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Mg-Li magnesium alloy and preparation method thereof

A technology of magnesium alloys and polymers, applied in prosthetics, coatings, medical science, etc., can solve the problems of increased strength of alloys at room temperature, reduced strength of alloys and corrosion resistance, etc., to improve low plasticity, make up for strength and Insufficient effect of corrosion resistance

Active Publication Date: 2015-04-29
PEKING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] However, the addition of Li element inevitably reduces the strength and corrosion resistance of the alloy, while the addition of a small amount of Al element forms Al-containing intermetallic compound phases at the grain boundaries and within the grains of the matrix. Due to the small size and The distribution is relatively uniform, so the room temperature strength of the alloy is increased

Method used

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  • Mg-Li magnesium alloy and preparation method thereof
  • Mg-Li magnesium alloy and preparation method thereof
  • Mg-Li magnesium alloy and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0046] Embodiment 1, preparation Mg-Li-(Al, RE) alloy

[0047] The test materials used pure Mg (99.9wt.%), Li (99.9wt.%), Al (99.95wt.%) and RE (99.8wt.%).

[0048] Weigh the materials according to the following proportions:

[0049] (a) Li 3.3% and the balance of Mg; (b) Li 3.3%, Al 1% and the balance of Mg; (c) Li 8.5% and the balance of Mg; (d) Li 8.5%, Al 1% and the balance of Mg; (e) Li 3.5%, Al 2%, RE 2% and the balance of Mg; (f) Li 3.5%, Al 4%, RE 2% and the balance of Mg; (g) Li 8.5%, Al 2%, RE 2% and the balance of Mg; (h) Li 8.5%, Al 2%, RE 3.5% and the balance of Mg;

[0050] Put the fine magnesium ingot in a crucible and melt it under the protection of argon, then add the rest of the components weighed above to the molten Mg, stir for 5 minutes, rapidly heat the melt to about 720°C, keep it warm and statically After standing for 30 minutes, pour the molten material into a mold preheated to 300°C, grind the gate, anneal at 250°C for 12 hours, and extrude at 280°...

Embodiment 2

[0053] Example 2, Room temperature tensile properties of Mg-Li-(Al, RE) alloy

[0054] The Mg-Li-(Al, RE) alloy prepared in Example 1 was prepared as a tensile sample according to the ASTM-E8-04 tensile test standard, and the SiC water-resistant sandpaper was polished to 2000#, and the room temperature tensile test was carried out using a general tensile testing machine , the stretching speed is 1mm / min.

[0055] The tensile properties at room temperature of the Mg-Li-(Al, RE) alloy prepared by the present invention are as follows: figure 2 shown by figure 2 It can be seen that with the increase of Li content, the yield strength and tensile strength of the alloy decreased, and the elongation was greatly improved. The addition of aluminum element improves the mechanical strength and elongation of the alloy, and the addition of rare earth element improves the yield strength and tensile strength of the alloy, but has little effect on the elongation.

Embodiment 3

[0056] Example 3, Corrosion resistance of Mg-Li-(Al, RE) alloy

[0057] The Mg-Li-(Al, RE) alloy prepared in Example 1 was processed by wire cutting into Grinding and polishing to 2000# with sandpaper. Electrochemical experiments were then performed in Hank's simulated body fluid at 37°C.

[0058] The corrosion potential-corrosion current curve of the Mg-Li-(Al, RE) alloy obtained by the present invention is as follows image 3 shown.

[0059] The corrosion potential-corrosion current curve of the Mg-Li-(Al, RE) alloy prepared by the present invention is as follows image 3 It can be seen from the analysis of the figure that, for the alloy without RE element, the corrosion resistance of the alloy decreases with the increase of Li element content, which is manifested by the decrease of corrosion potential and the increase of corrosion current; the addition of Al element causes The decrease of the corrosion current of the alloy improves the corrosion resistance of the alloy...

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Abstract

The invention discloses an Mg-Li magnesium alloy and a preparation method thereof. The magnesium alloy comprises the following components in percentage by weight: 0-10% (excluding 0) of Li and the balance of Mg. The preparation method of the magnesium alloy comprises the following steps: adding one of the materials shown as (1) -(6) into molten Mg to obtain a melt: (1) Li; (2) Li and Al; (3) Li, Al and mixed rare earths; (4) Li and microelements; (5) Li, Al and microelements; and (6) Li, Al, mixed rare earths and microelements; smelting the melt to obtain a molten material; and extruding the molten material to obtain the magnesium alloy. The Mg-Li-(Al, RE) alloy for biodegradable intravascular stents disclosed by the invention adopts lithium with favorable biocompatibility as the alloying element, thereby overcoming the defect of low plasticity in the traditional magnesium alloy.

Description

technical field [0001] The invention relates to a Mg-Li series magnesium alloy and a preparation method thereof, and belongs to the field of medical magnesium alloy materials and preparation methods thereof. Background technique [0002] There is a huge market demand for bone repair and vascular stent materials. According to statistics, there are 1.8-2 million cases of joint transplantation worldwide every year, and more than 1 million vascular stents are transplanted into patients every year for the treatment of arteriosclerosis. [0003] Vascular stent materials widely used clinically mainly include metal materials such as 316L stainless steel, Co-Cr alloy, pure titanium, Ni-Ti alloy, Pt-Ir alloy, and metal Ta. Since these materials are inert materials and cannot be degraded by themselves in the body, a second operation is required to remove them, which increases the treatment cost and patient risk. In addition, long-term storage of vascular stents made of these inert met...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C23/00C22C1/02A61L27/04A61L27/28
Inventor 郑玉峰周维瑞成艳
Owner PEKING UNIV