Modified polyurethane foam plastic

A technology of foamed plastics and polyurethane, which is applied in the field of plastics, can solve the problems that the excellent properties of carbon fibers cannot be fully utilized, reduce the mechanical and mechanical properties of foamed plastics, and poor interface compatibility, etc., and achieve excellent thermo-oxidative stability, light weight, and durability. The effect of high temperature performance enhancement

Active Publication Date: 2015-05-06
芜湖市新京桥包装科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the flexibility of polyurethane foam is poor, which cannot meet the requirements in special industries. The surface of carbon fiber is hydrophilic, the surface has high activity, and good toughness, but the interface compatibility with other materials is poor, which reduces the foam to a cer

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] A kind of modified polyurethane foam plastics proposed by the present invention, its raw material comprises by weight: 40 parts of sucrose polyether, 20 parts of polyurethane, 20 parts of dimethyl methylphosphonate, 2 parts of paraffin, 2 parts of brominated epoxy resin 40 parts of inorganic hollow microspheres, 10 parts of modified carbon fiber, 15 parts of channel black, 1 part of toluene diphenyl phosphate, 1 part of water-soluble silicone oil, 0.4 parts of foaming agent, 2 parts of higher fatty alcohol, sulfide Type phenolic antioxidant 0.2 part; wherein blowing agent comprises by weight: 16 parts of 1-chloro-3,3,3-trifluoropropene, 2 parts of 1,1,1,3-tetrafluoropropene and pentane 2 copies;

[0017] In the preparation process of modified carbon fiber, weigh 1 part of carbon fiber by weight, the length of carbon fiber is 1-5mm, put it in an oven at 90°C for drying, and then place it in a radiation-resistant metal aluminum pool, under vacuum Carry out γ-ray irradiat...

Embodiment 2

[0019] A modified polyurethane foam plastic proposed by the present invention, its raw materials include by weight: 50 parts of sucrose polyether, 10 parts of polyurethane, 30 parts of dimethyl methylphosphonate, 1 part of paraffin, 3 parts of brominated epoxy resin , 20 parts of inorganic hollow microspheres, 15 parts of modified carbon fiber, 10 parts of channel black, 1.5 parts of cresyl diphenyl phosphate, 0.5 parts of water-soluble silicone oil, 0.8 parts of foaming agent, 1 part of higher fatty alcohol, sulfide Type phenolic antioxidant 0.5 part; Wherein blowing agent comprises by weight: 12 parts of 1-chloro-3,3,3-trifluoropropene, 3 parts of 1,1,1,3-tetrafluoropropene and pentane 1 copy;

[0020] In the preparation process of the modified carbon fiber, weigh 2 parts of carbon fiber by weight, the length of the carbon fiber is 1-5mm, put it in an oven at 85°C for drying, and then put it in a radiation-resistant metal aluminum pool, under vacuum Carry out γ-ray irradiat...

Embodiment 3

[0022] A kind of modified polyurethane foam plastics proposed by the present invention, its raw material comprises by weight: 43 parts of sucrose polyether, 15 parts of polyurethane, 23 parts of dimethyl methylphosphonate, 1.5 parts of paraffin, 2.5 parts of brominated epoxy resin Parts, 32 parts of inorganic hollow microspheres, 13 parts of modified carbon fiber, 13 parts of channel black, 1.32 parts of cresyl diphenyl phosphate, 0.7 parts of water-soluble silicone oil, 0.6 parts of foaming agent, 1.6 parts of higher fatty alcohol, sulfide Type phenolic antioxidant 0.35 parts; wherein blowing agent comprises by weight: 1-chloro-3,3,3-trifluoropropene 15 parts, 1,1,1,3-tetrafluoropropene 2.2 parts and pentane 1.6 copies;

[0023]In the preparation process of the modified carbon fiber, weigh 1.5 parts of carbon fiber by weight, the length of the carbon fiber is 1-5mm, put it in an oven at 89°C for drying, and then put it in a radiation-resistant metal aluminum pool, under vacuu...

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Abstract

The invention discloses a modified polyurethane foam plastic which comprises the following components in parts by weight: 40-50 parts of sucrose polyether, 10-20 parts of polyurethane, 20-30 parts of dimethyl methylphosphonate, 1-2 parts of paraffin, 2-3 parts of brominated epoxy resin, 20-40 parts of inorganic hollow microspheres, 10-15 parts of modified carbon fibers, 10-15 parts of channel black, 1-1.5 parts of cresyl diphenyl phosphate, 0.5-1 part of water-soluble silicone oil, 0.4-0.8 parts of a foamer, 1-2 parts of higher aliphatic alcohol and 0.2-0.5 part of a thioether phenolic antioxidant, wherein the foamer comprises the following components in parts by weight: 12-16 parts of 1-chloro-3,3,3-trifluoropropene, 2-3 parts of 1,1,1,3-tetrafluoropropene and 1-2 parts of pentane. The modified polyurethane foam plastic is excellent in toughness, heat-resistant stability and mechanical property.

Description

technical field [0001] The invention relates to the technical field of plastics, in particular to a modified polyurethane foamed plastic. Background technique [0002] Polyurethane foam is a good raw material, which is used in sofas, mattresses, shoe materials, high-end furniture and other fields, and plays an increasingly important role in the national economy. However, the flexibility of polyurethane foam is poor, which cannot meet the requirements in special industries. The surface of carbon fiber is hydrophilic, the surface has high activity, and good toughness, but the interface compatibility with other materials is poor, which reduces the foam to a certain extent. The mechanical and mechanical properties of plastics prevent the excellent properties of carbon fibers from being fully utilized. How to prepare a polyurethane foam with good toughness and excellent mechanical properties has become a technical problem that needs to be solved at present. Contents of the inve...

Claims

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Application Information

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IPC IPC(8): C08L71/02C08L75/04C08L63/00C08L91/06C08K13/06C08K9/00C08K9/04C08K7/06C08K5/5333C08K7/24C08K3/04C08K5/523C08J9/14
Inventor 彭其周
Owner 芜湖市新京桥包装科技有限公司
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