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Solvent-free flexible anticorrosion epoxy coating material, preparation method thereof and using method thereof

An epoxy coating, solvent-free technology, used in anti-corrosion coatings, coatings, etc., can solve the problems of delayed construction progress, anti-corrosion life limit, coating cracking, etc., achieves obvious maze effect, inhibits VOC emissions, and improves coating. The effect of layer flexibility

Inactive Publication Date: 2014-05-14
CENT RES INST OF BUILDING & CONSTR CO LTD MCC GRP +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, most of the existing epoxy coatings use organic solvents to dissolve epoxy resin, or use organic solvents as diluents, and the volume solid content of the coatings generally does not exceed 60%, so the emission of volatile organic compounds (VOC) is seriously polluting, which is harmful to the use of People cause serious health hazards and have been strictly restricted in developed countries
For example, the thickness of a single film does not exceed 50 microns, which makes it impossible to complete a single thick coating project and delays the construction progress. Therefore, multiple sprays are often used, but multiple sprays cannot normally guarantee the construction quality
Secondly, the flexibility of the coating above 100 microns obtained by using the existing epoxy coating cannot reach 2mm. After the coating is finished, the hoisting and installation of the rear section of the ring will often cause the coating to crack due to the thick coating and poor flexibility. ,crack
In addition, the existing epoxy coating has a relatively short anti-corrosion period. When used in combination with fluorocarbon and siloxane coatings, it cannot reach the anti-corrosion period of the external coating, resulting in the anti-corrosion period being limited by the internal epoxy coating.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] In this embodiment, according to the percentage by mass, the formula of the solvent-free flexible anti-corrosion epoxy coating is:

[0024] Bisphenol A resin with an epoxy value of 0.54: 35 parts

[0025] Bisphenol A resin with an epoxy value of 0.42: 15 parts

[0026] Polyethylene glycol diglycidyl ether 6 parts

[0027] Glycidyl methacrylate 6 parts

[0028] Wetting and dispersing additive: 3 parts of methyltrimethoxysilane

[0029] 9 glass flakes

[0030] Mica powder 6 parts

[0031] Talc powder 7 parts

[0032] Aluminum tripolyphosphate 11 parts

[0033] Anti-sedimentation additive: BYK410 1 part

[0034] Leveling aid: BYK354 1 part

[0035] The preparation method of above-mentioned solvent-free flexible anticorrosion epoxy coating is as follows:

[0036] (1) Add the wetting and dispersing agent methyltrimethoxysilane into the glass flakes, mix and stir evenly to obtain prefabricated glass flakes for later use;

[0037] (2) Add bisphenol A resin with an ep...

Embodiment 2

[0053] In this embodiment, according to the percentage by mass, the formula of the solvent-free flexible anti-corrosion epoxy coating is:

[0054] Bisphenol A resin with an epoxy value of 0.54: 40 parts

[0055] Bisphenol A resin with an epoxy value of 0.42: 16 parts

[0056] Polyethylene glycol diglycidyl ether 4 parts

[0057] Glycidyl methacrylate 7 parts

[0058] 1 part methyltrimethoxysilane

[0059] Alkyl polyoxyethylene 1 part

[0060] 9 glass flakes

[0061] 5 parts mica powder

[0062] Talc powder 5 parts

[0063] Aluminum tripolyphosphate 12 parts

[0064] The preparation method of above-mentioned solvent-free flexible anticorrosion epoxy coating is as follows:

[0065] (1) Add the wetting and dispersing agent methyltrimethoxysilane into the glass flakes, mix and stir evenly to obtain prefabricated glass flakes for later use;

[0066] (2) Add bisphenol A resin with an epoxy value of 0.54, bisphenol A resin with an epoxy value of 0.42, polyethylene glycol dig...

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Abstract

The invention provides a solvent-free flexible anticorrosion epoxy coating material, a preparation method thereof and a using method thereof. The epoxy coating material comprises 45-60 parts by weight of epoxy resin, 10-15 parts by weight of a reactive diluent, 10-13 parts by weight of aluminium triphosphate, 7-10 parts by weight of glass flake, 2-3 parts by weight of wetting and dispersing auxiliaries and 10-14 parts by weight of a filling material, wherein the epoxy resin comprises 30-40 parts by weight of bisphenol A resin having an epoxide number of 0.54 and 15-20 parts by weight of bisphenol A resin having an epoxide number of 0.42, and the reactive diluent comprises 4-8 parts by weight of poly(ethylene glycol) diglycidyl ether and 6-7 parts by weight of glycidyl methacrylate. Compared with the prior art, the epoxy coating material has advantages of no solvent and zero VOC discharge, improves durability and brittleness of epoxy coatings and prolongs the durable time and anticorrosion age limit of the epoxy coatings, and therefore the epoxy coating material is environmental-friendly, flexible, long-acting and anticorrosion.

Description

technical field [0001] The invention relates to the technical field of epoxy coatings with epoxy resin as the main film-forming substance, in particular to a solvent-free flexible anti-corrosion epoxy coating and its preparation method and use method, which are suitable for the surface of steel structures and other substrates, and have excellent flexibility. , can withstand large steel hoisting, deformation during installation, and does not contain organic solvents and fugitive small organic molecules, solvent-free epoxy anti-corrosion coatings with zero VOC emissions. Background technique [0002] Metal corrosion is a very serious problem faced by people. It is roughly estimated that the annual loss of metal structures, equipment and materials due to corrosion in my country is approximately equivalent to 20% to 40% of the metal output of the year, and more than 100 million tons of metals are scrapped due to corrosion every year in the world, accounting for 100% of economic ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D4/02C09D4/06C09D5/08C09D7/12
Inventor 崔梓杰于钦萍王炜赵希娟严岳荣邓宽
Owner CENT RES INST OF BUILDING & CONSTR CO LTD MCC GRP
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