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Environment-friendly flame-retardant glass fiber reinforced PP/PA610 (polypropylene/polyamide 610) alloy material with high CTI (comparative tracking index) value and high GWIT (glow-wire ignition temperature) value and preparation method thereof

A technology of PA610 and alloy materials, applied in the field of PP/PA610 alloy materials and their preparation, to achieve the effects of improving impact performance, high CTI value and improving oxidation resistance

Inactive Publication Date: 2015-07-15
SHANGHAI SUNNY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there is no report on the environmentally friendly flame-retardant glass fiber reinforced PP / PA610 alloy material with high CTI value and high GWIT value and excellent comprehensive performance.

Method used

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  • Environment-friendly flame-retardant glass fiber reinforced PP/PA610 (polypropylene/polyamide 610) alloy material with high CTI (comparative tracking index) value and high GWIT (glow-wire ignition temperature) value and preparation method thereof
  • Environment-friendly flame-retardant glass fiber reinforced PP/PA610 (polypropylene/polyamide 610) alloy material with high CTI (comparative tracking index) value and high GWIT (glow-wire ignition temperature) value and preparation method thereof
  • Environment-friendly flame-retardant glass fiber reinforced PP/PA610 (polypropylene/polyamide 610) alloy material with high CTI (comparative tracking index) value and high GWIT (glow-wire ignition temperature) value and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0058] Example 1 Preparation of PP / PA610 alloy material of the present invention (1)

[0059] Weigh raw materials by weight percentage: PP 25%, PA610 (intrinsic viscosity: 2.8dl / g) 25.1%, compound flame retardant 12%, antimony trioxide 4%, alkali-free glass treated with silane coupling agent Fiber 30%, maleic anhydride grafted PP 3%, antioxidant 1330 0.4%, iron oxide 0.5%; put the weighed raw materials into a high-mixer and mix for 5 minutes, and discharge; extrude with a twin-screw extruder For granulation, the processing temperature is 220-240°C, the screw speed is 35HZ, and the specific processing conditions are shown in the table below.

[0060]

Embodiment 2

[0061] Example 2 Preparation of PP / PA610 alloy material of the present invention (2)

[0062] Weigh raw materials by weight percentage: PP 25%, PA610 (intrinsic viscosity: 2.8dl / g) 23%, compound flame retardant 12%, antimony trioxide 4%, alkali-free glass treated with silane coupling agent Fiber 30%, maleic anhydride grafted PP 5%, antioxidant 1330 0.4%, iron oxide 0.6%; put the weighed raw materials into a high-mixer and mix for 2 minutes, and discharge; extrude with a twin-screw extruder For granulation, the processing temperature is 220-240°C, the screw speed is 35HZ, and the specific processing conditions are shown in the table below.

[0063]

Embodiment 3

[0064] Example 3 Preparation of PP / PA610 alloy material of the present invention (3)

[0065] Weigh raw materials by weight percentage: PP 23%, PA610 (intrinsic viscosity: 2.8dl / g) 22%, compound flame retardant 20%, antimony trioxide 4.3%, alkali-free glass treated with silane coupling agent Fiber 20%, maleic anhydride grafted PP 10%, antioxidant 1330 0.1%, iron oxide 0.6%; put the weighed raw materials into a high-mixer and mix for 2 minutes, and discharge; extrude with a twin-screw extruder For granulation, the processing temperature is 220-240°C, the screw speed is 30HZ, and the specific processing conditions are shown in the table below.

[0066]

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PUM

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Abstract

The invention provides an environment-friendly flame-retardant glass fiber reinforced PP / PA610 (polypropylene / polyamide 610) alloy material with a high CTI (comparative tracking index) value and a high GWIT (glow-wire ignition temperature) value, which is prepared by following materials by weight percent: 23-41% of PP, 22-41% of PA610, 6-20% of compound type flame retardant, 3-15% of antimony trioxide, 20-30% of glass fiber, 2-10% of compatilizer, 0.1-1% of antioxidant and 0.1-1% of oxidizing materials, wherein the compound type flame retardant is prepared by the following substances by weight percent: 50% of BPS (Brominated Polystyrene), 25% of magnesium hypophosphite and 25% of talcum powders. The invention also provides a preparation method the material. The environment-friendly flame-retardant glass fiber reinforced PP / PA610 alloy material has the advantages that a novel flame-retardant compound system is adopted, so that the GWIT of the material is improved by 50-100 DEG C, the material can pass 850 DEG C glow-wire, the GWIT values of the material is obviously improved due to the addition of glass fibers, meanwhile, the impact performance and the anti-aging performance of the material are improved, the processing mobility and the smoothness are improved, and the friction coefficient is reduced.

Description

technical field [0001] The invention relates to a PP / PA610 alloy material and a preparation method thereof, in particular to an environmentally friendly flame-retardant glass fiber reinforced PP / PA610 alloy material with a high CTI value and a high GWIT value and a preparation method thereof. Background technique [0002] Nylon (Nylon), Chinese name polyamide, English name polyamide, referred to as PA, is the general term for thermoplastic resins containing repeated amide groups—[NHCO]—on the main chain of the molecule, and its naming is determined by the specific number of carbon atoms in the synthetic monomer , such as PA-6, PA-66, PA-1010, PA-610. PA has high crystallinity and obvious melting point; high surface hardness, wear resistance, small friction coefficient, self-lubrication and noise reduction; good low temperature performance and certain heat resistance (can be used below 100°C); non-toxic , Odorless, no mildew, self-extinguishing, good weather resistance, but ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/12C08L77/06C08L25/04C08K13/06C08K3/22C08K7/14C08K3/32C08K3/34
Inventor 郭建鹏孟诚铭
Owner SHANGHAI SUNNY
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