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Nanometer level film sample tester

A nano-scale, tester technology, applied in the direction of color/spectral characteristic measurement, etc., to achieve good effect, simple structure, and beneficial to the effect of measurement accuracy

Inactive Publication Date: 2015-05-06
QINGDAO JIAHEXING MILLING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The tester in the prior art usually uses a contact temperature measurement method when measuring samples. Since the position where the infrared light is irradiated and the area where the light path passes is not allowed to be blocked by objects, the temperature measurement point cannot be placed in the detection area. The deviation of the placement position of the temperature point will cause a large deviation in the temperature measurement, so the general temperature measurement method cannot be applied to the reflection technology
For general heating devices and temperature measuring devices, the temperature measurement point is located inside the hot stage, and the sample film is close to the surface of the hot stage during the test. The temperature of the hot stage is basically the temperature of the sample, but for the reflective infrared spectroscopy device, Because the substrate belongs to glass with low thermal conductivity, there must be a temperature difference between the upper and lower surfaces of the substrate. Therefore, the surface temperature has a great relationship with the selection of temperature measurement points and temperature measurement methods. Therefore, the temperature of the sample cannot be accurately measured in the prior art. It is impossible to accurately control the temperature

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] The crystallization behavior of polylactic acid (PLLA) was measured during heating and cooling.

[0038] Place the substrate coated with polylactic acid (PLLA) samples on the hot stage, set the heating rate and set temperature through the temperature controller, start the cooling water and the semiconductor refrigeration chip, and conduct the infrared spectrum test. image 3It is the infrared spectrum change map measured when polylactic acid rises from minus 10 degrees Celsius at a heating rate of 2 degrees Celsius per minute to 180 degrees and then cools down to room temperature at a cooling rate of 2 degrees Celsius per minute. The scanning frequency is once per minute, but for Obviously observe the spectral changes of the sample during the heating process, and only select part of the spectrum for graphing. From the changes in the characteristic peaks in the figure, we can get the glass transition temperature Tg, crystallization temperature Tc, melting point Tm and oth...

Embodiment 2

[0041] Measurement of the crystallization behavior of poly-3-hexylthiophene (P3HT) during heating and cooling (continuous heating).

[0042] Place the substrate coated with poly-3-hexylthiophene (P3HT) sample on the hot stage, set the heating rate and set temperature through the temperature controller, start the cooling water and the semiconductor refrigeration chip, and conduct the infrared spectrum test. Figure 4 and Figure 5 (a) is the infrared spectrum change graph measured after poly-3-hexylthiophene rises from minus 10 degrees Celsius to 200 degrees Celsius at a heating rate of 2 degrees Celsius per minute, and the scanning frequency is once per minute. Investigate the changes in the crystal form and orientation structure of the sample during the continuous heating process. In order to clearly observe the spectral changes of the sample during the heating process, only part of the spectrum was selected for mapping.

[0043]

Embodiment 3

[0045] Measurement of the crystallization behavior of poly-3-hexylthiophene (P3HT) during heating and cooling (step heating).

[0046] Place the substrate coated with poly-3-hexylthiophene (P3HT) sample on the hot stage, set the heating rate and set temperature through the temperature controller, start the cooling water and the semiconductor refrigeration chip, and conduct the infrared spectrum test. The heating method adopts a step-by-step heating mode, that is, the sample is heated up quickly, then the sample is kept at a constant temperature for 10 minutes, and then the temperature is quickly cooled to the original temperature, and then the infrared spectrum measurement is performed. For example, the P3HT film is quickly heated to 50 degrees, kept at 50 degrees for 10 minutes, and then quickly lowered back to the original temperature for infrared spectrum measurement. Figure 5 (b) is the infrared spectrum change graph measured after the poly-3-hexylthiophene is raised fro...

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Abstract

A disclosed nanometer level film sample tester comprises a reflection mechanism and a temperature control mechanism; the reflection mechanism comprises a polaroid, a first reflector and a second reflector; the temperature control mechanism comprises a heating bench, a refrigeration sheet, a cooling-water block and an infrared temperature-test sensor; the heating bench and the infrared temperature-test sensor are connected with a temperature controller via leads; the infrared temperature-test sensor is disposed on the heating bench via a sensor support; the refrigeration sheet and the cooling-water block are overlapped and disposed below the heating bench; the heating bench is installed on a pedestal via an adjustable heating bench support; and the polaroid, the first reflector and the second reflector are respectively fixedly disposed on corresponding supports via rotation parts. The temperature characteristic is measured by employing the infrared temperature-test sensor being indirectly contacted with a measured article, and the heating bench height, the reflector angle and the polaroid angle are adjustable and randomly adjustable, thereby facilitating adjusting of measured light. The measure effect is good.

Description

[0001] technical field [0002] The invention relates to a device for spectrum detection, in particular to a nanoscale film sample tester. 【Background technique】 [0003] When performing spectral analysis on nanoscale ultra-thin samples, it is necessary to use a grazing angle reflectance spectrometer. The tester in the prior art usually uses a contact temperature measurement method when measuring samples. Since the position where the infrared light is irradiated and the area where the light path passes is not allowed to be blocked by objects, the temperature measurement point cannot be placed in the detection area. The offset of the placement position of the temperature point will cause a large deviation in the temperature measurement, so the general temperature measurement method cannot be applied to the reflection technology. For general heating devices and temperature measuring devices, the temperature measurement point is located inside the hot stage, and the sample fi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N21/25
Inventor 刘泽生
Owner QINGDAO JIAHEXING MILLING
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