Unlock instant, AI-driven research and patent intelligence for your innovation.

Heat-resistant flame-retardant resin composition, insulated electric wire, and tube

A flame retardant resin and composition technology, applied in plastic/resin/wax insulators, insulated cables, insulators, etc., can solve the problems of low cut-through performance, weak intermolecular force, deformation, etc., to reduce production costs and achieve high cut-through performance. performance effect

Active Publication Date: 2014-06-25
SUMITOMO ELECTRIC IND LTD
View PDF4 Cites 4 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, compared with resin-coated electric wires having an insulating coating layer made of resin such as polyethylene, a fluororubber electric wire having an insulating coating layer made of a fluoroelastomer has a problem in terms of mechanical strength, specifically, There is a problem of low cut-through performance
In addition, fluoroelastomers have the following problems: when the insulating coating is formed by extrusion molding, the fluoroelastomers are not vulcanized immediately after extrusion, so they are easily deformed under load
However, silicones do not contain crystalline components and have very weak intermolecular forces
Therefore, compared with resin-coated electric wires coated with resin such as polyethylene, the mechanical strength of silicone rubber is low, specifically, its cut-through performance is low.
In addition, silicone rubber also has the following problem: Silicone rubber usually does not vulcanize immediately after extrusion, so it is easy to deform under load
Therefore, when the extruded silicone rubber is rolled up with a reel, the silicone rubber is easily deformed

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Heat-resistant flame-retardant resin composition, insulated electric wire, and tube
  • Heat-resistant flame-retardant resin composition, insulated electric wire, and tube
  • Heat-resistant flame-retardant resin composition, insulated electric wire, and tube

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1 to 3 and comparative example 1 to 7

[0057] The components shown in Table I or II (expressed in parts by mass in the table) were kneaded with an open mill, and the kneaded mixture was granulated with a granulator. The obtained pellets were then supplied to an extruder for electric wire coating, through which they were then extruded onto a conductor of TA12 / 0.18. Thus, the conductor was covered so that the outer diameter of the insulation was 1.5 mmφ (thickness of the covering layer: 0.375 mm). Then, the obtained covered conductor was irradiated with an electron beam of 100 kGy using an electron beam irradiation apparatus. Thus, an insulated electric wire having an insulating coating composed of the crosslinked resin composition was produced. The tensile properties (tensile strength and tensile elongation), heat resistance, flame retardancy, insulating properties, oil resistance and cut-through properties of the insulated wires produced as described above were evaluated by the methods described below. The result...

Embodiment 4 to 7

[0085] The components shown in Table III (expressed in parts by mass in the table) were kneaded with an open mill, and the kneaded mixture was made into granules with a granulator. The obtained pellets were then supplied to an extruder for electric wire coating, through which they were then extruded onto a conductor of TA12 / 0.18. Thus, the conductor was covered so that the outer diameter of the insulation was 1.5 mmφ (thickness of the covering layer: 0.375 mm). Then, the obtained covered conductor was irradiated with an electron beam of 100 kGy using an electron beam irradiation apparatus. Thus, an insulated electric wire having an insulating coating composed of the crosslinked resin composition was produced. The tensile properties (tensile strength and tensile elongation), flame retardancy, insulating properties, oil resistance and cut-through properties of the insulated wires produced as described above were evaluated by the same methods as in Examples 1 to 3. In addition,...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Tensile strengthaaaaaaaaaa
Outer diameteraaaaaaaaaa
Thicknessaaaaaaaaaa
Login to View More

Abstract

Provided is a heat-resistant flame-retardant resin composition which is a resin composition made by blending an inorganic filler and / or a flame retardant to a mixture of a random polypropylene and a fluorine rubber composition that comprises a tetrafluoroethylene-alpha-olefin copolymer and a vinylidene fluoride-hexafluoropropylene copolymer and by further irradiating the mixture with an ionizing radiation to cross-link said fluorine rubber composition and said random polypropylene, the mixing ratio between said tetrafluoroethylene-alpha-olefin copolymer and said vinylidene fluoride-hexafluoropropylene copolymer and the mixing ratio between said fluorine rubber composition and said random polypropylene being within predetermined ranges, the heat-resistant flame-retardant resin composition being inexpensive and having excellent insulating properties, heat resistance, flame retardancy, and oil resistance as well as mechanical strength, such as cut-through properties and crimping workability, in a balanced manner. Also provided are an insulated electric wire having an insulating sheath made of said resin composition, and a tube made of said heat-resistant flame-retardant resin composition.

Description

technical field [0001] The present invention relates to a heat-resistant and flame-retardant resin composition constituting an electric wire covering material used in a high-temperature environment, an insulated wire having an insulating coating layer composed of the heat-resistant and flame-retardant resin composition, and the heat-resistant and flame-retardant A tube made of a resin composition. Background technique [0002] Wire harnesses and the like in the engine compartment of automobiles are exposed to high-temperature environments and are often in contact with oil. Therefore, as a material for insulating coatings of electric wires forming these wire harnesses, resin compositions are required to have not only high insulating properties but also high heat resistance, high flame retardancy, and high oil resistance. The insulating coating also needs to have high mechanical strength, for example, good so-called cut-through performance, which is the property that the coat...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C08L27/18C08J3/28C08K3/26C08L23/12C08L27/16H01B3/00H01B3/44H01B7/02H01B7/295
CPCC08K3/26C08J3/28C08J2323/10C08F214/22C08F214/265C08L23/10C08L27/18H01B3/44H01B7/295C08J3/246H01B3/00C08J2327/18C08L23/12C08L23/142C08L27/16H01B3/28H01B3/441H01B3/445C08K2003/265C08L2205/02
Inventor 藤田太郎堀贤治西川信也萩田晃一
Owner SUMITOMO ELECTRIC IND LTD