Method for producing silicon carbide and silicon carbide
A manufacturing method and technology of silicon carbide, applied in the direction of silicon carbide, chemical instruments and methods, carbide, etc., to achieve the effect of high purity, low cost and low energy
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Embodiment 1
[0084] implement figure 1 The method for producing silicon carbide of the present invention shown in . use figure 2 The CZ single crystal pulling apparatus 1 shown in , grows single crystal silicon.
[0085] In addition, a heater made of a graphite material and having an outer diameter of about 800 mm was used as the carbon material heater. In addition, on the inner side of the water-cooled main furnace chamber, a heat insulating material (insulation plate) made of carbon fiber is arranged to suppress heat loss, and the inner side of the heat insulating material is covered with a thin graphite material (inner partition plate) to Prevents deterioration of insulation materials. In addition, on the upper part of the graphite heater, an upper partition formed of the upper partition heat insulating material and the graphite material on the surface is arranged, and the upper partition is made to protrude forward from the heat insulating plate and the inner partition.
[0086] A...
Embodiment 2
[0097] The same manufacturing batch as in Example 1 was repeated. As a result, silicon carbide of the graphite heater proceeds, and the graphite portion forming the gap becomes thinner and agglomerates of silicon carbide are formed until the performance as a graphite heater cannot be satisfied.
[0098] And by peeling off the graphite heater, the silicon carbide accumulated on the graphite heater after the end of the heater life is recovered. The yellow-green silicon carbide crystals thus recovered were about 3.1 kg.
[0099] In addition, the obtained yellow-green silicon carbide was scraped off, and analyzed by X-ray diffraction and solid-state nuclear magnetic resonance (Nuclear Magnetic Resonance, NMR). As a result, the crystal system was 3C type (β type). also, image 3 Solid NMR peaks are shown. In addition, for comparison, solid state NMR was used to analyze commercially available silicon carbide powder produced by conventional methods, and the results are shown in ...
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