Water-based graphene conductive alkyd resin and preparation method thereof

A water-based graphene and alkyd resin technology, used in conductive coatings, coatings, polyester coatings, etc., can solve the problems of high coating density, difficult to improve mechanical strength and electrical conductivity of coatings at the same time, and expand the scope of application. effect with field

Inactive Publication Date: 2015-11-04
张东海
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The invention provides a water-based graphene conductive alkyd resin and a preparation method thereof, which solves the problems of traditional conductive coatings t

Method used

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] The invention provides a water-based graphene conductive alkyd resin, which uses ricinoleic acid, neopentyl glycol, trimethylolpropane, isophthalic acid, trimellitic anhydride, diethylene glycol butyl ether, butanol, graphene Toluene solution is raw material, and its raw material is counted as by weight percentage:

[0025] 20% ricinoleic acid, 5% neopentyl glycol, 10% trimethylolpropane, 15% isophthalic acid, 5% trimellitic anhydride, 15% diethylene glycol butyl ether, 10% butanol, graphene 5% toluene solution.

[0026] Utilize above-mentioned raw material to prepare the method for aqueous graphene conductive alkyd resin, comprise the steps:

[0027] (1) Add ricinoleic acid, neopentyl glycol, trimethylolpropane, isophthalic acid, and graphene xylene solution into the reaction kettle, and cover the lid;

[0028] (2) After raising the temperature of the reactor to 130°C within 1 hour, start stirring, and at the same time, introduce CO 2 and condensate;

[0029] (3) R...

Embodiment 2

[0037] The invention provides a water-based graphene conductive alkyd resin, which uses ricinoleic acid, neopentyl glycol, trimethylolpropane, isophthalic acid, trimellitic anhydride, diethylene glycol butyl ether, butanol, graphene Toluene solution is raw material, and its raw material is counted as by weight percentage:

[0038] Ricinoleic acid 25%, neopentyl glycol 8%, trimethylolpropane 14%, isophthalic acid 20%, trimellitic anhydride 7%, diethylene glycol butyl ether 16%, butanol 10%, graphene di Toluene solution 55%.

[0039] Utilize above-mentioned raw material to prepare the method for aqueous graphene conductive alkyd resin, comprise the steps:

[0040] (1) Add ricinoleic acid, neopentyl glycol, trimethylolpropane, isophthalic acid, and graphene xylene solution into the reaction kettle, and cover the lid;

[0041] (2) After raising the temperature of the reactor to 135°C within 1.2 hours, start stirring, and at the same time, introduce CO 2 and condensate;

[0042...

Embodiment 3

[0050] The invention provides a water-based graphene conductive alkyd resin, which uses ricinoleic acid, neopentyl glycol, trimethylolpropane, isophthalic acid, trimellitic anhydride, diethylene glycol butyl ether, butanol, graphene Toluene solution is raw material, and its raw material is counted as by weight percentage:

[0051] Ricinoleic acid 30%, neopentyl glycol 10%, trimethylolpropane 15%, isophthalic acid 20%, trimellitic anhydride 10%, diethylene glycol butyl ether 20%, butanol 15%, graphene xylene Solution 100%.

[0052] Utilize above-mentioned raw material to prepare the method for aqueous graphene conductive alkyd resin, comprise the steps:

[0053] (1) Add ricinoleic acid, neopentyl glycol, trimethylolpropane, isophthalic acid, and graphene xylene solution into the reaction kettle, and cover the lid;

[0054] (2) After raising the temperature of the reactor to 140°C within 1.5 hours, start stirring, and at the same time, introduce CO 2 and condensate;

[0055]...

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Abstract

The invention provides water-based graphene conductive alkyd resin. Ricinoleic acid, neopentyl glycol, trimethylolpropane, m-benzene, trimellitic anhydride, diethylene glycol monobutyl ether, butanol and graphene xylene liquor are used as the raw materials, the mechanical strength and the electric conductivity of a coating prepared through traditional conductive coating paint cannot be easily improved at the same time, the density of the coating is large, and all the problems greatly restrain the application range of the coating. A recently-developed material using graphene as conductive filler can hopefully solve the above problems existing in the conductive coating paint, and the application range and field of the conductive coating paint are greatly widened. However, graphene cannot be dispersed in a water-based system easily in general, and thus the graphene is evenly dispersed in water-based alkyd resin through resin synthesis. High-performance conductive coating paint can be prepared through the resin. The problems that the mechanical strength and the electric conductivity of the coating prepared through the traditional conductive coating paint cannot be easily improved at the same time, and the density of the coating is large.

Description

technical field [0001] The invention relates to an organic compound, in particular to a water-based graphene conductive alkyd resin and a preparation method thereof. Background technique [0002] Graphene is a new material because of its low density and high mechanical strength. In addition, its carrier mobility reaches 200000cm2V -1 the s -1 , more than 10 times the mobility of commercial silicon wafers, and has a higher conductivity than silver. At present, conductive coatings mainly use conductive fillers, and conductive fillers mainly include metal systems, metal / glass composites, and carbon systems. Water-based alkyd resin is a common water-based resin and an important raw material for the preparation of conductive coatings. Water-based graphene alkyd resin has not been reported in the literature. With traditional conductive coatings, it is difficult to increase the mechanical strength and electrical conductivity of the coating at the same time, and the density of ...

Claims

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Application Information

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IPC IPC(8): C08G63/49C08K3/04C09D167/08C09D5/24
Inventor 张东海郭晓峰
Owner 张东海
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