Water-based viscosity-increasing and shearing agent for drilling fluid and preparation method thereof
A water-based, drilling fluid technology, applied in the field of drilling fluid water-based viscosity-increasing and shearing agent and its preparation, can solve the problems of insufficient temperature resistance stability, insufficient dynamic-plastic ratio, and narrow application range, etc., to achieve excellent growth The effect of sticking and cutting performance and temperature resistance, excellent compatibility
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[0017] The invention provides a preparation method of a water-based viscosity-increasing and shearing agent for drilling fluid, the method comprising the following steps:
[0018] (1) Dissolve and mix the anionic monomer, nonionic monomer and cationic monomer in water under stirring;
[0019] (2) Adjust the pH value of the mixed solution obtained in step (1) to 5-10, and continue stirring;
[0020] (3) Add oxidizing agent, reducing agent and azo initiator to the mixture obtained in step (2), and react under stirring.
[0021] In step (1), the inventors of the present invention found that by blending anionic monomers, nonionic monomers and cationic monomers in a certain ratio, the viscosity-increasing performance, temperature resistance performance and system applicability can be obtained better product. The inventors of the present invention have found through a large number of tests that the amount ratio of the anionic monomer, the nonionic monomer and the cationic monomer ...
Embodiment 1
[0035] (1) Mix water, benzenesulfonic acid, acrylamide, and dimethylaminoethyl methacrylate at a mass ratio of 7000:600:500:200 at room temperature, and stir for 25 minutes at a stirring speed of 400 r / min;
[0036] (2) Adjust the pH value of the solution obtained in step (1) to 8, and continue stirring for 40 minutes at a stirring speed of 350 r / min under a water bath condition of 35° C.; then
[0037] (3) Add ammonium persulfate, sodium bisulfite and azobisisobutyronitrile successively in a mass ratio of 2:4:2, and stir and react with a stirring speed of 300r / min for 4 hours, wherein the weight of the azo initiator is 0.5% by weight of the solid raw material gross weight in the step (1);
[0038] (4) Dry the mixture obtained in step (3) at 90° C. for 12 hours, and then grind it into a powder with an average particle size of about 60 mesh, which is the final product.
Embodiment 2
[0040] (1) Mix water, acrylic acid, acrylamide, and dimethyl diallyl ammonium chloride at normal temperature in a mass ratio of 7000:550:550:250, and stir for 20 minutes at a stirring speed of 350 r / min;
[0041] (2) Adjust the pH value of the solution obtained in step (1) to 7, and continue stirring for 30 minutes at a stirring speed of 300 r / min under a water bath condition of 30 ° C; then
[0042] (3) Potassium persulfate, sodium bisulfite and azobisisoheptanonitrile were added successively in a mass ratio of 1:3:1, and stirred and reacted for 3 hours with a stirring speed of 250r / min, wherein the weight of the azo initiator was 0.2% by weight of the solid raw material gross weight in the step (1);
[0043] (4) Dry the mixture obtained in step (3) at 85° C. for 16 hours, and then grind it into a powder with an average particle size of about 80 mesh, which is the final product.
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