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Preparation method of flame retardant SEBS modified polycarbonate alloy material

A polycarbonate and alloy material technology is applied in the field of polycarbonate alloy material preparation, which can solve the problems of difficulty in meeting, high processing temperature, and high residual stress in the material.

Inactive Publication Date: 2013-01-02
CHANGSHU KAILIDA HONEYCOMB PACKING MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The flame retardant performance of polycarbonate reaches the V-2 level. Although it is superior to ordinary thermoplastic materials, it is still difficult to meet the requirements for flame retardant performance of polycarbonate materials in certain application fields, such as computer components, automobile parts, and building materials.
Moreover, the processing temperature of polycarbonate material is high, and the residual internal stress of the material is high, which is easy to cause the material to crack

Method used

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  • Preparation method of flame retardant SEBS modified polycarbonate alloy material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] Put 175 parts of bisphenol A polycarbonate resin weighed in parts by weight into a drying device and dry at 106°C for 150 min, and then combine SEBS resin weighed in parts by weight, that is, hydrogenated styrene-butadiene - 27 parts of styrene rubber, 10 parts of a mixture of SEBS grafted with maleic anhydride and EVA resin, 28 parts of decabromodiphenylethane, 7 parts of molybdenum trioxide, β (3,5-di-tert-butyl-4- 0.7 parts of octadecyl hydroxybenzene) propionate and 1.8 parts of bis stearic acid amide were put into a high-speed mixer and mixed for 9 minutes, and then transferred to a twin-screw extruder for melt extrusion. The temperature control of the zone is: the temperature of the first zone is 265°C, the temperature of the second zone is 268°C, the temperature of the third zone is 273°C, the temperature of the fourth zone is 278°C, the temperature of the fifth zone is 283°C, the temperature of the sixth zone is 288°C, the temperature of the seventh zone is 288°C...

Embodiment 2

[0015] Put 180 parts of bisphenol A polycarbonate resin weighed in parts by weight into a drying device and dry it at 106°C for 150 min, and then combine it with SEBS resin weighed in parts by weight, that is, hydrogenated styrene-butadiene - 34 parts of styrene rubber, 8 parts of a mixture of maleic anhydride grafted SEBS and EVA resin, 21 parts of decabromodiphenylethane, 11 parts of molybdenum trioxide, β (3,5-di-tert-butyl-4- 0.3 parts of octadecyl hydroxybenzene) propionate and 2 parts of distearic acid amide were put into a high-speed mixer and mixed for 9 minutes, then transferred to a twin-screw extruder for melt extrusion, and the rest were the same as the description of Example 1.

Embodiment 3

[0017] Put 160 parts of bisphenol A polycarbonate resin weighed in parts by weight into a drying device and dry it at 106°C for 150 minutes, and then combine SEBS resin weighed in parts by weight, that is, hydrogenated styrene-butadiene - 29 parts of styrene rubber, 11 parts of a mixture of maleic anhydride grafted SEBS and EVA resin, 24 parts of decabromodiphenylethane, 8 parts of molybdenum trioxide, β (3,5-di-tert-butyl-4- 0.4 parts of octadecyl hydroxybenzene) propionate and 2.2 parts of bis stearic acid amide were put into a high-speed mixer and mixed for 9 minutes, then transferred to a twin-screw extruder for melt extrusion, and the rest were the same as the description of Example 1.

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Abstract

Belonging to the technical field of high polymer material preparation, the invention relates to a preparation method of a flame retardant SEBS (styrene-ethylene / butadiene-styrene) modified polycarbonate alloy material. The method consists of: first putting 160-180 parts of polycarbonate resin into a drying device and drying it at 106DEG C, then placing the polycarbonate resin with 27-34 parts of SEBS resin, 8-14 parts of a compatibilizer masterbatch, 21-28 parts of a flame retardant, 7-11 parts of a metal oxide, 0.3-0.7 part of an anti-aging agent, and 1.8-2.6 parts of a lubricating agent into a high-speed mixer to conduct mixing, then transferring the mixture into a twin-screw extruder to carry out melt extrusion, controlling the first zone of the twin-screw extruder at a temperature of 265DEG C, the second zone at 268DEG C, the third zone at 273DEG C, the fourth zone at 278DEG C, the fifth zone at 283DEG C, the sixth zone at 288DEG C, the seventh zone at 288DEG C and the eighth zone at 288DEG C, and subjecting the material from a die to trough cooling and pelletizing, thus obtaining the flame retardant SEBS modified polycarbonate alloy material, which, in addition to good processing performance and cracking resistance as well as excellent mechanical properties, and also has ideal flame retardance.

Description

technical field [0001] The invention belongs to the technical field of polymer material preparation, and in particular relates to a method for preparing a flame-retardant SEBS-modified polycarbonate alloy material. Background technique [0002] SEBS refers to the copolymer of "styrene-ethylene / butadiene-styrene". Polycarbonate has excellent comprehensive properties and is widely used in the fields of electronics, construction, packaging, medical equipment and transportation. The flame retardant performance of polycarbonate reaches the V-2 level. Although it is superior to ordinary thermoplastic materials, it is still difficult to meet the requirements for flame retardant performance of polycarbonate materials in certain application fields, such as computer components, automobile parts, and building materials. Moreover, the processing temperature of polycarbonate material is high, and the residual internal stress of the material is high, which is easy to cause the material to...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L69/00C08L53/02C08L51/00C08L51/06C08K13/02C08K3/22B29B9/06B29C47/92B29C48/92
CPCB29C48/04B29C48/40B29C48/875B29C48/92B29C2948/92704B29C2948/92895
Inventor 方云祥
Owner CHANGSHU KAILIDA HONEYCOMB PACKING MATERIALS
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