Dye-sensitized solar cell based on ZnO transparent conductive nanowire array electrode and preparation method thereof
A nanowire array, transparent and conductive technology, applied in the field of solar cells, can solve the problems of electron transmission limitation, electron blockage, etc., and achieve the effects of high conductivity, improved efficiency, and improved light capture efficiency
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Embodiment 1
[0034] a kind of like figure 1 The dye-sensitized solar cell based on ZnO transparent conductive nanowire array electrode of the present invention shown, the dye-sensitized solar cell is mainly composed of ZnO transparent conductive nanowire array electrode 2, dye-sensitized TiO 2 Nanocrystalline semiconductor photoanode 3, electrolyte 4 (LiI, I 2 and 4-tert-butylpyridine in acetonitrile) and counter electrode 5 (platinum electrode). The nanowire array structure of the ZnO transparent conductive nanowire array electrode 2 is a suede structure, and the sunlight 6 passes from the ZnO transparent conductive nanowire array electrode 2 to the dye-sensitized TiO 2 The direction of the nanocrystalline semiconductor photoanode 3 is incident into the battery, and light scattering occurs at the electrode 2 of the ZnO transparent conductive nanowire array.
[0035] In this embodiment, the ZnO transparent conductive nanowire array electrode 2 is an Al-doped ZnO transparent conductive na...
Embodiment 2
[0043] A dye-sensitized solar cell based on a ZnO transparent conductive nanowire array electrode of the present invention is basically the same as the dye-sensitized solar cell in Example 1, the only difference being: image 3 As shown, the dye-sensitized TiO of this example 2 The nanocrystalline semiconductor photoanode 3 consists of a layer of dye-sensitized dense fine-grained TiO covered on the surface of the ZnO transparent conductive nanowire array. 2 Film 7 and dye-sensitized coarse-grained TiO filled between ZnO transparent conductive nanowire arrays 2 Composition of particles 8, fine-grained TiO 2 The grain size is 5nm; coarse-grained TiO 2 The grain size of the particles was 25 nm.
[0044] A method for preparing a dye-sensitized solar cell based on the ZnO transparent conductive nanowire array electrode of the above-mentioned embodiment is basically the same as the steps in Example 1, the only difference is that in step (2), the TiO 2 Before the slurry, it also ...
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