PC/PET halogen-free flame-retardant alloy containing recycled resin and preparation method thereof

A recycled resin and alloy technology, applied in the field of composition and its preparation, can solve the problems of PC/PET alloy compatibility, thermal stability and chemical resistance, poor chemical resistance, and brittle plastic parts Chemical and other issues, to achieve excellent physical and mechanical properties, good chemical resistance, increase the effect of stability

Active Publication Date: 2017-01-18
SHANGHAI KUMHO SUNNY PLASTICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

CN102604352A patent description Utilizes styrene-acrylonitrile-glycidyl methacrylate terpolymer to manufacture recycled PET master batches, so as to increase the viscosity of recycled PET and end-block the end groups, increase its molecular weight, stabilize molecular weight distribution and inhibit transesterification , but the compatibility, thermal stability and chemical resistance of PC / PET alloys are not mentioned
Poor chemical resistance often leads to embrittlement, cracking and surface damage of plastic parts

Method used

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  • PC/PET halogen-free flame-retardant alloy containing recycled resin and preparation method thereof
  • PC/PET halogen-free flame-retardant alloy containing recycled resin and preparation method thereof
  • PC/PET halogen-free flame-retardant alloy containing recycled resin and preparation method thereof

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Experimental program
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Embodiment 1~13 and comparative example 1~3

[0048] 1.1. Explanation of the meaning of the component code

[0049] Component A-1: ​​PC, polycarbonate with a number average molecular weight of 25,000, produced by Hunan Petrochemical;

[0050] Component A-2: PC, polycarbonate with a number average molecular weight of 21,000, produced by Hunan Petrochemical;

[0051] Component A-3: Regenerated PC, commercially available, the number average molecular weight of polycarbonate is 24000;

[0052] Component A-4: Regenerated PC, commercially available, the number average molecular weight of polycarbonate is 15000;

[0053] Component B-1: recycled PET, commercially available, its source is PET beverage bottle flakes, with a viscosity of 0.8dl / g;

[0054] Component C-1: styrene-acrylonitrile copolymer-glycidyl methacrylate terpolymer (SAN-co-GMA), GMA content is 5%, acrylonitrile content is 28%;

[0055] Component C-2: styrene-acrylonitrile copolymer-glycidyl methacrylate terpolymer (SAN-co-GMA), GMA content is 2%, acrylonitril...

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Abstract

The invention discloses a PC / PET halogen-free flame retarding alloy containing regenerative resin, and a preparation method of the PC / PET halogen-free flame retarding alloy. The PC / PET halogen-free flame retarding alloy comprises the following components in percentage by weight: 5-40% of original PC, 25-63% of regenerative PC, 5-35% of regenerative PET, 5-15% of a toughening agent, 10-20% of a flame retardant, 0.1-0.8% of a flame retardant anti-dropping agent, 0.1-1% of an antioxidant, 0.1-2% of a lubricant, 0.2-3% of an ethylene-methyl acrylic ester copolymer, and 0.2-2% of a GMA-St-AN copolymer. The preparation method comprises the following steps: firstly, sufficiently mixing the regenerative PET, 5-99wt% of the GMA-St-AN copolymer and the ethylene-methyl acrylic ester copolymer so as to prepare master batch; then, sufficiently mixing the master batch with the rest components, and performing eduction, extrusion and pelletization on the mixture so as to obtain the PC / PET halogen-free flame retarding alloy. The halogen-free flame retarding alloy disclosed by the invention not only has excellent physical properties, but also has good heat stability and chemical resistance.

Description

technical field [0001] The invention relates to a composition and a preparation method thereof, in particular to a PC / PET halogen-free flame-retardant alloy containing recycled resin and a preparation method thereof. Background technique [0002] With the continuous and rapid development of the plastic industry, plastic products have been widely used in various industries, but accompanied by an increasing number of plastic waste, resulting in a huge waste of energy, more and more attention has been paid to the recycling of waste plastics . [0003] As we all know, plastic raw materials are chemical products extracted from natural petroleum and are non-renewable natural resources. According to statistics from relevant departments, the annual plastic waste generated by a medium-sized city can meet the raw material needs of 20 small and medium-sized plastic enterprises. Since the vast majority of plastics are non-degradable, they accumulate over time, causing serious white po...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L69/00C08L67/02C08L25/08C08L23/08C08K5/523C08J3/22B29C47/92B29C48/92
CPCB29B9/06B29C48/92B29C2948/9258B29C2948/92704C08J3/226C08J2369/00C08J2467/02C08L69/00C08L2201/02C08L2201/08C08L2201/22C08L2205/025C08L2205/035C08L2205/08C08L2207/20C08L67/02C08L25/14C08L51/04C08L23/0869C08K5/523
Inventor 高磊李强罗明华辛敏琦
Owner SHANGHAI KUMHO SUNNY PLASTICS
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