Production method for preparing calcium hydrophosphate with special Chinese prickly ash fertilizer as byproduct

A technology of calcium hydrogen phosphate and its production method, which is applied in the direction of ammonium orthophosphate fertilizer, alkaline orthophosphate fertilizer, phosphate fertilizer, etc., and can solve problems affecting the quality of calcium hydrogen phosphate products, poor purity of calcium hydrogen phosphate products, and affecting soil quality, etc. , to avoid a large amount of waste liquid discharge, ensure the quality of the growth environment, and improve the effect of the growth environment of Zanthoxylum bungeanum

Inactive Publication Date: 2015-01-14
GUIZHOU KAILIN GRP CO LTD +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, there is no special compound fertilizer for the cultivation of Zanthoxylum bungeanum. The fertilizer is usually used by the growers in combination with traditional chemical fertilizers, potassium dihydrogen phosphate, and urea. When planting Zanthoxylum bungeanum, farmers basically first Use chemical fertilizers as the base fertilizer, and then use potassium dihydrogen phosphate and urea to make compound fertilizers to fertilize Zanthoxylum bungeanum. The amount of each fertilization is 100kg containing 3kg of potassium dihydrogen phosphate and 0.5kg of urea. It needs to be applied 6 times a year. A total of 18 kg of potassium dihydrogen phosphate and 3 kg of urea are used, and the effective absorption of nitrogen, phosphorus and potassium by crops is 20% to 46%, 10% to 25%, and 45% to 60%. It can be seen that a large amount of nitrogen, phosphorus, and potassium Potassium fertilizer put into the soil is difficult to be absorbed by pepper crops, and then remains in the soil. At the same time, according to the mass ratio of nitrogen, phosphorus and potassium elements fertilized into the soil: 5.6:31:39, and the ratio of effective absorption by crops However, it cannot meet this requirement. The absorption of nitrogen and potassium elements is relatively large, while the absorption of phosphorus elements is relatively small. Therefore, it can be concluded that the compound fertilizer prepared according to the traditional pepper fertilizer will leave a large amount of Phosphorus in the soil, and then erodes and reacts with calcium eleme

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  • Production method for preparing calcium hydrophosphate with special Chinese prickly ash fertilizer as byproduct
  • Production method for preparing calcium hydrophosphate with special Chinese prickly ash fertilizer as byproduct
  • Production method for preparing calcium hydrophosphate with special Chinese prickly ash fertilizer as byproduct

Examples

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Embodiment 1

[0048] A production method for preparing calcium hydrogen phosphate by-product special fertilizer for Chinese prickly ash, comprising the following steps:

[0049] (1) Preparation and mixing of raw materials: phosphoric acid and carbonamide are placed in a stirring reaction kettle according to a molar ratio of 1.8:1, at a temperature of 80 ° C, and the stirring speed of the stirring tank is controlled to be 180 r / min for stirring and mixing for 2 h to obtain an intermediate slurry;

[0050] (2) Preparation of calcium hydrogen phosphate: the soluble calcium salt is then added to the reaction kettle containing the intermediate slurry obtained in step 1) at a constant speed for 2h, and when the pH value is controlled to be 5.5, after continuing the stirring reaction for 10min, the reaction ends, and the obtained Slurry containing calcium hydrogen phosphate;

[0051] (3) cyclic crystallization filtration: the slurry containing calcium hydrogen phosphate obtained in step 2) is pla...

Embodiment 2

[0058] A production method for preparing calcium hydrogen phosphate by-product special fertilizer for Chinese prickly ash, comprising the following steps:

[0059] (1) Preparation and mixing of raw materials: phosphoric acid and carbonamide are placed in a stirring reaction kettle in a molar ratio of 2.0:1, at a temperature of 100 ° C, and the stirring speed of the stirring tank is controlled to be 200 r / min for stirring and mixing for 3 hours to obtain an intermediate slurry;

[0060] (2) Preparation of calcium hydrogen phosphate: the soluble calcium salt is then added to the reaction kettle containing the intermediate slurry obtained in step 1) at a constant speed for 3h, and when the control pH value is 6.5, after continuing the stirring reaction for 15min, the reaction ends, and the obtained Slurry containing calcium hydrogen phosphate;

[0061] (3) cyclic crystallization filtration: the slurry containing calcium hydrogen phosphate obtained in step 2) is placed in a cooli...

Embodiment 3

[0068] A production method for preparing calcium hydrogen phosphate by-product special fertilizer for Chinese prickly ash, comprising the following steps:

[0069] (1) Raw material preparation and mixing: phosphoric acid and carbonamide are placed in a stirring reaction kettle according to a molar ratio of 1.9:1, at a temperature of 90 ° C, and the stirring speed of the stirring kettle is controlled to be 190 r / min for stirring and mixing reaction for 2.5 h, to obtain a middle body slurry;

[0070] (2) prepare calcium hydrogen phosphate: add soluble calcium salt to the reaction kettle containing the intermediate slurry obtained in step 1) at a constant speed for 2.5h, when the control pH value is 6, after continuing the stirring reaction for 13min, the reaction ends, Obtain a slurry containing calcium hydrogen phosphate;

[0071] (3) cyclic crystallization filtration: the slurry obtained in step 2) containing calcium hydrogen phosphate is placed in a cooling crystallizer and ...

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Abstract

The invention relates to the technical field of chemical engineering, and particularly relates to a production method for preparing calcium hydrophosphate with a special Chinese prickly ash fertilizer as a byproduct. Through analysis on the effective absorptive amount of nitrogen phosphorus potassium elements according to the fertilizer required by Chinese prickly ash, and adjustment and collocation of element content in a production process, the prepared composite fertilizer in a compound sate can meet the requirements of the Chinese prickly ash to the maximal extent while over-high cost caused by improper collocation of the elements in production of the composite fertilizer is reduced, and excessive elements are further prevented from being fed to soil to cause environmental pollution due to solidification of the composite fertilizer; meanwhile, the effective absorption rate of the prepared special Chinese prickly ash fertilizer is relatively high and can reach over 97.5%, nutrient elements left in a soil structure layer are relatively few, the damage caused by soil hardening is avoided, the growth environment of the Chinese prickly ash is improved, and the growth environment quality of the Chinese prickly ash is ensured.

Description

technical field [0001] The invention relates to the technical field of chemical industry, in particular to a production method for preparing a special fertilizer for Zanthoxylum bungeanum by-product of calcium hydrogen phosphate. Background technique [0002] Sichuan pepper (scientific name: Zanthoxylum bungeanum Maxim.), alias: fenugreek, Dajiao, Qinjiao, Shujiao, Sichuan pepper, Dahongpao or Sanjiao. It is a deciduous shrub or small tree of Rutaceae and Zanthoxylum, which can be planted alone or used as a protective thorn fence. The peel can be used as seasoning, and aromatic oil can be extracted, and it can be used as medicine. The seeds can be eaten, and it can also be processed to make soap. It can remove the fishy smell of various meats; promote saliva secretion, increase appetite; dilate blood vessels, thereby lowering blood pressure. [0003] At present, there is no special compound fertilizer for the planting of Chinese prickly ash. The fertilizers are usually mad...

Claims

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Application Information

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IPC IPC(8): C01B25/32C05G1/00C05B7/00
Inventor 魏发展陈肖虎廖吉星高贵龙朱飞武薛涛蔺忠建赵伟毅曾舒王丽远
Owner GUIZHOU KAILIN GRP CO LTD
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