a nickel-containing pickling solution; adding a neutralizing agent into the primarily purified nickel-cobalt-manganese solution to adjust the pH value, adding an oxidizing agent, and separating to obtain filtrate and filter residues; concentrated sulfuric acid is added into the filter residues for curing and leaching, and cured leaching residues and desiliconized filtrate are obtained through separation; cured leaching residues are returned for reduction leaching; adding a second neutralizer into the desiliconized filtrate to adjust the pH value, reacting, and separating to obtain iron-aluminum slag and nickel-containing impurity-removed filtrate; adding a third neutralizer into the nickel-containing impurity-removed filtrate to adjust the pH and precipitate nickel, and separating to obtain a nickel-containing alkaline substance; and removing impurities in the filtrate to obtain the nickel-cobalt-manganese purified liquid. According to the method, the nickel-cobalt-manganese purified liquid, the scandium-containing iron-aluminum slag, the by-product manganese-silicon slag and the like can be obtained, solid waste reduction and high value are achieved, and the method is more economical, more efficient and more environmentally friendly.

The invention relates to a method for preparing sponge iron from laterite-nickel ore hydrometallurgy tailings, which comprises the following steps: (1) carrying out acid leaching on laterite-nickel ore hydrometallurgy tailings to obtain leached residues without at least part of CaSO4; (2) oxidizing and roasting the leaching residues obtained in the step (1), so that at least part of sulfate is discharged as sulfur-containing gas; performing hydrogen reduction to obtain a reduced material; and (3) the reduction material in the step (2) is sequentially subjected to ore grinding and magnetic separation, and the sponge iron with the Fe content being 90 wt% or above and the S content being 0.01 wt% or below is obtained. According to the method, iron resources in the laterite-nickel ore hydrometallurgy tailings are recycled, desulfurization and reduction are carried out step by step, the desulfurization efficiency is improved, the reduction temperature is reduced, and the sponge iron with the Fe content being 90 wt% or above and the S content being 0.01 wt% or below is obtained.

The invention discloses a method for cascade recovery of tellurium from a complex tellurium-containing material. The method comprises the steps of acid pickling, reduction neutralization, pyrogenic transformation, leaching and neutralization. According to the method, through cooperative treatment of a wet process and a pyrogenic process, the problem of slag phase wrapping is effectively solved, and tellurium with different valence states in a complex tellurium-containing material is converted into high-quality tellurium neutralization slag in a gradient mode. The selenium removal rate is not lower than 95%, the tellurium recovery rate reaches up to 90% or above, efficient separation of selenium and tellurium is achieved, and the produced tellurium dioxide neutralization slag can be used for further purification and refining.

The invention belongs to the technical field of hydrometallurgy, and particularly relates to a pretreatment method for improving the leaching rate and the carbon adsorption rate of high-sulfur-arsenic gold ore. Comprising the following steps that the high-sulfur-arsenic gold ore is ground and then prepared into ore pulp; a green oxygen activating agent and hydrogen peroxide are sequentially added into the ore pulp, oxidation pretreatment is conducted on the high-sulfur-arsenic gold ore, ore pulp activating liquid is formed, and the green oxygen activating agent is a mixture of calcium oxide, sodium persulfate and soluble bivalent iron salt; and adding a gold leaching agent into the ore pulp activation solution, adjusting the pH value of the ore pulp to 9-12, carrying out stirring gold leaching treatment, filtering to obtain a leaching solution, and then adding activated carbon to adsorb and extract gold. According to the method, a stronger oxidation environment is provided, meanwhile, the residual concentration of arsenate radicals in the solution is effectively reduced, the leaching rate of gold and the adsorption rate of activated carbon are greatly increased, excellent oxidation performance and environment friendliness are shown, and a more sustainable high-sulfur-arsenic gold ore pretreatment process is provided.

The invention relates to a method for recycling battery-grade nickel sulfate from nickel-containing industrial waste, and belongs to the technical field of nonferrous metallurgy. The method comprises the steps that the nickel-containing industrial waste is subjected to water leaching treatment, and nickel-containing leachate is obtained; carrying out gradient pH regulation and control on the nickel-containing leaching solution by adopting calcium carbonate to obtain a purified solution; carrying out first countercurrent extraction on the purified liquid by adopting an organic phase I with the D2EHPA concentration of 0.1-0.3 mol / L; carrying out second counter-current extraction on the raffinate I obtained in the step (3) by adopting an organic phase II with the CYANEX 272 concentration of 0.05-0.2 mol / L; the raffinate II obtained in the step (4) is subjected to adsorption and oil removal through activated carbon and then is subjected to evaporative crystallization, and nickel sulfate crystals and crystallization mother liquor are obtained. The method is high in nickel recovery rate, the purity of nickel sulfate is larger than or equal to 99.9%, and the sodium content is low.

The invention belongs to the field of metallurgy, and particularly relates to a method for comprehensively recovering iron, vanadium, titanium, scandium and gallium through cooperation of vanadium titano-magnetite and red mud, which comprises the following steps: a) mixing vanadium titano-magnetite concentrate powder and red mud powder, roasting, leaching in water, and carrying out solid-liquid separation to obtain leached residues and leached liquid; b) mixing the leachate with a precipitant to precipitate vanadium, and carrying out solid-liquid separation to obtain vanadium-rich slag and vanadium-precipitated clear liquid; dissolving the vanadium-rich slag in a sulfuric acid solution, mixing the vanadium-rich slag with ammonium salt to react, carrying out solid-liquid separation, and roasting the obtained solid product ammonium polyvanadate to obtain V2O5; resin is used for adsorbing and desorbing gallium ions in the vanadium precipitation clear liquid, the pH of desorption liquid is adjusted to be alkaline, then electrolysis is conducted, and crude gallium is obtained; c) washing and drying the leaching residues to prepare pellets; after the pellets are pre-reduced, a carbonaceous reducing agent is mixed, melt separation treatment is carried out, and scandium-containing high-titanium slag and molten iron are obtained; and Ti and Sc in the scandium-containing high titanium slag are recycled. The method has the advantages of simple process, cleanness, high efficiency and the like.

The invention discloses a method for recovering Mo and Fe from direct coal liquefaction oil residues, and belongs to the technical field of hydrometallurgy. The method comprises the steps of solvent extraction, roasting enrichment, wet leaching, extracting agent extraction, ammonia water reverse extraction and evaporative crystallization, and ammonium molybdate and Fe (OH) 3 are obtained. Wherein in the wet leaching process, a leaching aid and sulfuric acid are jointly used for leaching, so that Ca and Si in the oil residues are left in leaching residues, and Mo, Fe, Al and the like enter a solution. The method comprises the following steps: simultaneously extracting Mo and Fe from a solution by using an extracting agent, precipitating Fe in a Fe (OH) 3 state by using an ammonia water reverse extraction method, leaving Mo in a reverse extraction solution in the form of ammonium molybdate, and further evaporating and crystallizing the reverse extraction solution to obtain the ammonium molybdate. According to the method, two valuable metals Mo and Fe in the direct coal liquefaction oil residue can be effectively recovered, and resource recycling is facilitated.

The invention relates to a method for recovering lithium and fluorine from aluminum electrolysis hazardous waste, which comprises the following steps: firstly, mixing organic polyol and alkaline hydroxide according to a molar ratio of 1: (0.5-2) to obtain a eutectic solvent; heating the eutectic solvent to 80-150 DEG C, and adding a proper amount of raw material fine powder and calcium oxide for reaction leaching; carbonating and filtering the leachate to obtain lithium carbonate; washing the leaching residues with an acetic acid solution to obtain a calcium fluoride product; the concentration of fluorine ions in the leachate is smaller than or equal to 200 ppm, and the purity of calcium fluoride is larger than or equal to 90%; the leaching rate of lithium in the method is greater than 85%; the slag feeding rate of fluorine is greater than 95%; and no hydrogen fluoride gas is generated in the method. According to the method, a non-toxic and biodegradable eutectic solvent is adopted as a leaching agent, and efficient leaching of lithium and fluorine in the aluminum electrolysis dangerous waste materials is achieved; calcium oxide is used as a precipitating agent, free fluorine is promoted to be precipitated and recycled as calcium fluoride, the whole process meets the requirement of green metallurgy, and the win-win situation of resources and the environment is achieved.

The invention provides a comprehensive utilization method of clay type lithium ore, and relates to the field of hydrometallurgy. The comprehensive utilization method of the clay type lithium ore comprises the following steps: mixing the clay type lithium ore with concentrated sulfuric acid, and carrying out low-temperature roasting at the temperature of 100-300 DEG C to obtain a roasted cured material; adding water into the roasted and cured material, leaching, and carrying out solid-liquid separation to obtain a lithium-rich aluminum leaching solution; adsorbing the lithium-rich aluminum leaching solution by using an aluminum ion sieve adsorbent to obtain an aluminum-rich adsorbed solution and a lithium-loaded ion sieve; analyzing the lithium-loaded ion sieve to obtain a lithium-rich desorption solution; the lithium-rich desorption solution is sequentially subjected to purification and lithium precipitation, and battery-grade lithium carbonate is obtained; sequentially carrying out iron removal, purification and impurity removal on the aluminum-rich adsorption post-liquid to obtain iron slag and an aluminum sulfate solution; and sequentially carrying out aluminum precipitation and roasting on the aluminum sulfate solution to obtain the metallurgical-grade aluminum oxide. The method has the advantages of high-efficiency leaching of lithium and aluminum, high-efficiency separation of lithium and aluminum, environment friendliness, simple process and the like.

The invention provides a flotation pretreatment reagent system and a method for treating gold-bearing waste soot and recycling gold through the flotation pretreatment reagent system, and belongs to the technical field of hydrometallurgy. According to the invention, a multi-agent synergistic agent system is designed, a gold recovery system of'catalytic oxidation-bridging anchoring-hydrophobic flotation 'is constructed, and strategy transformation from passive inhibition of carbon adsorption to active separation of a carbon carrier is successfully realized. Compared with a traditional method which only tries to passivate the adsorption activity of carbon, the method has the advantages that gold-robbing carbon interfering with gold recovery is converted into a flotation carrier easy to separate through accurate reagent matching, and the problem that carbonaceous interferes with cyaniding gold extraction is fundamentally solved. The modified carbon agglomerates are subjected to efficient flotation separation due to the excellent hydrophobic characteristic, and the gold is enriched in the tailings due to the fact that the gold is not hydrophobized. According to the method, the gold recovery rate of follow-up cyanidation leaching is remarkably increased, the agent consumption is greatly reduced, and the important technical value of achieving technological process innovation through molecular-level collaborative design is shown.

The invention belongs to the technical field of pyrometallurgy and hydrometallurgy, and discloses an efficient leaching method for Joule thermal shock strengthened vanadium titano-magnetite. The Joule thermal shock strengthened vanadium-titanium resource efficient leaching comprises the steps that low-grade vanadium-titanium magnetite ore powder and a carbon source are mixed and then subjected to Joule thermal shock activation treatment, and an obtained activation product is leached through dilute acid or organic acid, so that valuable metal such as vanadium, titanium and iron can be efficiently leached out. Vanadium titano-magnetite and a small amount of carbon powder are subjected to Joule thermal shock, so that the valence state of metal ions is reduced, and the leaching activity of metal is improved. The Joule thermal shock strengthening low-grade vanadium titano-magnetite acid leaching method has the advantages of being high in activation efficiency, high in metal element leaching efficiency and the like.

The invention relates to a method for recovering tellurium from copper anode slime through cooperation of ultrasound and hydrogen peroxide, and belongs to the field of wet metallurgy of scattered metal. The method comprises the following steps: drying and grinding copper anode slime to obtain copper anode slime powder; the method comprises the following steps: adding copper anode slime powder into a sulfuric acid solution, mixing to obtain copper anode slime slurry, adding hydrogen peroxide into the copper anode slime slurry, carrying out ultrasonic enhanced leaching for 20-160min, and carrying out solid-liquid separation to obtain a leaching solution containing copper and tellurium and high-grade valuable metal leaching residues. According to the method, hydrogen peroxide is effectively promoted to be decomposed by ultrasound to generate hydroxyl radicals, the oxidation potential of a system is regulated and controlled, copper and tellurium are selectively converted into copper ions, tellurate radicals enter a solution, and valuable elements such as gold, silver and selenium are enriched in slag; necessary heat is provided for the reaction by utilizing the heat effect of ultrasonic and heat released by chemical reaction, and extra heating is not needed; strong jet flow generated by ultrasound effectively destroys raw material inclusion and secondary wrapping, reaction mass transfer is enhanced, and the leaching rate of tellurium is increased. The method disclosed by the invention is simple in leaching process operation, low in cost and high in reaction speed.

The invention provides a laterite-nickel ore leaching solution catalytic oxidation-fractional precipitation method, and relates to the field of hydrometallurgy, the method comprises the following steps: adding a catalytic oxidant and a first neutralizer into a laterite-nickel ore leaching solution to obtain a first filtrate and iron slag; adding a catalytic oxidant, a second neutralizer and a first coalescing agent into the first filtrate to obtain a second filtrate and a second precipitate; adding a third neutralizer and a first reducing agent into the second filtrate to obtain a nickel-cobalt precipitate and a third filtrate; adding a fourth neutralizer and a second reducing agent into the third filtrate to obtain a fourth precipitate and a fourth filtrate; mixing the second precipitate with a third reducing agent, performing reduction leaching, and adding a second coalescing agent and a fifth neutralizing agent to obtain a silicon-aluminum precipitate and manganese-scandium filtrate; the manganese-scandium filtrate is extracted, and manganese enters raffinate; and adding a catalytic oxidant and a sixth neutralizer into the raffinate to obtain the manganese oxide. Elements are recycled step by step, and the method has the advantages of multiple types of recycled elements, less resource waste and the like.

The invention discloses a method for recovering lithium in lithium clay, and belongs to the technical field of non-ferrous metallurgy. The method comprises the following steps: carrying out mechanical activation pretreatment on lithium clay to obtain mineral powder; the mineral powder is subjected to acid leaching and solid-liquid separation, and leaching residues and lithium-containing leaching liquid are obtained; performing sectional aluminum removal on the lithium-containing leachate to obtain aluminum-removed liquid; and removing iron and magnesium in the molten aluminum, and then adding a precipitant to carry out lithium precipitation reaction to obtain lithium carbonate. According to the method, the lithium leaching efficiency is improved by creatively utilizing ion replacement and mineral lattice destruction, deep removal of aluminum impurities is achieved by combining ammonium / potassium alum directional crystallization, the comprehensive lithium recovery rate exceeds 78% (the comprehensive lithium recovery rate can exceed 85% in a part of schemes), meanwhile, ammonium alum and potassium alum with the purity higher than 95% are produced as byproducts, and the method is suitable for industrial production. And an efficient, low-consumption and environment-friendly solution is provided for industrial development of carbonate type lithium clay ore.

The invention belongs to the technical field of metallurgy, and discloses a hydrogen reduction dissolution method for bauxite. Comprising the following steps: mixing bauxite and circulating mother liquor to form raw ore pulp, adding a reducing agent, and performing Bayer process reduction dissolution; the reducing agent is hydrogen. According to the method, impurity-free and low-energy-consumption efficient dissolution is realized by introducing the gas-phase reducing agent hydrogen, red mud discharge is reduced from the source, and the recovery rate of valuable components is increased.

The invention belongs to the technical field of metallurgy, and relates to a comprehensive recovery method for antimony-containing gold concentrate, which comprises the following steps: S1, mixing antimony-containing gold concentrate and an antioxidant, carrying out size mixing, then adding sodium sulfide and sodium hydroxide to obtain a size, and reacting to obtain a leaching solution and leaching residues; s2, the leachate obtained in the step S1 is subjected to electrodeposition, and crude antimony and barren liquor are obtained; wherein in the step S1, the antioxidant is a mixture of sodium ascorbate and ethylenediamine tetraacetic acid disodium salt. According to the method, the antimony-containing gold concentrate is subjected to antimony leaching through Na2S under the alkaline condition, in order to avoid gold loss caused by the fact that S < 2-> is oxidized into S < x > < 2-> and then the S < x > < 2-> and Au generate AuSx dissolved in an alkaline solution in the leaching process, an antioxidant is added in the leaching process, leaching of gold in the antimony-containing gold concentrate can be remarkably reduced, and the recovery rate of gold is increased.

The invention discloses a metallurgical solid waste all-component collaborative recovery and high-value utilization method, and belongs to the technical field of metallurgical resource recycling and green metallurgy. According to the method, blast furnace gas sludge, iron-manganese slag and vanadium extraction converter sludge are synergistically blended, and after briquetting and drying, reduction smelting is carried out in an inert atmosphere. Reducing the iron into molten iron; volatile metals such as zinc, indium and gallium are evaporated and enter flue gas, and gallium-indium alloy, crude zinc and residual ash are recovered in a graded manner through a multi-stage condensation system; the slag is subjected to acid leaching to enrich scandium, the leaching liquid is separated to extract vanadium, manganese and scandium, and the leaching slag is used for preparing low-carbon cement. According to the method, all-component collaborative recovery of valuable metals in various metallurgical solid wastes and building material utilization of residual solid wastes are realized, and the method has the advantages of high resource efficiency and environmental friendliness.

The invention belongs to the technical field of metallurgy, and particularly relates to a comprehensive utilization method of waste lithium iron phosphate lithium extraction slag. According to the method, the waste lithium iron phosphate lithium extraction slag is used as a raw material, potassium hydroxide is used as an additive for aerobic calcination, carbon in the lithium extraction slag is combusted, lithium iron phosphate is decomposed, then aqueous solution leaching is carried out to enable phosphorus to be dissolved into a solution in a potassium phosphate form, a leaching solution is purified and then evaporated, concentrated and crystallized to form potassium phosphate, and the lithium iron phosphate is obtained. Potassium phosphate is dissolved in water to react with ferric chloride, calcium chloride, magnesium chloride and the like to prepare ferric phosphate, tricalcium phosphate or trimagnesium phosphate, and leaching residues are dried and converted into ironmaking raw materials with iron oxide as a main component. Through the steps of water leaching pretreatment, calcination oxidation, potassium phosphate conversion, leaching residue recovery and the like, the problems that in the prior art, the waste lithium iron phosphate lithium extraction residues are low in additional value and cannot be effectively utilized are solved, the waste lithium iron phosphate lithium extraction residues are effectively utilized, and efficient separation and high-value utilization of phosphorus and iron resources are achieved.

The invention belongs to the field of rare earth extraction processes, and particularly relates to a closed-loop dressing and smelting process for coal-series associated rare earth mineral resources based on a DESs solvent. Comprising the following steps: taking a sample, carrying out ball milling, adding a leaching agent into the sample after ball milling, leaching the ion adsorption type rare earth elements in the sample, and stirring to obtain a turbid solution; adding a precipitant into the leachate, and then carrying out solid-liquid separation to obtain supernate and precipitates; taking supernate and analyzing the extraction efficiency of the rare earth elements through inductively coupled plasma mass spectrometry (ICP-MS); and adding deionized water into the obtained supernate to recover the leaching agent for next use. The invention aims to obtain a series of deep eutectic solvent (DESs) systems capable of efficiently leaching coal series associated rare earth mineral resources, so that the efficient separation and leaching of ion adsorption type rare earth elements in coal ores are realized; and by utilizing the reversibility of DESs, the recycling of the DESs solvent and the closed-loop dressing and smelting process of coal-series associated rare earth mineral resources are realized.

The invention relates to the technical field of rare earth secondary resource recovery and chemical metallurgy, in particular to a method for roasting and recovering rare earth in neodymium iron boron waste. The invention discloses a method for roasting and recovering rare earth in neodymium iron boron waste. The method comprises the following steps: mixing materials; performing flash chlorination roasting; quenching and leaching; and recovering iron. According to the method, the neodymium-iron-boron waste is finely ground and then fully mixed with zinc chloride powder, zinc chloride is rapidly melted at the reaction temperature of 350-550 DEG C, high-activity ZnCl liquid drops and HCl gas are generated, the ZnCl liquid drops and the HCl gas are subjected to instantaneous and violent gas-solid-liquid-solid reaction with waste particles in a suspended state, rare earth elements are efficiently converted into water-soluble rare earth chlorides, and the rare earth chlorides are recycled. The rare earth and the iron are basically converted into magnetic oxide insoluble in water, efficient separation of the rare earth and the iron can be achieved through simple hot water leaching, a pure rare earth chloride solution and high-grade iron ore concentrate are obtained, the technological process is extremely short, the reaction efficiency is high, and the rare earth recovery rate and the selectivity are both good.

The application belongs to the technical field of metallurgy, and relates to a method for efficiently purifying and directionally removing oxygen and impurities from a precious antimony alloy, which comprises the following steps: S1, after the precious antimony alloy is melted, an arsenic-tellurium removal agent is added, and smelting is performed at 600-610 DEG C to obtain a pre-impurity removal alloy melt and an arsenic-tellurium residue; the arsenic-tellurium removal agent is a mixture of sodium hydroxide and sodium nitrate; S2, the pre-impurity removal alloy melt obtained in step S1 is heated to 620-640 DEG C, a reducing agent is added, and smelting is performed to obtain an arsenic alkali residue and a refined antimony alloy; the reducing agent is a mixture of antimony sulfide and sodium hydroxide; S3, the arsenic-tellurium residue obtained in step S1 and the arsenic alkali residue obtained in step S2 are ball milled, leaching and filtration are performed to obtain a filtrate and a filter residue; S4, the filtrate obtained in step S3 is mixed with sulfuric acid, and after reaction, a neutralization residue and a neutralization liquid are obtained. By introducing the efficient arsenic-tellurium removal agent and the reducing agent, the content of antimony in the arsenic alkali residue is significantly reduced, and the direct recovery rate of antimony and the recovery rate of tellurium are effectively improved.

The invention discloses a method for leaching valuable elements in silicate rare earth ore, and belongs to the technical field of rare earth metallurgy. According to the method, the valuable elements in the rare earth concentrate are efficiently leached by adopting the processes of low-temperature sulfating intensified roasting, clinker hydrometallurgy, leached ore pulp flocculation and filter cake washing. The strengthened low-temperature sulfating roasting process avoids the problems of high energy consumption, serious equipment corrosion, low rare earth leaching rate and complex waste gas treatment (SO2 escape) of a traditional process, meanwhile, silicate rare earth ore decomposition is achieved, the effect of a back-end leaching process is remarkably improved, compared with an acid pickling process, the hydrometallurgy process reduces the acid consumption and the wastewater treatment difficulty, and the production cost is reduced. The leaching ore pulp flocculating settling process is beneficial for improving the industrial production efficiency, the filter cake washing process is beneficial for further improving the leaching rate of valuable elements, the silicate rare earth ore concentrate resources are utilized to the maximum extent on the premise of being environmentally friendly, and a technical path is provided for industrial utilization of silicate type rare earth ore.

The invention relates to the technical field of hydrometallurgy, in particular to a selective leaching method of alkaline hydroxide ore, which comprises the following steps: fully mixing the alkaline hydroxide ore, an ammonium leaching agent and water to react, and obtaining reaction slurry after the reaction is finished; carrying out solid-liquid separation on the obtained reaction slurry to obtain a leaching solution I and a leaching residue I, and collecting the leaching solution I; s3, mixing the leached residues I with water for slurrying to obtain leached residue slurry; and S4, an acid leaching agent and a reducing agent are added into the leaching residue slurry under the conditions of heating and stirring, solid-liquid separation is conducted after full reaction, second leaching liquid and second leaching residues are obtained, and the second leaching liquid is collected. According to the leaching method, the follow-up impurity removal difficulty can be reduced while the leaching rate of cobalt, manganese and nickel of the alkaline hydroxide ore can be increased.

A comprehensive utilization method of beneficiation-metallurgy-chemical combination for germanium-rich lignite includes the following steps: 1) germanium-rich lignite sizing and grinding, 2) catalytic pre-oxidation, 3) nitric acid leaching, and 4) recycling and enrichment of germanium solution. The high effective extraction of germanium from the germanium-rich lignite was achieved via a combination of mineral beneficiation, hydrometallurgy, and chemical processing. Meanwhile, a high yield and high degree of depolymerization humic acid product was produced as byproducts. This method could not only effectively avoid high carbon emission and organic resource waste during conventional germanium-rich lignite pyrometallurgical processing, but also could produce humic acid as quality raw materials for metallurgical and agricultural industries, which has advantages of less environmental pollution, high extraction efficiency, and low comprehensive costs.

The invention relates to the technical field of wet smelting, in particular to a method for normal-pressure oxygen leaching of zinc sulfide concentrate and recovery of sulfur in slag. The method comprises the following steps: grinding the zinc sulfide concentrate to a target particle size; sulfuric acid and a leaching agent are added into the zinc sulfide concentrate to obtain a first reaction system, low-acid first-section normal-pressure oxygen leaching treatment is conducted on the first reaction system, and first-section normal-pressure oxygen leaching liquid and first-section normal-pressure oxygen leaching residues are obtained; the redox potential of the first reaction system is 280-380 mV; waste electrolyte is added into the first-section normal-pressure oxygen leaching residues to obtain a second reaction system, high-acid second-section normal-pressure oxygen leaching treatment is conducted on the second reaction system, and second-section normal-pressure oxygen leaching liquid and second-section normal-pressure oxygen leaching residues are obtained; the redox potential of the second reaction system is 350-450 mV; adding water into the second-section normal-pressure oxygen leaching residues to obtain slurry; performing sulfur transformation treatment on the slurry to obtain transformed slag; and recovering sulfur in the slag. The method can improve the direct recovery rate of sulfur recovery with low cost and low energy consumption.

The application provides a beryllium glass leaching solution purification method, and belongs to the technical field of hydrometallurgy, and comprises the following steps: the beryllium glass leaching solution is heated to a preset temperature, and an alkaline calcium-based ore slurry is added to carry out pre-neutralization reaction to obtain a pre-neutralized solution; the pre-neutralized solution is subjected to first liquid-solid separation treatment to obtain a pre-neutralized liquid and a filter residue; the pre-neutralized liquid is subjected to deep iron and aluminum removal treatment according to a first deep iron and aluminum removal route or a second deep iron and aluminum removal route to obtain a beryllium-containing leaching solution and an iron and aluminum-containing leaching residue, so as to complete the purification of the beryllium glass leaching solution; the first deep iron and aluminum removal route comprises neutralization reaction treatment, second liquid-solid separation treatment and first pressure leaching treatment; the second deep iron and aluminum removal route comprises oxidation neutralization reaction treatment and second pressure leaching treatment. The application can solve the problems of existing technologies, such as the introduction of impurities, strict control, complex process and large beryllium loss.

The invention discloses a method for efficiently leaching and extracting germanium from germanium-containing zinc oxide smoke dust based on ultrasonic strengthening, and relates to the technical field of metal metallurgy, the method comprises the specific steps of raw material pretreatment, ultrasonic-assisted leaching, solid-liquid separation and zinc powder replacement germanium precipitation, germanium-enriched slag strengthened leaching and germanium enrichment and purification; according to the method, the ultrasonic leaching device is introduced, the leaching efficiency of germanium in the germanium-containing zinc oxide smoke dust is improved, passive films on the surfaces of smoke dust particles are effectively damaged through the action of the ultrasonic leaching device, permeation of a leaching agent into the particles is accelerated, and therefore efficient leaching of germanium is achieved within a short time, and meanwhile the leaching efficiency of germanium in the germanium-containing zinc oxide smoke dust is improved. According to the method, the leaching rate of germanium is increased by optimizing the proportion and leaching conditions of the mixed leaching agent, the germanium slag leaching solution is merged into the initial leaching solution, and a secondary enhanced leaching process of a subsequent zinc powder replacement germanium precipitation procedure is carried out, so that the maximum recovery of germanium resources is ensured, the overall resource utilization rate is increased, and the production cost is reduced.