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Metal organic coordination polymer thermoelectric material and preparation method and application thereof

A reaction, tetracyano technology, applied in the field of metal-organic coordination polymer thermoelectric materials and their preparation, to achieve the effects of easy preparation, improved thermoelectric properties, and low cost

Active Publication Date: 2014-07-02
INST OF CHEM CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

(O. Bubnova, Z.U. Khan, A. Malti, S. Braun, M. Fahlman, M. Berggren, X. Crispin, Nature Materials, 10 (2011) 429-433; I. Levesque, P. O. Bertrand, N. Blouin, M.Leclerc, S.Zecchin, G.Zotti, C.I.Ratcliffe, D.D.Klug, X.Gao, F.Gao, J.S.Tse, Chemistry of Materials, 19(2007) 2128-2138; D.Belo, J.Morgado, E.B. Lopes, I.C.Santos, S.Rabaca, M.T.Duarte, V.Gama, R.T.Henriques, M.Almeida, Synthetic Metals, 102 (1999) 1751-1752) There are many studies on organic thermoelectric materials, but materials with relatively high properties still less

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  • Metal organic coordination polymer thermoelectric material and preparation method and application thereof
  • Metal organic coordination polymer thermoelectric material and preparation method and application thereof
  • Metal organic coordination polymer thermoelectric material and preparation method and application thereof

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Experimental program
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Effect test

Embodiment 1

[0032] Embodiment 1, copper-7,7,8, the preparation of 8-tetracyano p-quinone

[0033] In an argon atmosphere, dissolve 0.510g (2.5mmol) of 7,7,8,8-tetracyano-p-dimethylbenzoquinone in anhydrous acetonitrile, heat to reflux for about 20min until completely dissolved; use solid sample Add 0.476g (2.5mmol) cuprous iodide dispersed in acetonitrile suspension, reflux for 1min; filter, wash the obtained microcrystalline solid with a large amount of acetonitrile in turn, dry in a vacuum oven at 50oC to obtain copper-7 , 7,8,8-Tetracyano-p-dimethylbenzoquinone crystallite sample.

[0034] The X-ray diffraction spectrum of the copper-7,7,8,8-tetracyano-p-dimethylbenzoquinone crystallite sample prepared in this embodiment is as follows figure 1 As shown, its X-ray photoelectron spectrum is shown as figure 2 As shown, among them, figure 2 (A) is the N1s spectrum of copper-7,7,8,8-tetracyano-4-quinone microcrystalline sample, figure 2 (B) is the Cu2pXPS spectrum of copper-7,7,8,8-t...

Embodiment 2

[0036] Example 2. Copper-7,7,8,8-tetracyano-p-quinone doped with 2,3,5,6-tetrafluoro-7,7',8,8'-tetracyanodimethyl-p-benzoquinone Preparation of Dimethylbenzoquinone

[0037]In an argon atmosphere, weigh 3.5 mg, 0.0125 mmol 2,3,5,6-tetrafluoro-7,7',8,8'-tetracyanodimethyl-p-benzoquinone (purchased from Acros Reagent Company) and 0.510 g. 2.5mmol 7,7,8,8-tetracyano-p-methylbenzoquinone (molar ratio 1:200), dissolved in 100ml of anhydrous acetonitrile, heated to reflux for about 20min until completely dissolved; use a solid sampler Add 0.4785g, 2.5125mmol of cuprous iodide dispersed in acetonitrile suspension, reflux for 10s; rapidly heat filter, wash the obtained microcrystalline solid with a large amount of acetonitrile in turn, and dry it in a vacuum oven at 50oC to obtain the doped A microcrystalline sample of copper-7,7,8,8-tetracyano-p-dimethylbenzoquinone.

[0038] Follow the same steps above, and change the dosage of 2,3,5,6-tetrafluoro-7,7',8,8'-tetracyanodimethyl-p-be...

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Abstract

The invention discloses a copper-7, 7, 8, 8-tetracyanoquinodimethane material and a preparation method and an application thereof. The method comprises the following steps: in an inert atmosphere, dissolving -7, 7, 8, 8-tetracyanoquinodimethane in acetonitrile; and then, adding cuprous iodide, and carrying out a reaction under reflux to obtain the material. The material prepared by the invention can be used for preparing organic thermoelectric materials. Through verification, the thermoelectricity of the copper-7, 7, 8, 8-tetracyanoquinodimethane doped by 2, 3, 5, 6-tetrafloro-7, 7', 8, 8'-tetracyanodimethyl p-benzoquinone is remarkably improved, for instance, when the dosage concentration of 2, 3, 5, 6-tetrafloro-7, 7', 8, 8'-tetracyanodimethyl p-benzoquinone under 360K is 1mol%, the power factor is improved from 1.4 mu W / mK<2> to 2.2 mu W / mK<2>. Meanwhile, the preparation method provided by the invention is simple in process, easy in preparation and low in cost.

Description

technical field [0001] The invention relates to a metal-organic coordination polymer thermoelectric material, a preparation method and application thereof, and belongs to the technical field of organic thermoelectric materials. Background technique [0002] Thermoelectric materials use the thermoelectric effect, that is, the Seebeck effect, to realize the conversion between thermal energy and electrical energy. Thermoelectric materials are mainly used in thermoelectric power generation, electric refrigeration, and various sensor devices to recover various waste heat and convert them into electrical energy. The improvement of utilization efficiency alleviates the energy crisis; at the same time, refrigeration and heating devices made of thermoelectric materials using the Peltier effect also have broad application prospects because of their characteristics of no moving parts, no noise, and no pollution. [0003] At present, the research on thermoelectric materials mainly focus...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07F1/08H01L35/24H10N10/856
Inventor 孙源慧黄大真狄重安朱道本徐伟
Owner INST OF CHEM CHINESE ACAD OF SCI
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