Halogen-free flame retardant polyphenyl ether/polystyrene alloy material and preparation method thereof

A technology of polystyrene and alloy materials, applied in the field of polymer materials, can solve the problems of low impact strength, poor flame retardancy, poor light resistance, etc., and achieve the effect of good light resistance, good corrosion resistance and wide application

Inactive Publication Date: 2013-05-15
SHANGHAI GENIUS ADVANCED MATERIAL (GRP) CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The present invention provides a halogen-free flame-retardant polyphenylene ether / polystyrene (PPO / PS) alloy in order to solve the problems of low notched impact strength, poor light resistance, and poor flame retardancy of the PPO / PS alloy in the prior art. Materials and their preparation methods

Method used

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  • Halogen-free flame retardant polyphenyl ether/polystyrene alloy material and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] (1) Weigh the raw materials of each component according to the following parts by weight:

[0030] 90 parts of polyphenylene ether,

[0031] High impact polystyrene 10 parts,

[0032] RDP 5 copies,

[0033] 5 parts of toughening agent SEBS,

[0034] Antioxidant 1010 0.2 parts,

[0035] Antioxidant 168 0.1 part,

[0036] 0.1 part of hindered amine light stabilizer 944;

[0037] (2) Mix the above raw materials at a high speed with a high-speed mixer, control the speed of the high-speed mixer to 800-1000rpm, mix the temperature at 40°C, and mix for 10 minutes; the mixed material is pelletized through a twin-screw extruder to obtain the product , Control the temperature in each zone at 260-300°C.

Embodiment 2

[0039] (1) Weigh the raw materials of each component according to the following parts by weight:

[0040] 38 parts of polyphenylene ether,

[0041] High impact polystyrene 50 parts,

[0042] TPP 20 parts,

[0043] Toughener SEBS-g-MAH 5 parts,

[0044] Antioxidant 1076 0.2 parts,

[0045] 0.1 part of hindered amine light stabilizer 944;

[0046] (2) Mix the above raw materials at a high speed with a high-speed mixer, control the speed of the high-mixer at 800-1000rpm, mix at a temperature of 80°C, and mix for 3 minutes; extrude the mixed material through a twin-screw extruder and cut into strands. The product is obtained, and the temperature in each zone is controlled at 240-265°C.

Embodiment 3

[0048] (1) Weigh the raw materials of each component according to the following parts by weight:

[0049] 58 parts of polyphenylene ether,

[0050] High impact polystyrene 28 parts,

[0051] 9 copies of TCF,

[0052] Long glass fiber (diameter 12μm) 8 parts,

[0053] Antioxidant 1010 0.2 parts,

[0054] Antioxidant 168 0.2 parts,

[0055] 0.1 part of hindered amine light stabilizer 944;

[0056] (2) Mix the above raw materials at a high speed with a high-speed mixer, control the speed of the high-mixer to 800-1000rpm, mix at a temperature of 60°C, and mix for 6 minutes; extrude the mixed material through a twin-screw extruder and cut into pellets To obtain the product, the temperature in each zone is controlled at 250-280°C.

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Abstract

The invention discloses a halogen-free flame retardant polyphenyl ether/polystyrene alloy material. The material comprises the following components by weight: 37-90 parts of polyphenyl ether, 10-50 parts of polystyrene, 5-20 parts of a flame retardant, 0.2-0.5 parts of an antioxidant and 5.1-35.1 parts of an assistant. The invention also discloses a preparation method of the halogen-free flame retardant polyphenyl ether/polystyrene alloy material. The PPO/PS alloy material provided by the invention has advantages of excellent property, low cost and energy saving, and can realize steel substitution by plastic. The added halogen-free flame retardant endows the alloy with good flame retardancy, is friendly to the environment, and does not cause secondary pollution. Besides, the material forming process is simple, and saves processing cost. Further, a section bar produced from the PPO/PS alloy material has wide application, and can be used for parts in special electronic and electrical appliances and large equipment, due to the advantages of good flame resistance, corrosion resistance, insulation, good strength and toughness, light resistance and light weight.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a halogen-free flame-retardant polyphenylene ether / polystyrene (PPO / PS) alloy material and a preparation method thereof. Background technique [0002] With the progress of society and the development of science and technology, people's life is becoming more and more convenient, and at the same time, people are paying more and more attention to the environment. Polyphenylene oxide (PPO) is a thermoplastic engineering plastic with excellent performance, because it has the following advantages: (1) Excellent physical and mechanical properties. Small density, non-toxic, high mechanical strength, good creep resistance, low molding shrinkage; (2) Excellent heat resistance. Glass transition temperature (T g ) is the highest among thermoplastics, about 210°C, and its melting point is about 260°C. It can work continuously in the range of 160-190°C. The creep resistance at high...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L71/12C08L51/00C08L53/02C08K5/523C08K5/521C08K5/527C08K7/14
Inventor 赵亚囡
Owner SHANGHAI GENIUS ADVANCED MATERIAL (GRP) CO LTD
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