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Smelting method for treating zinc leached residues in mixed manner by using oxygen leached residues

A technology of zinc leaching slag and mixed treatment, which is applied in the field of zinc smelting, can solve the problems of high production cost, flue gas treatment, high energy consumption, etc., and achieve the effects of saving fuel, reducing energy consumption, and simplifying the process flow

Active Publication Date: 2014-11-05
CINF ENG CO LTD
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Problems solved by technology

[0007] Combined with zinc sulfide concentrate leaching treatment technology, the present invention provides a smelting method for mixing zinc leaching slag with oxygen leaching slag to overcome the traditional volatilization method with high energy consumption, poor environment and low concentration of SO 2 The flue gas needs to be treated, and the production cost is high

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  • Smelting method for treating zinc leached residues in mixed manner by using oxygen leached residues

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Embodiment Construction

[0029] The present invention will be further described below in conjunction with the examples, and the percentages mentioned in the present invention are all mass percentages.

[0030] Such as figure 1 Shown, a kind of smelting method of zinc leaching slag mixed treatment with oxygen leaching slag, concrete steps are:

[0031] (1) After direct leaching of zinc sulfide concentrate at 110°C-150°C (atmospheric pressure or pressurized), an underflow is produced, the temperature of the underflow is 80°C-85°C, the solid concentration of the underflow is 30%-35%, and the acidity is 20 g / L~60g / L, directly filtered without flotation, to obtain an oxygen leaching residue with high sulfur content and low zinc content, and the supernatant is sent to purification, electrowinning and casting to produce electrolytic zinc. The oxygen leaching residue contains 48-52% of S, 16-20% of Fe and 1-3% of Zn.

[0032] (2) Add zinc leaching slag to the oxygen leaching slag so that the sulfur content ...

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Abstract

The invention belongs to the technical field of smelting of zinc, in particular to a smelting method for treating zinc leached residues in a mixed manner by using oxygen leached residues, which comprises the following steps of: generating underflow after directly leaching zinc sulphide concentrate, directly filtering the underflow without carrying out floatation of the underflow to obtain oxygen leached residues with high sulphur content and low zinc content; mixing the oxygen leached residues with the zinc leached residues to obtain a mixed material; and smelting the mixed material by adopting two sections of oxygen-enriched smelting pools to obtain smoke and smelted residue, the sulphur content of which is less than 1% and the zinc content of which is less than 1%, recycling afterheat in smoke and collecting dust to obtain zinc oxide smoke fed into a zinc system, and carrying out acid treatment of smoke, the dust of which is collected. According to the invention, oxygen pressure leached underflow is directly filtered to obtain the oxygen leached residues with high sulphur content and low zinc content; the zinc leached residues are treated in a mixed manner by using the oxygen leached residues; the property for treating materials is changed; coke or coal as a reducing agent is replaced by sulphur in the oxygen leached residues; a lot of fuel is saved; the environment is improved; and the production cost is reduced.

Description

technical field [0001] The invention belongs to the technical field of zinc smelting, and in particular relates to a smelting method for mixing zinc leaching slag with oxygen leaching slag. Background technique [0002] A large amount of zinc leaching slag is produced in the process of wet zinc smelting, which mainly includes medium leaching slag, high leaching slag, and iron slag (jarosite slag, goethite slag and hematite slag). The general wet zinc smelting method produces medium leaching slag; the high temperature and high acid method produces two kinds of slag, one is high leaching slag, and the other is iron slag produced during the iron removal process; iron slag is produced according to different iron removal processes. Three types of jarosite slag, goethite slag and hematite slag are produced. [0003] The leaching slag produced by the conventional method has a high zinc content, so it must be treated by pyrolysis to recover zinc, and the leaching slag is sold outsi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22B7/00C22B3/08C22B19/30
CPCY02P10/20
Inventor 何醒民邓孟俐左小红谢冰仝一喆舒见义
Owner CINF ENG CO LTD
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