White organic light-emitting diode and manufacturing method thereof
An electroluminescent device, organic technology, applied in the direction of organic semiconductor devices, electric solid devices, semiconductor/solid device manufacturing, etc., can solve the problems of high working current and low color rendering index
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[0066] Such as figure 2 As shown, a method for preparing a white light organic electroluminescent device according to an embodiment includes the following steps:
[0067] Step S310: Making a micro pattern composed of a plurality of spaced protrusions on one surface of the refractive layer, pressing the micro-patterned surface of the refractive layer with the glass substrate, and then depositing on the other surface of the refractive layer to form a transparent Conductive layer to obtain anode layer, wherein multiple gaps are formed between the refractive layer and the glass substrate.
[0068] Preferably, before pressing the micro-patterned surface of the refractive layer with the glass substrate, it further includes the steps of sequentially cleaning and surface activation treatment on the glass substrate; the cleaning step is: sequentially using detergent, deionized water, and Ultrasonic cleaning with acetone and ethanol, and then drying. In a specific embodiment, each wash is...
Embodiment 1
[0087] The structure of the white light organic electroluminescent device of this embodiment is: ITO / PU / ITO / NPB:MoO 3 / NPB / TCTA:Ir(MDQ) 2 (acac) / Bphen / MoO 3 / NPB:MoO 3 / NPB / TCTA:Ir(ppy) 3 / CBP:Firpic:MoO 3 / Bphen / Bphen:Cs 2 CO 3 / Ag.
[0088] The preparation of the white light organic electroluminescent device of this embodiment is as follows:
[0089] (1) The ITO glass substrate with a thickness of 100 nanometers was cleaned with detergent, deionized water, acetone and ethanol in sequence. Each cleaning was performed for 5 minutes, stopped for 5 minutes, repeated 3 times, and then dried in an oven. The dried glass substrate is subjected to surface activation treatment; on one surface of the refractive layer, a micropattern composed of a plurality of spaced protrusions is made, each protrusion has a width of 5 microns and a height of 5 microns, and two adjacent The distance between the protrusions is 5 microns; press the surface of the refractive layer with micro-patterns and the I...
Embodiment 2
[0093] The structure of the white light organic electroluminescent device of this embodiment is: ITO / PU / AZO / TCTA:WO 3 / TCTA / mCP:PQIr / BCP / V 2 O 5 / TCTA:WO 3 / TCTA / mCP:Ir(ppy) 2 (acac) / mCP:FIr6:V 2 O 5 / BCP / BCP:CsF / Al.
[0094] The preparation of the white light organic electroluminescent device of this embodiment is as follows:
[0095] (1) The ITO glass substrate with a thickness of 100 nanometers was cleaned with detergent, deionized water, acetone and ethanol in sequence. Each cleaning was performed for 5 minutes, stopped for 5 minutes, repeated 3 times, and then dried in an oven. The dried glass substrate is subjected to surface activation treatment; on one surface of the refractive layer, a micro pattern composed of a plurality of spaced protrusions is made, each protrusion has a width of 10 micrometers and a height of 10 micrometers. The distance between the protrusions is 10 microns; the micro-patterned surface of the refractive layer is pressed against the ITO glass substrat...
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