Method for preparing high-tenacity hot-melt prepreg by hot-melt resin matrix

A resin-based, high-toughness technology, applied in the direction of chemical instruments and methods, synthetic resin layered products, lamination, etc., can solve the problems of sacrificing the mechanical properties of composite materials, increasing costs, and increasing resin viscosity, so as to eliminate prepregs Decreased pavement and difficulty in pressurization, strong adaptability, and improved toughness

Active Publication Date: 2013-02-13
AVIC BEIJING INST OF AERONAUTICAL MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The unavoidable problem in the ordinary high-toughening resin preparation method is that on the one hand, the toughness needs to be improved, and the thermoplastic content needs to be increased in a large amount; The preparation process (film formation) and prepreg use process (stickiness) have brought great difficulties
[0005] Based on the above problems, high-toughness resin systems are mainly used at home and abroad. The main methods are: 1) Use intrinsically high-toughness epoxy resin and the corresponding high-toughness structure as the curing agent for the skeleton, and at the same time, melt into thermoplastics to ensure manufacturability or rubber, but this method requires special ra

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0021] Example 1:

[0022] When the resin film is made of phenolic resin, one or more of polysulfone, polyamide, polyether ether ketone, and polytetrafluoroethylene are used as the powder material. The specific examples are:

[0023] Raw material: T700 carbon fiber, fiber surface density is 250g / m 2 ; The prepreg resin is a phenolic resin system, and the prepreg resin content is required to be 40%±2%, that is, the unit area weight of the phenolic resin film is 167g / m2 2 ±8g / m 2 .

[0024] Ordinary prepreg: control the unit area weight of the single-sided film to be 83.5g / m2 2 ±5g / m 2 , after hot pressing, prepreg, cooling and winding with double-sided adhesive film.

[0025] This method: control the unit area weight of the single-sided film to be 63.5g / m2 2 ±4g / m 2 , using 300 mesh polyamide powder, the powder is dispersed on one side, and the weight of the single side of the control powder is: 40g / m 2 ±3g / m 2 , the thermoplastic content is about 24%. After film hot ...

Example Embodiment

[0027] Embodiment 2:

[0028] When the resin film is made of cyanate resin, the powder is made of one or more of polysulfone, polyethersulfone, polyetherimide, and polytetrafluoroethylene. The specific examples are:

[0029] Raw material: aramid fiber fabric, fiber surface density is 220g / m 2 ; The prepreg resin is a modified cyanate ester resin system, and the prepreg resin content is required to be 40%±2%, that is, the weight per unit area is 147g / m2 2 ±7g / m 2 .

[0030] Ordinary prepreg: control the unit area weight of single-sided adhesive film to be 73.5g / m2 2 ±5g / m 2 , after hot pressing, prepreg, cooling and winding with double-sided adhesive film.

[0031] This method: control the unit area weight of the film to be 18.5g / m 2 ±2g / m 2 , using 100 mesh polysulfone powder, the powder is dispersed on one side, and the area weight of the control powder is: 110g / m 2 ±10g / m 2 , The thermoplastic content is about 75%, after film hot pressing, prepreg, cooling and windi...

Example Embodiment

[0033] Embodiment three:

[0034] When epoxy resin is used for the resin film, one or more of polysulfone, polyamide, polyethersulfone, polyetherimide, and polyetheretherketone are used as the powder material; specific examples are:

[0035] Raw material: T700-12K carbon fiber, fiber surface density is 145g / m 2 ; The prepreg resin is a medium temperature epoxy resin system, and the prepreg resin content is required to be 45%±3%, that is, the weight per unit area is 118g / m2 2 ±8g / m 2 .

[0036] Ordinary prepreg: the squeegee temperature is 50℃±5℃, and the total weight of the prepreg is controlled at 263g / m 2 ±10g / m 2 , Rewind after pre-soaking.

[0037] This method: the squeegee temperature is 50℃±5℃, and the unit area weight of each single-sided adhesive film is controlled to be 44g / m2 2 ±4g / m 2 , using 800-mesh polyethersulfone powder, dusting on both sides for toughening, and controlling the single-sided area weight of the powder: 15g / m 2 ±3g / m 2 , the thermoplastic...

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Abstract

The invention provides a method for preparing a high-tenacity hot-melt prepreg by a hot-melt resin matrix. Aiming at conditions that preparation difficulty of a high-tenacity resin matrix is high and the difficulties of subsequent technical processes are easily increased, a non-high-tenacity or non-toughened resin matrix with excellent processing properties is adopted, a proper amount of small-grain-size toughening powder is added in a preparation process of the prepreg in a specific manner, the overlaying property of the prepreg can be maintained, parameters of a curing process of the prepreg are not basically changed, and the tenacity of a composite material can be greatly improved. According to the method for preparing the high-tenacity hot-melt prepreg by the hot-melt resin matrix, the tenacity of the composite material after being solidified is greatly improved when the processing property of the prepreg is maintained; and the method can be applied to hot press molding of aerospace composite material structures and can be applicable to high-tenacity composite material structures in national defense industry applications such as ships, warships and weapons as well as various composite material structures being subjected to hot press molding.

Description

technical field [0001] The invention relates to a method for preparing a high-toughness hot-melt prepreg by using a hot-melt resin matrix, which belongs to the composite material prepreg preparation technology. Background technique [0002] In the new generation of aerospace vehicles, the proportion of fiber-reinforced resin-based composite materials in the structural weight has increased significantly, and the use of parts has become more extensive. However, the use of composite materials is limited by the toughness of composite materials. In many structures, especially It is the main load-bearing structure that requires the composite material to have better toughness, which requires the toughness of the resin matrix to be improved. [0003] According to the level of toughness, the resin matrix can be divided into three generations, the first generation is non-toughened resin, represented by 5208; the second generation is medium toughened resin, represented by 914; the thir...

Claims

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Application Information

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IPC IPC(8): B32B37/06B32B27/04B32B27/12D06M15/41D06M15/37D06M15/55C03C25/32
Inventor 钟翔屿包建文李晔陈祥宝
Owner AVIC BEIJING INST OF AERONAUTICAL MATERIALS
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