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Highlight low-volatile polybutylene terephthalate (PBT) composition as well as preparation method and application of composition

A polybutylene terephthalate and low-volatility technology, which is applied in the field of high-gloss and low-volatility polybutylene terephthalate composition and its preparation, can solve the problem of gas gas easily generated by PBT materials and the gloss of injection molded parts Insufficient brightness, affecting the mechanical properties of materials, etc., to achieve excellent mechanical and processing properties, less volatile matter, and improve gloss

Active Publication Date: 2014-05-21
KINGFA SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, PBT still has shortcomings in some aspects, such as the glossiness of PBT injection molded parts is not bright enough, and it is easy to produce air marks, especially when preparing high-gloss products, the rejection rate is high
[0003] For a long time, without affecting the mechanical and processing properties of PBT materials, improving the glossiness of PBT materials and the output rate of high-gloss products has always been a difficult problem in the industry , researchers have done a lot of work on high-gloss and low-volatility PBT materials and have achieved some results. For example, patent CN 1026601 09A adds a mesoporous material to absorb the gas generated during the processing of the material, and has achieved certain results in the preparation of high-gloss and spray-free materials. , but the high content of the mesoporous material will affect the mechanical properties of the material
Patent CN 101580632A PMMA resin and special heat-resistant agent are added to PBT resin to improve the gloss and thermal stability of the material. The PBT material prepared by this method is prone to gas gas and is not suitable for preparing products with high gloss requirements

Method used

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  • Highlight low-volatile polybutylene terephthalate (PBT) composition as well as preparation method and application of composition

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~16 and comparative example 1~6

[0053] According to the proportions in Table 1~2, mix the dried PBT resin, PET resin, gloss additives, black seeds and additives in a high-speed mixer for 1-2 minutes to obtain a premix, and add the premix to the twin-screw extruder The extruder (screw diameter: 35mm, aspect ratio L / D=36) is melt-extruded, glass fiber is side-fed, and the finished product is made by two-stage vacuum granulation. Among them, the temperature of each screw barrel of the twin-screw extruder (from the feeding port to the machine head) is: 140°C, 220°C, 230°C, 240°C, 240°C, 220°C, the screw speed is 300 rpm, and the feeding amount 50kg / h. The product obtained above was dried in an oven at 120°C for 3-4 hours and then injected into a standard sample strip at a temperature of 250°C. The injection-molded standard strips were placed at 25°C and 50% relative humidity for 24 hours before testing performance. The performance test results are shown in Table 1-2.

[0054]

[0055] Table 1 High-gloss and ...

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Abstract

The invention discloses a highlight low-volatile polybutylene terephthalate (PBT) composition as well as a preparation method and application of the composition. The highlight low-volatile PBT composition comprises the following components: 100 parts of PBT resin, 2-20 parts of PET (polyethylene terephthalate) resin, 0-20 parts of glass fiber, 0.5-2 parts of highlight auxiliary, 0.5-2 parts of black seeds and 0.1-2 parts of auxiliary. The preparation method comprises the steps of mixing the PBT resin, the PET resin, the highlight auxiliary, the black seeds and the auxiliary in a high-speed mixer for 1-2min to obtain a premix; melting and extruding the premix by using a double screw extruder; laterally feeding the glass fiber; carrying out two-stage vacuum granulation to obtain a finished product. The highlight auxiliary is introduced to the PBT composition, so that the glossiness of the material and the output rate of a highlight product can be effectively increased on the premise that the mechanical performance and processability of the composition are not affected, and the prepared PBT composition is high in glossiness, good in flowability, few in volatile matters, favorable in mechanical performance and processability and suitable for products such as electronic and electrical products, automobile lamp ornaments and the like with highlight requirements.

Description

technical field [0001] The invention relates to a polybutylene terephthalate composition, in particular to a high-light and low-volatility polybutylene terephthalate composition and a preparation method thereof. Background technique [0002] Polybutylene terephthalate (PBT) is a semi-crystalline engineering plastic with good mechanical properties, electrical properties, heat resistance and chemical resistance, etc. It is widely used in automobiles, electronics, electrical appliances and other industries. However, PBT still has shortcomings in some aspects, such as the glossiness of PBT injection molded parts is not bright enough, and it is easy to produce air marks, especially when preparing high-gloss products, the rejection rate is high. [0003] For a long time, without affecting the mechanical and processing properties of PBT materials, improving the glossiness of PBT materials and the output rate of high-gloss products has always been a difficult problem in the industry...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/02C08K13/04C08K7/14C08K5/5419C08J3/22B29B9/06
Inventor 刘晓亮杨波丁正亚丁超罗忠富袁绍彦周英辉
Owner KINGFA SCI & TECH CO LTD
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