A kind of preparation method of high plasticity tini51 alloy wire

A technology of alloy wire and high plasticity, which is applied in the field of preparation of high-plasticity titanium-nickel shape memory alloy Ti-Ni51at% wire, which can solve the problems of poor alloy fluidity, reduced material processing performance, and not being widely used, so as to improve plastic processing performance effect

Active Publication Date: 2016-05-18
西安赛特新材料科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the limitations of the smelting equipment itself and the smelting process, small ingots below 20Kg are generally prepared, and the fluidity of the alloy is poor, as well as the limitations of pouring conditions, which inevitably produce defects such as pores and cold shuts, which reduces the processing of materials. performance
TiNi alloy smelting vacuum self-consumption + vacuum induction smelting or vacuum shell solidification + vacuum consumable smelting and other vacuum smelting methods are mostly used for experimental comparison and demonstration, and cannot be transformed due to problems in welding, composition control and production costs. A stable process for manufacturability, not commonly used

Method used

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  • A kind of preparation method of high plasticity tini51 alloy wire
  • A kind of preparation method of high plasticity tini51 alloy wire

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] The processing method of TiNi51 (Ti-Ni51at%) alloy Φ6.5mm wire material: firstly, the raw material 0-grade sponge titanium and Ni9999 electrolytic nickel are melted in 25Kg medium frequency vacuum induction according to the ratio of Ti-Ni51at% (Ti-Ni56.06wt%) Φ100-15Kg primary titanium-nickel alloy ingot. Cut off the riser of the primary ingot, peel off the skin, select 4 for assembly and welding as consumable electrodes, weighing 45Kg. A Φ160mm copper crucible is used for smelting in a vacuum consumable furnace to obtain a Φ160-45Kg ingot. Then homogenize the ingot at high temperature, the temperature is 950-1150°C, and the holding time is 4-6 hours. After forging and rolling, it is processed into a wire billet; finally, it is drawn and straightened to produce a finished wire.

Embodiment 2

[0032] The processing method of TiNi51 (Ti-Ni51at%) alloy Φ3.5mm wire material: firstly, the raw material 0-grade sponge titanium and Ni9999 electrolytic nickel are melted in 25Kg medium frequency vacuum induction according to the ratio of Ti-Ni51at% (Ti-Ni56.06wt%) Φ100-15Kg primary titanium-nickel alloy ingot. Cut off the riser of the primary ingot, peel off the skin, and select 10 ingots for assembly and welding as consumable electrodes with a weight of 110Kg. A Φ160mm copper crucible is used for smelting in a vacuum consumable furnace to obtain a Φ160-110Kg ingot. Then homogenize the ingot at high temperature, the temperature is 950-1150°C, and the holding time is 6-8 hours. After forging and rolling, it is processed into a wire billet; finally, it is drawn and straightened to produce a finished wire. The straightening process is at a temperature of 800-950°C, a speed of 5-14mm / s, and water cooling. The wire can be automatically threaded to Φ1.1mm at one time, and the c...

Embodiment 3

[0034] The processing method of TiNi51 (Ti-Ni51at%) alloy Φ1mm wire material: first, the raw material 0-grade sponge titanium and Ni9999 electrolytic nickel are smelted in 25Kg medium frequency vacuum induction melting Φ100- 15Kg primary titanium-nickel alloy ingot. Cut off the riser of the primary ingot, peel off the skin, and select 14 for assembly welding as consumable electrodes with a weight of 150Kg. A Φ160mm copper crucible is used for smelting in a vacuum consumable furnace to obtain a Φ160-150Kg ingot. Then homogenize the ingot at high temperature, the temperature is 950-1150°C, and the holding time is 6-8 hours. After forging and rolling, it is processed into a wire billet; finally, it is drawn and straightened to produce a finished wire. Temperature 800~860℃, speed 10~20mm / s, water cooling.

[0035] Metallographic appearance of TiNi51at%-Φ2.0mm alloy wire prepared by the present invention figure 1 , belonging to equiaxed organization, distribution of fine two-ph...

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Abstract

The invention discloses a preparation method of a high-plasticity TiNi51 alloy wire material. The method comprises steps of: carrying out medium frequency induction smelting and vacuum self-consuming smelting so that the casting defects of primary ingots are eliminated to obtain pure and uniform cast ingots and moreover titanium and nickel alloy large-scale ingot casting are obtained and the production efficiency and material batch stability are improved further; then, homogenizing the cast ingot at a high temperature so as to reduce the brittle phase of the materials; forging and rolling to form wire blanks; and finally, drawing and correcting to produce the finished wire materials. Compared with the prior art, the method has the following advantages that the technology combining medium frequency induction smelting with vacuum self-consuming smelting is adopted so as to obtain the uniform, pure and large-scale titanium-nickel cast ingots; the brittle phase of the materials is reduced through high-temperature homogenizing treatment; and reasonable heating and finished product correcting technologies are adopted so as to improve the plastic processing performance of the materials. The TiNi51 alloy wire materials with large ingot shape, uniformity, stability and high plasticity are prepared.

Description

technical field [0001] The invention relates to a method for preparing a titanium-nickel wire, in particular to a method for preparing a high-plasticity titanium-nickel shape memory alloy Ti-Ni51at% wire. Background technique [0002] Titanium-nickel-based shape memory alloy is a new type of metal functional material that emerged in the 1960s with three characteristics: shape memory, superelasticity and high damping. It also has excellent biocompatibility. It has been used in electronics, machinery , aerospace, energy, medical care and daily necessities and other fields. [0003] The main application characteristics of equiatomic ratio Ti-Ni alloy materials are superelasticity and shape memory effect, including parameters such as alloy phase transition point, recovery stress and recovery rate, and chemical composition is the most sensitive factor affecting alloy performance. When the Ni content is less than 50.5at%, the superelasticity of Ti-Ni alloy is poor; the higher the...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C19/03C22C1/02C22F1/10
Inventor 毛江虹曹继敏杨华斌牛中杰雷亚军薛飒
Owner 西安赛特新材料科技股份有限公司
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