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Wet chemical treatment method for crystalline silicon solar cells by performing texturing and cleaning step by step

A solar cell, wet chemical treatment technology, applied in circuits, photovoltaic power generation, electrical components, etc., can solve the problems of cleaning effect, general anti-reflection effect, and shortening of the service life of cleaning solution, so as to prevent cross-contamination of solutions and avoid undesired Uniform etching, the effect of improving production efficiency

Active Publication Date: 2016-08-17
TRINA SOLAR CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, the existing wet chemical treatment methods for crystalline silicon solar cells are generally composed of silicon wafer pretreatment, polishing, texturing, RCA cleaning, drying and other processes. The production efficiency is seriously limited. After wet chemical treatment, the uniformity of the suede surface of the silicon wafer is poor, the size of the "pyramid" structure is large, and the anti-reflection effect is average. It is easy to be brought into the cleaning process, causing solution pollution, reducing the service life of the cleaning solution, and affecting the cleaning effect, etc.

Method used

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  • Wet chemical treatment method for crystalline silicon solar cells by performing texturing and cleaning step by step
  • Wet chemical treatment method for crystalline silicon solar cells by performing texturing and cleaning step by step
  • Wet chemical treatment method for crystalline silicon solar cells by performing texturing and cleaning step by step

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] The operation of the velvet section is as follows:

[0041] (1) Provide a pre-treated silicon wafer; the pre-treatment is: put the silicon wafer in the flower basket into pure water to soak and overflow, rinse for 5 minutes, and remove dust, etc. The resistivity of pure water is 10-18MΩ.

[0042] (2) Pre-cleaning the silicon wafer with the first cleaning solution to remove particle impurities and pollution on the surface of the silicon wafer;

[0043] (3) The silicon wafer is polished with a polishing etchant to corrode the mechanically damaged layer on the surface. The mechanically damaged layer is as follows: image 3 shown;

[0044] (4) adopt texturing liquid to carry out texturing process to silicon chip, make its surface form the textured structure;

[0045] (5) Using the second cleaning solution to clean the silicon wafer to remove surface metal ions, neutralize alkaline impurities, and reduce surface chemical residues;

[0046] (6) Treat the silicon wafer wit...

Embodiment 2

[0068] The operation of the velvet section is as follows:

[0069] (1) Provide a pre-treated silicon wafer; the pre-treatment is: put the silicon wafer in the flower basket into pure water to soak and overflow, rinse for 8 minutes, and remove dust, etc. The resistivity of pure water is 10-18MΩ.

[0070] (2) Pre-cleaning the silicon wafer with the first cleaning solution to remove particle impurities and pollution on the surface of the silicon wafer;

[0071] (3) The silicon wafer is polished with a polishing etchant to corrode the mechanically damaged layer on the surface. The mechanically damaged layer is as follows: image 3 shown;

[0072] (4) adopt texturing liquid to carry out texturing process to silicon chip, make its surface form the textured structure;

[0073] (5) Using the second cleaning solution to clean the silicon wafer to remove surface metal ions, neutralize alkaline impurities, and reduce surface chemical residues;

[0074] (6) Treat the silicon wafer wit...

Embodiment 3

[0096] The operation of the velvet section is as follows:

[0097] (1) Provide a pre-treated silicon wafer; the pre-treatment is: put the silicon wafer in the flower basket into pure water to soak and overflow, rinse for 1 min, and remove dust, etc. The resistivity of pure water is 10-18MΩ.

[0098] (2) Pre-cleaning the silicon wafer with the first cleaning solution to remove particle impurities and pollution on the surface of the silicon wafer;

[0099] (3) The silicon wafer is polished with a polishing etchant to corrode the mechanically damaged layer on the surface. The mechanically damaged layer is as follows: image 3 shown;

[0100] (4) adopt texturing liquid to carry out texturing process to silicon chip, make its surface form the textured structure;

[0101] (5) Using the second cleaning solution to clean the silicon wafer to remove surface metal ions, neutralize alkaline impurities, and reduce surface chemical residues;

[0102] (6) Treat the silicon wafer with an o...

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Abstract

The invention discloses a crystalline silicon solar cell wet chemical treatment method for performing texture surface making and cleaning steps. The method comprises the following steps: (1) providing a pre-treated silicon slice; (2) pre-cleaning the silicon slice by adopting a first cleanout fluid to remove granular impurities and pollution on the surface of the silicon slice; (3) polishing the silicon slice by adopting a polishing corrosive liquid to corrode a medicinal damage layer on the surface; (4) adopting a texture surface making solution to perform texture surface processing on the silicon slice to form a textured surface on the surface of the silicon slice; (5) cleaning the silicon slice by adopting a second cleanout fluid to remove surface metal ions and neutralize alkali impurities, so that the chemical residues on the surface of the silicon slice are reduced; and (6) treating the silicon slice by adopting an oxidation corrosion liquid to remove the oxide layer and to form a hydrophobic drying structure on the surface of the silicon slice. The textured silicon slice can be stored for a long time, the surface cleanliness and the antireflection effects of the textured silicon slice reach relatively high level, the production time is greatly reduced and the production efficiency is improved.

Description

technical field [0001] The invention relates to a method for wet chemical treatment of crystalline silicon solar cells by performing texturing and cleaning step by step. Background technique [0002] At present, the existing wet chemical treatment methods for crystalline silicon solar cells are generally composed of silicon wafer pretreatment, polishing, texturing, RCA cleaning, drying and other processes. The production efficiency is seriously limited. After wet chemical treatment, the uniformity of the suede surface of the silicon wafer is poor, the size of the "pyramid" structure is large, and the anti-reflection effect is average. It is easy to be brought into the cleaning process, causing solution pollution, reducing the service life of the cleaning solution, and affecting the cleaning effect. Contents of the invention [0003] The technical problem to be solved by the present invention is to overcome the defects of the prior art, and to provide a wet chemical treatm...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L31/18
CPCH01L31/18H01L31/186H01L31/1868Y02E10/50Y02P70/50
Inventor 舒欣
Owner TRINA SOLAR CO LTD
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