Preparation method of flame-retardant electroplating ABS for shell of electronic apparatus

A technology for electronic appliances and shells, which is applied in the field of flame-retardant electroplating ABS and its preparation, can solve the problems of fire hazards, lack of flame-retardant effect, etc., reduce flame-retardant performance, improve thermal stability and safety, and facilitate uniformity Effect

Active Publication Date: 2015-01-14
HEFEI GENIUS NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, electroplated acrylonitrile-butadiene-styrene copolymer (ABS) is widely used in the field of electronic and electrical housings, which has the advantages of

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Mix 85 parts of ABS (emulsion method, glue content 30%), 7.5 parts of flame retardant tetrabromobisphenol A, 2.5 parts of antimony trioxide, 5 parts of magnesium hydroxide (mesh 3000-5000), 0.1 part of tetra[β -(3,5-di-tert-butyl 4-hydroxyphenyl) propionate] pentaerythritol ester (antioxidant 1010), 0.2 parts of tris-(2,4-di-tert-butylphenyl) phosphite (antioxidant 168), 0.1 part of ethylene bis stearamide (EBS) into the high mixer, mixed for 2 minutes, and then extruded and granulated with a screw extruder, the extrusion temperature is 160-220 ° C, and the screw speed is 250 rpm , the material performance test results are shown in Table 1.

Embodiment 2

[0026] 82 parts of ABS (emulsion method, glue content 35%), 12 parts of flame retardant tetrabromobisphenol A, 3 parts of antimony trioxide, 3 parts of magnesium hydroxide (mesh 3000-5000), 0.1 part of β-( 3,5-di-tert-butyl-4-hydroxyphenyl) n-octadecyl propionate (antioxidant 1076), 0.2 parts of tris-(2,4-di-tert-butylphenyl) phosphorous acid Ester (antioxidant 168) and 0.2 parts of polyethylene wax are put into a high mixer, mixed for 2 minutes, and then extruded and granulated with a screw extruder, the extrusion temperature is 160-220 ° C, the screw speed is 250 rpm, the material Performance test results are shown in Table 1

Embodiment 3

[0028] 79 parts of ABS (emulsion method, glue content 40%), 16 parts of flame retardant tetrabromobisphenol A, 4 parts of antimony trioxide, 1 part of magnesium hydroxide (mesh 3000-5000), 0.1 part of tetra[β -(3,5-di-tert-butyl 4-hydroxyphenyl) propionate] pentaerythritol ester (antioxidant 1010), 0.3 parts of tris-(2,4-di-tert-butylphenyl) phosphite (antioxidant agent 168), 0.2 parts of ethylene bis stearamide (EBS), and 0.1 parts of polyethylene wax are put into a high mixer, mixed for 2 minutes, and then extruded with a screw extruder to granulate, and the extrusion temperature is 160-220 °C, the screw speed is 250rpm, the material performance test results are shown in Table 1

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Abstract

The invention discloses a flame-retardant electroplating ABS for the shell of an electronic apparatus. The flame-retardant electroplating ABS is prepared by using the following components, by weight, 65-85 parts of ABS, 10-30 parts of a flame retardant, 1-5 parts of a filler, 0.1-0.5 parts of an antioxidant and 0.1-0.3 parts of a lubricant. The invention also discloses a preparation method of the flame-retardant electroplating ABS (acrylonitrile butadiene styrene copolymer) for the shell of the electronic apparatus. The flame-retardant electroplating ABS for the shell of the electronic apparatus can be obtained by controlling the content of the filler and a rubber phase in a system. The flame-retardant electroplating ABS for shell of the electronic apparatus meets the flame retardation requirements of electroplating and electronic products. The increase of the filler benefits the heat resistance and the flame retardation of the ABS material, reduces the cost, and makes the flame retardant ABS material have an electroplating etching property.

Description

technical field [0001] The invention belongs to the technical field of polymer composite materials, and in particular relates to a flame-retardant electroplated ABS for electronic and electric appliance casings and a preparation method thereof. Background technique [0002] At present, electroplated acrylonitrile-butadiene-styrene copolymer (ABS) is widely used in the field of electronic and electrical housings, which has the advantages of aesthetics and anti-aging, but the traditional ABS used in electronic and electrical housings does not have flame retardant effect. There is a certain fire hazard during use. The international and domestic requirements for the flame retardancy of plastic materials used in electronic appliances are getting higher and higher. The UL standard of the United States has become an international standard and is being continuously improved. This has a certain impact on the flame retardancy of plastic products used in electronic appliances. Requir...

Claims

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Application Information

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IPC IPC(8): C08L55/02C08K5/136C08K5/03C08K3/22C08K3/26
Inventor 杨桂生何璟
Owner HEFEI GENIUS NEW MATERIALS
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