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Carbon fiber surface treatment method

A surface treatment and carbon fiber technology, applied in the field of carbon fiber surface treatment technology, can solve problems such as inability to continue production

Inactive Publication Date: 2015-05-20
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the currently studied low-temperature plasma carbon fiber surface treatment method is mainly under vacuum conditions, which cannot achieve continuous production in the carbon fiber surface treatment process.

Method used

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  • Carbon fiber surface treatment method

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0012] use figure 1 The low-temperature plasma device shown treats the carbon fiber surface. Under an atmospheric pressure environment, nitrogen gas is used as the carbon fiber surface treatment medium to generate low-temperature plasma, and the low-temperature plasma bombards the surface of the moving carbon fiber tow. The low-temperature plasma is a jet-type low-temperature plasma. The running speed of carbon fiber tow is 90m / h; the working environment temperature of carbon fiber treatment is 25°C; the gap between carbon fiber tow 2 and jet low-temperature plasma emission device 1 is 8mm; the environmental humidity of carbon fiber surface treatment is 60%; the power range of carbon fiber surface treatment is 1000W / bundle; low temperature plasma carbon fiber surface treatment temperature 80 ℃. The total content of polar functional groups (mainly -OH, -C=O, -COOH) on the surface of carbon fiber is 22.32%, and the interlaminar shear strength is 90MPa.

Embodiment 2

[0014] use figure 1 The low-temperature plasma device shown treats the carbon fiber surface. Under an atmospheric pressure environment, nitrogen gas is used as the carbon fiber surface treatment medium to generate low-temperature plasma, and the low-temperature plasma bombards the surface of the moving carbon fiber tow. The low-temperature plasma is a jet-type low-temperature plasma. The running speed of carbon fiber tow is 90m / h; the working environment temperature of carbon fiber treatment is 25°C; the gap between carbon fiber and plasma emission device is 8mm; the environmental humidity of carbon fiber surface treatment is 60%; the power range of carbon fiber surface treatment is 1400W / bundle; low temperature plasma The body carbon fiber surface treatment temperature is 80°C. The total content of polar functional groups (mainly -OH, -C=O, -COOH) on the surface of carbon fiber is 23.2%, and the interlaminar shear strength is 100MPa.

Embodiment 3

[0016] use figure 1 The low-temperature plasma device shown treats the carbon fiber surface. Under an atmospheric pressure environment, nitrogen gas is used as the carbon fiber surface treatment medium to generate low-temperature plasma, and the low-temperature plasma bombards the surface of the moving carbon fiber tow. The low-temperature plasma is a jet-type low-temperature plasma. The running speed of carbon fiber tow is 90m / h; the working environment temperature of carbon fiber treatment is 25°C; the gap between carbon fiber and plasma emission device is 8mm; the environmental humidity of carbon fiber surface treatment is 60%; the power range of carbon fiber surface treatment is 1600W / bundle; low temperature plasma The body carbon fiber surface treatment temperature is 80°C. The total content of polar functional groups (mainly -OH, -C=O, -COOH) on the surface of carbon fiber is 23.1%, and the interlaminar shear strength is 105MPa.

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Abstract

The invention relates to carbon fiber surface treatment method. The method is characterized in that under an atmospheric pressure, nitrogen is taken as the carbon fiber surface treatment medium so as to generate low-temperature plasma to bombard the surface of moving carbon fiber bundles by ions. After the surface treatment, the active polar functional groups on the carbon fiber surface are increased, the grooves on the carbon fiber surface are deepened, the specific surface area is enlarged, the interlayer shearing strength of the composite material of carbon fibers is enhanced, the energy consumption is reduced, the energy is saved, and the method is clean and pollution-free.

Description

Technical field: [0001] The invention relates to a carbon fiber surface treatment method, which is mainly applied to the carbon fiber surface treatment process in the carbon fiber production link. Background technique: [0002] Because carbon fiber has high elastic modulus, high specific strength and excellent heat resistance, it can be combined with high polymer to obtain composite materials with excellent mechanical properties, which have been widely used in aviation, aerospace, sports equipment, civilian fishing gear, etc. . However, the surface of untreated carbon fiber is very smooth, the specific surface area is small, and it shows hydrophobicity, so the interface with the polymer is poor, resulting in low strength of the composite material, and the superior performance of carbon fiber has not been effectively utilized. Therefore, before the composite of carbon fiber and resin, it is necessary to treat the surface to improve the interface between the fiber and the mat...

Claims

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Application Information

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IPC IPC(8): D06M10/00
Inventor 刘兆政肖建文王文胜
Owner PETROCHINA CO LTD
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