Neodymium-ion-doped bivalent cation fluoride laser crystal and preparation method thereof
A divalent cation and laser crystal technology, applied in chemical instruments and methods, crystal growth, single crystal growth, etc., can solve problems such as fluorescence quenching effect, achieve the effect of reducing fluorescence quenching effect and improving fluorescence quantum efficiency
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0037] Example 1 Growth of 2%Nd, 6%Y:CaF by temperature gradient method 2 the crystal
[0038] Weighing NdF to scale 3 (5N)23.78g, YF 3 (5N)51.73g, CaF 2 (5N)424.49g and PbF 2 (5N) 5.0 g. Mix well in a vacuum glove box, place in a graphite crucible, and use pure CaF in the direction as the seed crystal 2 Crystal, seed size: Φ5.8*20mm. The temperature gradient method is used to grow crystals, the atmosphere is high-purity argon atmosphere, the raw material is melted at 1430°C and the growth begins, the growth rate of cooling is 1.5°C / h, and the crystal growth is completed after 120 hours, and then the temperature is lowered to room temperature at 20°C / h; after testing, the sample The emission bandwidth at 1054nm is 19m, the fluorescence quantum efficiency is 40.12%, the fluorescence lifetime is 227.07μs, and the emission cross section is 2.43×10 -20 cm 2 .
[0039] Such as figure 1 Show the Nd grown by temperature gradient method in embodiment 1 3+ ,Y 3+ :CaF 2 Ph...
Embodiment 2
[0040] Example 2 Growth of 0.5%Nd, 2%Y:SrF by crucible drop method 2 the crystal
[0041] Weighing NdF to scale 3 (5N)1.43g, YF 3 (5N)4.16g, SrF 2 (5N)174.41g and PbF 2 (5N) 1.8 g. Fully mixed in a vacuum glove box, placed in a platinum crucible, and the seed crystal was pure SrF in the direction 2 Crystal, seed size: Φ6*28mm. The crucible descending method is used to grow crystals, the atmosphere is high vacuum, and the vacuum degree is 2.5×10 -3 Pa, 1500°C melts the raw material and starts to grow, the crucible descends at a rate of 1.5mm / h, the crystal growth is completed after 260h, and then cools down to room temperature at 20°C / h. After testing, the emission bandwidth of the sample at 1057nm is 22nm, the fluorescence quantum efficiency is 72.11%, the fluorescence lifetime is 334.97μs, and the emission cross section is 3.6×10 -20 cm 2 .
[0042] figure 2 For the Nd grown by the crucible descending method of embodiment 2 3+ ,Y 3+ :SrF 2 Photo of crystals. ...
Embodiment 3
[0043] Example 3 Pulling method to grow 3%Nd, 3%Y:CaF 2 the crystal
[0044] Weighing NdF to scale 3 (5N)14.40g, YF 3 (5N) 10.45g, CaF 2 (5N)175.15g and PbF 2 (5N) 2.0 g. Mix well in a vacuum glove box, the seed crystal is pure CaF in direction 2 Crystal, seed size: Φ6*30mm. The crystal was grown by the pulling method, and the atmosphere was CF 4 In a flowing atmosphere, the raw material is melted at 1440°C and begins to grow, the pulling rate is 2mm / h, the seed rotation rate is 20rpm, and then the temperature is lowered to room temperature at 20°C / h. After testing, the emission bandwidth of the sample at 1054nm is 16nm, the fluorescence quantum efficiency is 19.31%, the fluorescence lifetime is 103.02μs, and the emission cross section is 2.19×10 -20 cm 2 .
PUM
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com