Multi-aperture graphene film manufacturing method and gas separation element

A graphene film and a manufacturing method technology are applied in the field of multi-porous graphene film manufacturing, can solve the problems of complex operation, unclear molecular passivation mechanism, difficult control of conditions, etc., and achieve a simple preparation process and are suitable for large-scale industry. Effects of application, strong selectivity and high permeability

Inactive Publication Date: 2015-05-27
NANJING UNIV OF TECH +1
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Problems solved by technology

However, due to the complex operation, uncontrollable conditions, and unclear mechanism of molecular passivation, it is still mainly in the stage of molecular dynamics simulation.
[0004] In summary, although the technology of using multi-aperture graphene for gas permeation has good prospects, there is no preparation method of multi-aperture graphene suitable for practical applications.

Method used

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  • Multi-aperture graphene film manufacturing method and gas separation element
  • Multi-aperture graphene film manufacturing method and gas separation element
  • Multi-aperture graphene film manufacturing method and gas separation element

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Embodiment Construction

[0019] The technical scheme of the present invention is described in detail below in conjunction with accompanying drawing:

[0020] As described in the background section, although single-layer or multi-layer intrinsic graphene is theoretically considered to be an ideal membrane for permeation and separation, it cannot actually be applied to membrane separation due to the lack of channels for gas permeation. There is also no technique disclosed for producing gas permeable pores in graphene membranes. In order to solve this problem, the idea of ​​the present invention is to consciously create lattice defects in the graphene film, and then use energy beam radiation in a certain energy range to make the graphene carbon rings without destroying the normal graphene structure. The carbon bonds with lattice defects in the hexagonal structure are broken, thereby creating pores for gas to pass through, and then obtaining a multi-aperture graphene membrane that can be used for membrane...

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Abstract

The invention discloses a multi-aperture graphene film manufacturing method. In the method, an energy beam is used for radiating the graphene film with lattice imperfection, as a result, the carbon bonding with lattice imperfection in graphene carbon ring hexagonal structure is broken, aperture is generated, and the multi-aperture graphene film is generated; moreover, size of the aperture is controlled by regulation on concentration of the lattice imperfection and/or radiation intensity of the energy beam. The invention further discloses a gas separation element using the multi-aperture graphene film manufactured by the method. By the method, the graphene film with gas permeation aperture is prepared actually for the first time, and application of the graphene film in the aspect of gas separation is realized successfully; in the method, size of aperture can be controlled as needed, moreover, the preparation technology is simple, the implementation cost is low, so that the method is suitable for large-scale industrial application; the gas separation element provided by the invention has very strong selectivity and high permeability to gas molecules, and by experimental verification, separation coefficient of the gas separation element to H2/N2 at normal temperature is up to 260.

Description

technical field [0001] The invention relates to a method for manufacturing a graphene membrane, in particular to a method for manufacturing a multi-aperture graphene membrane that can be used for gas separation. Background technique [0002] Inorganic material membranes represented by metals, metal oxides, ceramics, carbon, and porous glass have been widely used in gas separation, seawater desalination, food processing, wastewater treatment, and medicine due to their excellent physical, chemical, and biological properties. . However, it is a difficult problem to be solved that inorganic membranes have high gas selectivity and permeability at the same time. At the same time, how to improve the temperature and chemical resistance of the membrane while maintaining high permeability and high selectivity is another challenge for inorganic membrane separation applications. One of the main directions to solve these problems is to seek new inorganic membrane materials with control...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B31/04B01D53/22
Inventor 章伟许泳蔡依晨
Owner NANJING UNIV OF TECH
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