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Coating composition, coating system and construction member with the coating system

A technology of coating composition and coating system, applied in the direction of coating, layered products, metal layered products, etc., can solve problems such as weakening, failure of thermal barrier coating protection, failure, etc.

Active Publication Date: 2013-05-15
CHNA ENERGY INVESTMENT CORP LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] The above measures, whether it is to form an oxide protective film or a thermal barrier coating, will get better results in a high-temperature oxidizing atmosphere, but in some specific occasions, such as a high-temperature partial oxidation atmosphere or a high-temperature reducing atmosphere , the above methods will be greatly weakened or even ineffective, because under the above conditions, either an effective oxide protective film cannot be formed, or the thermal barrier coating will have limited physical and / or chemical interactions with the bonding coating and / or superalloy substrate. reaction, or the thermal barrier coating itself undergoes a reduction reaction and is destroyed, so that the protective effect of the thermal barrier coating is partially or completely ineffective.

Method used

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  • Coating composition, coating system and construction member with the coating system
  • Coating composition, coating system and construction member with the coating system
  • Coating composition, coating system and construction member with the coating system

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0064] The bituminous coal gasification slag (or ash) produced by the Texaco coal-water slurry gasifier was collected. The internal water content of the bituminous coal before gasification was 7.8% by weight, the ash content was 13.5% by weight, and the melting point of the ash was 1330°C. The above gasification slag is preferably decarbonized before use to remove ungasified carbon particles that may be contained in it, and then sintered at 1120 ° C for 16-20 hours in a neutral or reducing atmosphere to increase its compactness , and then grind it to the required particle size for later use. According to chemical analysis, the chemical composition of the above-mentioned bituminous coal gasification slag is as follows:

[0065] Table 1

[0066] SiO 2

[0067] In this embodiment, a single crystal nickel-based superalloy is used as the substrate; NiCrAlTaY is used as the bonding coating; 8% by weight yttrium oxide partially chemically stabilized zirconia (8YSZ) is us...

Embodiment 2

[0100] Put the nickel-based superalloy substrate sample obtained in the above-mentioned Example 1 with the coating system of the present invention into an electric furnace for testing, set the furnace temperature to 1000 ° C, and pass a certain amount of CO, H into the furnace 2 and water vapor, to keep the atmosphere in the furnace as a reducing atmosphere, and take out samples at regular intervals for testing to detect the performance changes of the coating system under high temperature and reducing atmosphere. The test results are shown in Table 7 and Table 8.

[0101] Table 7

[0102]

[0103] Table 8

[0104] Abrasion property of outer coating of vaporized slag after thermal cycle

[0105]

[0106] From Table 7 and Table 8, it can be clearly seen that after the coating system of the present invention and the outer coating of bituminous coal gasification slag are thermally cycled, almost all properties are lost or deteriorated to varying degrees except for surface r...

Embodiment 3

[0108] Long-flame cinders (or ash) produced by coal-fired boilers in thermal power plants were collected. Before combustion, the long-flame coal had an intrinsic water content of 13.4% by weight, an ash content of 17.6% by weight, and a melting point of 1260°C. The above-mentioned long-flame coal combustion slag is preferably calcined before use to remove unburned carbon particles that constitute the main loss on ignition, and then sintered at 1080 ° C for 10-18 hours in a neutral or oxidizing atmosphere to increase Its compactness, and then grind it to the required particle size for later use. After chemical analysis, the chemical composition of the above-mentioned long-flame coal combustion slag is as follows:

[0109] Table 9

[0110] SiO 2

[0111] In this embodiment, cobalt-based high-temperature-resistant alloy X-40 is used as the substrate; NiAl is used as the bonding coating; long-flame coal combustion slag (or ash) with the above-mentioned chemical compos...

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Abstract

The invention discloses a coating composition, a coating system and a construction member with the coating system. The coating composition comprises, by weight, 34 to 64 parts of SiO2, 14 to 41 parts of Al2O3, 1.2 to 25 parts of Fe2O3 or FeO, and 0.3 to 18 parts of CaO. The coating composition selectively comprises, by weight, 0 to 4 parts of TiO2, 0 to 4 parts of MgO, 0 to 6 parts of SO3, 0 to 5 parts of Na2O, 0 to 3 parts of K2O and 0 to 2% of ZnS. The coating composition is prepared from smoke or residual ash, ash residues and / or slag produced by carbonaceous material gasification, combustion or oxidization. The coating composition or the coating system can improve a service life of a high temperature-resistant superalloy construction member in a high-temperature corrosion environment and especially in a reducing atmosphere, and has strong adhesion with superalloy and thermal barrier coating surfaces.

Description

technical field [0001] The present invention relates to a kind of coating composition, coating system, and the member with said coating system, more particularly, relate to a kind of can effectively improve high temperature resistant superalloy member under high temperature and corrosion environment, especially in Coating compositions, coating systems, and components having said coating systems have service life under reducing atmospheres and have extremely strong adhesion to superalloy and thermal barrier coating surfaces. Background technique [0002] The operating environment of high-temperature and high-pressure vessels frequently used in the field of coal chemical industry, such as coking furnaces, combustion furnaces, oxidation furnaces, or gasifiers, is usually a high-temperature and corrosive environment. This harsh environment affects the internal structure of the container, especially It is the heated inner wall surface that causes great damage. In order to protect...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D1/00C09D5/00B32B15/04B32B9/04
Inventor 郭屹苗强郭强
Owner CHNA ENERGY INVESTMENT CORP LTD