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Catalytic processing method and catalytic processing device of high-temperature Fischer-Tropsch synthetic oil

A technology of Fischer-Tropsch synthetic oil and catalytic processing, which is applied in the fields of refining and cracking process treatment, organic chemistry, chemical recovery, etc. only in multi-stage series, and can solve the problem of not involving high-temperature Fischer-Tropsch synthetic oil processing and utilization, not suitable for the production of olefins, etc. problem, to achieve the effect of low olefin content, high octane number and high propylene yield

Active Publication Date: 2015-05-20
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] CN1854265A, CN1854266A and CN101812321A disclose a upgrading method with the main purpose of hydrogenation upgrading and increasing diesel oil production, which is not suitable for the production of olefins
However, the above methods mainly focus on the processing and utilization of low-temperature Fischer-Tropsch synthetic oil, and do not involve the processing and utilization of high-temperature Fischer-Tropsch synthetic oil.

Method used

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  • Catalytic processing method and catalytic processing device of high-temperature Fischer-Tropsch synthetic oil
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  • Catalytic processing method and catalytic processing device of high-temperature Fischer-Tropsch synthetic oil

Examples

Experimental program
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Effect test

Embodiment 1

[0051] This example is to illustrate that the method provided by the present invention separates the synthesized product obtained by the high-temperature Fischer-Tropsch synthesis process into different fractional segmented raw materials, and each enters the catalytic cracking effect of different reaction zones.

[0052] The experiment was carried out in a medium riser catalytic cracking unit. Such as figure 1 As shown, the riser reactor 1 of the medium-sized device has an inner diameter of 16 mm and a length of 3800 mm. The riser reactor 2 has an inner diameter of 16 mm and a length of 3200 mm. The outlet of the riser reactor 2 is connected to a dense-phase fluidized bed reaction. The fluidized bed reactor has an inner diameter of 64 mm and a height of 600 mm. The test is operated in a single pass. The 700℃ high temperature regenerant is introduced into the bottom of riser reactor 1 and 2 from the regenerator through the regeneration inclined pipe, and flows upward under the ac...

Embodiment 2

[0054] This embodiment illustrates the effect that the catalyst introduced into the riser reactor 2 is a mixed catalyst of a regenerating agent and a spent agent.

[0055] The experimental device is roughly the same as in Example 1. After the raw material 1-1 is preheated to 120°C and mixed with atomized steam, it enters the riser reactor 1 through the feed nozzle to contact the hot regenerant and undergo a catalytic conversion reaction, and the mixture of reaction oil gas and catalyst goes up, raw material 1 -3 After being preheated to 250°C and mixed with atomized steam, it enters the riser reactor 1 through the feed nozzle and contacts the upward reaction gas and catalyst mixture for catalytic conversion reaction, and the reaction gas and catalyst mixture are formed The mixture continues to move up the riser reactor 1, and separates gas and solid through the rapid separation device set at the outlet of the riser reactor 1. The separated reaction oil and gas are introduced into...

Embodiment 3

[0061] As shown in Example 2, the difference is that the refining pyrolysis light gasoline (distillation range 32~88℃) is mixed with the raw material 1-2 and then introduced into the lower part of the riser reactor 2 (introduced at the same height as the raw material 1-2 ). The mixture of reacted oil and gas and catalyst moves up the riser reactor 2 through the outlet of the riser reactor 2 and enters the fluidized bed reactor 3 to continue to participate in the cracking reaction. The reacted oil and gas are introduced into the settler and then introduced into the product separation system to separate into gas and liquid products. The refining pyrolysis light gasoline accounts for 10% of the total feed (including raw materials 1-1, raw materials 1-2 and raw materials 1-3) by weight.

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Abstract

The invention discloses a catalytic processing method and a catalytic processing device of high-temperature Fischer-Tropsch synthetic oil. The method comprises the following steps: separating the high-temperature Fischer-Tropsch synthetic oil to obtain a high-temperature condensate, a low-temperature condensate and gaseous hydrocarbon; introducing the gaseous hydrocarbon and the high-temperature condensate into a first riser reactor for catalytic conversion; introducing the low-temperature condensate into a second riser reactor for catalytic conversion. The device comprises a reactor, a regenerator and a spent catalyst mixture heat exchanger. The method for processing the high-temperature Fischer-Tropsch synthetic oil provided by the invention is high in propylene yield.

Description

Technical field [0001] The invention relates to a method and device for processing high-temperature Fischer-Tropsch synthetic oil. Background technique [0002] Petroleum hydrocarbons are the main source of chemical raw materials such as engine fuel and propylene. With the continuous rise of international oil prices and the depletion of petroleum resources, countries around the world are actively looking for alternative energy sources for petroleum. The Fischer-Tropsch (FT) synthesis, invented by German chemists F·Fischer and H·Tropsch in 1923, uses synthesis gas including carbon monoxide and hydrogen as raw materials to generate hydrocarbons under the action of a synthesis catalyst. The synthesis gas can be made from coal and natural gas. , Coalbed methane and biomass are transformed and produced from a wide range of sources. [0003] Fischer-Tropsch synthesis includes high-temperature F-T synthesis (HTFT) and low-temperature F-T synthesis (LTFT). The reaction temperature of low...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G55/06C07C4/06C07C11/02C07C11/06
CPCY02P20/52Y02P20/584
Inventor 朱金泉高永灿谢朝钢崔琰马建国杨轶男姜楠杨超
Owner CHINA PETROLEUM & CHEM CORP