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Dye-sensitized solar cell based on ZnO transparent conductive nanowire array electrode and preparation method thereof

A nanowire array, transparent and conductive technology, applied in the field of solar cells, can solve the problems of electron transmission limitation, electron blockage, etc., and achieve the effects of high conductivity, improved efficiency, and improved light capture efficiency

Active Publication Date: 2016-04-27
CHANGSHA UNIVERSITY OF SCIENCE AND TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When DSCs generate less photoelectrons, they can be transported very quickly; when DSCs generate more photoelectrons, electrons will be "jammed" and electron transport is limited.

Method used

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  • Dye-sensitized solar cell based on ZnO transparent conductive nanowire array electrode and preparation method thereof
  • Dye-sensitized solar cell based on ZnO transparent conductive nanowire array electrode and preparation method thereof
  • Dye-sensitized solar cell based on ZnO transparent conductive nanowire array electrode and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0034] a kind of like figure 1 The dye-sensitized solar cell based on ZnO transparent conductive nanowire array electrode of the present invention shown, the dye-sensitized solar cell is mainly composed of ZnO transparent conductive nanowire array electrode 2, dye-sensitized TiO 2 Nanocrystalline semiconductor photoanode 3, electrolyte 4 (LiI, I 2 and 4-tert-butylpyridine in acetonitrile) and counter electrode 5 (platinum electrode). The nanowire array structure of the ZnO transparent conductive nanowire array electrode 2 is a suede structure, and the sunlight 6 passes from the ZnO transparent conductive nanowire array electrode 2 to the dye-sensitized TiO 2 The direction of the nanocrystalline semiconductor photoanode 3 is incident into the battery, and light scattering occurs at the electrode 2 of the ZnO transparent conductive nanowire array.

[0035] In this embodiment, the ZnO transparent conductive nanowire array electrode 2 is an Al-doped ZnO transparent conductive na...

Embodiment 2

[0043] A dye-sensitized solar cell based on a ZnO transparent conductive nanowire array electrode of the present invention is basically the same as the dye-sensitized solar cell in Example 1, the only difference being: image 3 As shown, the dye-sensitized TiO of this example 2 The nanocrystalline semiconductor photoanode 3 consists of a layer of dye-sensitized dense fine-grained TiO covered on the surface of the ZnO transparent conductive nanowire array. 2 Film 7 and dye-sensitized coarse-grained TiO filled between ZnO transparent conductive nanowire arrays 2 Composition of particles 8, fine-grained TiO 2 The grain size is 5nm; coarse-grained TiO 2 The grain size of the particles was 25 nm.

[0044] A method for preparing a dye-sensitized solar cell based on the ZnO transparent conductive nanowire array electrode of the above-mentioned embodiment is basically the same as the steps in Example 1, the only difference is that in step (2), the TiO 2 Before the slurry, it also ...

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Abstract

The invention discloses a dye-sensitized solar cell based on a ZnO transparent conductive nanowire array electrode, and a preparation method of the dye-sensitized solar cell. The dye-sensitized solar cell mainly consists of the ZnO transparent conductive nanowire array electrode, a dye-sensitized TiO2 nano crystal semiconductor anode, an electrolyte and a counter electrode. The preparation method comprises the following steps: preparing the Al or In-doped ZnO transparent conductive nanowire array electrode through an electric sedimentation method and thermal treatment, subsequently preparing the dye-sensitized TiO2 nano crystal semiconductor anode in match with the ZnO nanowire array electrode in size, and finally assembling the cell. According to the dye-sensitized solar cell, a ZnO transparent conductive nanowire array of a suede structure is taken as a transparent electrode, the function of accelerating electron transport to a conductive electrode and the function of suede light trapping are achieved, and the photoelectric conversion efficiency is improved.

Description

technical field [0001] The invention belongs to the field of solar cells, and in particular relates to a dye-sensitized solar cell based on a ZnO transparent conductive nanowire array as a transparent electrode. Background technique [0002] Dye-sensitized Solar Cells (DSCs) is an organic-inorganic hybrid solar cell that imitates the principle of photosynthesis. It is known as a new generation of solar cells. Since Professor M made a breakthrough in 1991, he has been a research hotspot in the field of solar cells both at home and abroad. It has the advantages of abundant raw materials, low production cost (only 1 / 10-1 / 5 of silicon solar cells), relatively simple process technology, and easy large-scale industrial production. At the same time, it has a wide spectral response range, stable performance, and low attenuation. Preparation The process consumes less energy and is environmentally friendly, so it has attracted many scientists and companies to carry out basic researc...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01G9/042H01G9/20B82Y30/00
CPCY02E10/542Y02P70/50
Inventor 陈建林胡琳琳陈荐何建军李微任延杰邱玮
Owner CHANGSHA UNIVERSITY OF SCIENCE AND TECHNOLOGY
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