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Composite spinneret, conjugated fiber, and process for manufacturing conjugated fiber

A composite fiber and composite spinneret technology, which is applied in the direction of spinneret assembly, fiber treatment, fiber chemical characteristics, etc., can solve the problems of nanofiber degradation, distance reduction, sea polymer can not be discharged, etc., to achieve easy manufacturing Effect

Active Publication Date: 2015-07-22
TORAY IND INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the techniques disclosed in Patent Documents 1 to 4, when simply increasing the pore filling density, etc., the distance between the island components in the cross section of the sea-island composite fiber becomes small.
Therefore, in the process of eluting the sea polymer with a solvent for producing ultrafine fibers, the sea polymer dissolved by the solvent cannot be efficiently discharged from between the island polymers or between the ultrafine fibers, and the elution efficiency of the sea polymer may sometimes be reduced. reduce
Therefore, the time to completely dissolve the sea polymer increases, and in particular, when obtaining nanofibers, etc., there are problems such as deterioration of nanofibers, aggregation of nanofibers, and failure to obtain expected functions of nanofibers.

Method used

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  • Composite spinneret, conjugated fiber, and process for manufacturing conjugated fiber
  • Composite spinneret, conjugated fiber, and process for manufacturing conjugated fiber
  • Composite spinneret, conjugated fiber, and process for manufacturing conjugated fiber

Examples

Experimental program
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Effect test

Embodiment 1

[0225] A 5.0 PET (hereinafter referred to as "copolymerized PET1", melt viscosity: 140 Pa·s) containing 5-sodium sulfoisophthalate in mol% was melted at 290°C, and then measured and flowed into figure 2 The illustrated spin pack incorporating the composite spinneret 7 of this embodiment melts and discharges a sea-island composite polymer stream. Based on the input polymer mass per unit time, the sea-island polymer ratio is 50 / 50. After cooling and solidifying the discharged composite polymer flow, an oil agent was applied, and it was taken up at a spinning speed of 1500 m / min to obtain an undrawn fiber of 150 dtex-15 filaments (2.25 g / min per hole discharge).

[0226] The coiled undrawn fiber was stretched 3.0 times between rolls heated at 90°C and 130°C to form a 50dtex-15 filament conjugated fiber. Here, using the one used in Example 1 Image 6 The distribution pattern shown is the spinneret. In discharge plate 2, with Figure 28 For the illustrated hexagonal lattice a...

Embodiment 2

[0230] Make Figure 29 The island discharge holes 13 and the sea discharge holes 12 shown in the example form a quadrangular lattice, and the hole filling density is 2.0 (pcs / mm 2 ), in the same manner as in Example 1, using a composite spinneret equipped with a discharge plate that is assembled with a part of the sea island discharge hole group in the form of sandwiching four sea component area formation discharge hole groups, except that Outside, all implement according to embodiment 1. In Example 2, as in Example 1, a sea component region is formed in the composite cross section, thereby having good sea polymer dissolution properties (sea polymer dissolution properties: good), and extremely fine There was little fiber shedding (shedding evaluation: good). Table 1 shows the spinning conditions and the evaluation results of the conjugate fibers and ultrafine fibers.

Embodiment 3

[0232] Such as Figure 30 As shown, the island discharge holes 13 are arranged in a triangular grid, and the sea discharge holes 12 are arranged, and the hole filling density is set to 3.0 (pcs / mm 2 ), in the same manner as in Example 1, using a composite spinneret equipped with a discharge plate that is equipped with a group of discharge holes for forming a sea component area in a form that sandwiches a part of the group of discharge holes for sea islands at 4 places on both sides, except that Except that, all the composite fibers were obtained in the same manner as in Example 1.

[0233] In the cross section of the composite fiber of Example 3, there are Figure 14 The four sea composition regions illustrated in the figure. These sea component regions are directed toward the center from the top, right, bottom, and left of the surface of the fiber when the cross section is observed, but do not enter the center. Its shape is roughly rectangular. In addition, the cross-sect...

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Abstract

The present invention addresses the problem of providing: a conjugated fiber having a sea-island structure such that the sea polymer of the sea-island structure can be easily eluted even when the island component is present at a high density; and a spinneret suitable for manufacturing the conjugated fiber. This conjugated fiber has sea-island regions (42) and a sea component region (44), wherein the sea component region (44) lies among the sea-island regions (42), and has a width which is equal to or larger than a prescribed level. This composite spinneret has a discharge plate which has an extrusion hole assembly that is composed of both a group of sea extrusion holes for forming the sea component region and a group of sea-island extrusion holes.

Description

technical field [0001] The present invention relates to a composite spinneret for discharging a composite polymer stream composed of two or more polymers, composite fibers obtained by melt spinning with a composite spinning machine using the composite spinneret, and composite fibers Production method. Background technique [0002] Combining two or more types of polymers to complement the insufficient properties of single-component polymers or to impart new functions to conjugate fibers has been developed in large numbers due to the diversification of applications. [0003] The sea-island composite fiber, one of the composite fibers, is a fiber in which two or more polymers with different compositions are phase-separated when the cross-section is observed, one polymer is dispersed in another polymer, and the former polymer is dispersed. Think of things as islands and the aggregates of the latter as seas. Hereinafter, the former polymer is called "island polymer", and the la...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F8/00D01D5/36
CPCD01D5/36D01F8/00Y10T428/2931D01D4/025D01F8/14D01D5/082D10B2331/04
Inventor 增田正人宫下雅臣船越祥二
Owner TORAY IND INC