Chlorinated polyvinylchloride mixing material

A chlorinated polyvinyl chloride and chlorinated polypropylene technology, applied in the field of chlorinated polyvinyl chloride mixture, can solve the problem that the CPVC mixture cannot obtain smooth surface and good processing performance, the high-dimensional card is not easy to meet the standard, and the CPVC product loses and other problems, to achieve good demolding performance, increase operating flexibility, and improve processing performance.

Inactive Publication Date: 2013-08-28
SHANGHAI CHLOR ALKALI CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Adding a certain amount of internal and external lubricants can reduce the plasticizing temperature, but since most lubricants, especially internal lubricants that are compatible with CPVC, have a low melting point, it often causes a very severe drop in Vicat , so that CPVC products lose their high-dimensional card characteristics and are not easy to meet the standard
If simply adding an external lubricant will lead to lubrication precipitation, and the processing process is unstable, so that the CPVC mixture with smooth surface and good processing performance cannot be obtained
[0006] Chlorinated polypropylene is a thermoplastic material obtained by modifying polypropylene through chlorination. The polypropylene can be passed through the solvent method, solid phase method and aqueous phase suspension chlorination technology by passing an appropriate amount of chlorine gas or liquid chlorine in the initiator. It is chlorinated in the presence of CPVC, which is similar to CPVC in part of the structure, and has good fluidity and cohesiveness. The melting point of chlorinated polypropylene with different chlorine content is different. When the chlorine content of chlorinated polypropylene It has a low melting point at 30% and has a certain degree of crystallinity. Chlorinated polypropylene is widely used in the production of coatings and adhesives, and has also been reported in PVC blended modified soft products, but in chlorinated polypropylene The application in the processing and modification of PVC hard products has not been reported yet

Method used

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  • Chlorinated polyvinylchloride mixing material
  • Chlorinated polyvinylchloride mixing material
  • Chlorinated polyvinylchloride mixing material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~4, comparative comparative example 5

[0026] The formula is as in Table 1 and Table 2, all in parts by weight.

[0027] The preparation method is as follows: add organotin stabilizer, chlorinated polypropylene, and chlorinated polyethylene to chlorinated polyvinyl chloride resin and mix them in a mixer. The temperature rises to about 60-70 ° C, and other additives are added to mix to 100 After ~120°C, put it into a cooling mixer for cooling, cool down to below 45°C, and discharge, which is the product.

[0028] Table 1

[0029]

[0030]

[0031] As can be seen from Table 1, compared with Example 1 and Comparative Example 5, although the Vicat softening temperature of the compound added with chlorinated polypropylene is reduced, the processability and notched impact strength are greatly improved. And reduce the plasticizing temperature, improve the surface gloss, and broaden the processing width of CPVC.

[0032] Table 2

[0033]

[0034]

[0035] It can be seen from Table 2 that with the addition of...

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PUM

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Abstract

The invention discloses a chlorinated polyvinylchloride mixing material, which comprises the following components, by weight, 100 parts of a chlorinated polyvinylchloride resin, and 0.5-10 parts of chlorinated polypropylene. According to the present invention, the chlorinated polypropylene is added to the chlorinated polyvinylchloride resin so as to increase a plasticizing performance of the chlorinated polyvinylchloride resin during a processing process, reduce a plasticizing temperature, and improve processability, such that the obtained mixing material has a good demolding performance, and performances of notched impact strength, tensile strength and the like of the product are improved.

Description

technical field [0001] The invention relates to a chlorinated polyvinyl chloride compound. Background technique [0002] Chlorinated polyvinyl chloride resin (CPVC), also known as perchlorethylene, is a chlorinated product of polyvinyl chloride (PVC). Theoretically, the highest chlorine content of CPVC can reach 73.2%. Currently, it is produced by the aqueous phase method. The chlorine content of CPVC is usually controlled at 61%-68%. When the chlorine content increases to more than 65%, the tensile strength and bending strength of CPVC increase linearly due to the increase in polarity, and at the same time, the brittleness also increases, and the melt viscosity is more than twice higher than that of PVC. [0003] Since the chlorine content of CPVC is greatly improved compared with PVC, the physical and mechanical properties of CPVC, especially corrosion resistance, high temperature resistance, deformability, solubility and flame retardancy and self-extinguishing properties...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/24C08L23/28C08L23/12
Inventor 王健郑皓郭晓燕
Owner SHANGHAI CHLOR ALKALI CHEM
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