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Processing method of hydrolysis and alcoholysis resistant PPE (polyphenylene ether)/glass fiber masterbatch

A technology of glass fiber masterbatch and processing method, which is applied in the processing field of water-resistant alcoholysis PPE/glass fiber masterbatch, can solve the problem of anti-alcoholysis agent or alcoholysis-resistant agent decomposition, the ability to resist freezing liquid corrosion, and the joints. Do not allow problems such as stress cracking, achieve high mechanical properties, solve mechanical properties, and excellent alcoholysis resistance.

Inactive Publication Date: 2016-01-27
FOSHAN GAOMING DISTRICT MINGCHENG TOWN NEW ENERGYNEW MATERIAL IND TECH INNOVATION CENT
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The materials used for automotive water chamber components are required to be resistant to ethylene glycol solution, other chemical corrosive agents, and aqueous solutions above 100°C. At the same time, stress cracking is not allowed at the junction during the assembly process. Ordinary nylon materials have been difficult to meet the above requirements.
[0004] Most of the alcoholysis-resistant materials in the prior art achieve alcoholysis-resistant performance by adding an alcoholysis-resistant agent or an alcoholysis-resistant agent. Although it improves the alcoholysis-resistant properties of the material, the overall performance of the material decreases instead; At the same time, due to the high processing temperature, the anti-alcoholysis agent or anti-alcoholysis agent may decompose, resulting in a decrease in the overall corrosion resistance of the material, affecting production quality and efficiency

Method used

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  • Processing method of hydrolysis and alcoholysis resistant PPE (polyphenylene ether)/glass fiber masterbatch

Examples

Experimental program
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Effect test

Embodiment 1

[0017] An alcoholysis-resistant nylon composite material for automobiles, consisting of the following components by weight percentage: 658.1% nylon, 40% PPE / glass fiber masterbatch, 0.5% nucleating agent, 0.5% antioxidant, 0.6% lubricant, Heat stabilizer 0.3%.

[0018] The processing method of the alcoholysis-resistant nylon composite material for automobiles comprises the following steps:

[0019] (1) The processing method of PPE / glass fiber masterbatch, including the following steps:

[0020] a, first disperse graphene in water to form solution A, mix silane coupling agent with ethanol to form solution B, mix solution A and solution B at a mass ratio of 1:1 to prepare a mixed solution; wherein water in solution A and The mass ratio of graphene is 40:0.1, and the mass ratio of ethanol and silane coupling agent in solution B is 40:1; The silane coupling agent is 3-aminopropyltriethoxysilane;

[0021] b. Immerse the ordinary continuous glass fiber in the mixed solution, ultra...

Embodiment 2

[0029] An alcoholysis-resistant nylon composite material for automobiles, consisting of the following components by weight percentage: nylon 4658.5%, PPE / glass fiber masterbatch 40%, nucleating agent 0.1%, antioxidant 0.4%, lubricant 0.6%, Heat stabilizer 0.4%.

[0030] The processing method of the alcoholysis-resistant nylon composite material for automobiles comprises the following steps:

[0031] (1) The processing method of PPE / glass fiber masterbatch, including the following steps:

[0032] a, first disperse graphene in water to form solution A, mix silane coupling agent with ethanol to form solution B, mix solution A and solution B at a mass ratio of 1:1 to prepare a mixed solution; wherein water in solution A and The mass ratio of graphene is 45:1, and the mass ratio of ethanol and silane coupling agent in solution B is 35:0.8; The silane coupling agent is N-2-aminoethyl-3-aminopropyltrimethoxysilane;

[0033] b. Immerse the ordinary continuous glass fiber in the mixe...

Embodiment 3

[0041] Based on Example 2, the mass ratio of glass fiber to PPE resin is modified to 1:0.8, and the rest are the same.

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Abstract

The invention discloses a processing method of a hydrolysis and alcoholysis resistant PPE (polyphenylene ether) / glass fiber masterbatch. The processing method comprises the following steps: combining ultrasonic waves with mechanical vibration before and after and carrying out dip pretreatment on glass fibers by utilizing graphene, a silane coupling agent and a PPE melt, thus processing the hydrolysis and alcoholysis resistant PPE / glass fiber masterbatch. The processing method has the excellent effects that composite materials using the PPE / glass fiber masterbatch have excellent alcoholysis resistance which meets the TL-VW774 test requirements; specimen surfaces are good, are unchanged and do not crack; and not only is the problem that alcoholysis resistant agents need to be added to meet the requirement of alcoholysis resistance in the prior art solved but also the problem that the mechanical properties of base materials are obviously reduced after PPE is added in the prior art is solved.

Description

technical field [0001] The invention relates to the field of polymer materials, in particular to a processing method of hydroalcolysis-resistant PPE / glass fiber masterbatch. Background technique [0002] With the rapid development of the automobile industry, replacing steel with plastic has become the trend and direction of the development of automobile materials. Glass fiber reinforced nylon materials are widely used in water chamber parts of automobiles, such as thermostats, for their excellent heat resistance and mechanical properties. Shells, water tank joints, etc. These parts not only require the material to have excellent mechanical properties, but also require the material to have good hydrolysis resistance and alcoholysis resistance, and can be used for a long time in hot water and antifreeze ethylene glycol mixed solution without performance degradation. [0003] The materials used for automotive water chamber parts are required to be resistant to ethylene glycol ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L71/12C08K9/06C08K7/14C08K3/04C08L77/02C08L77/06
Inventor 严梅霞
Owner FOSHAN GAOMING DISTRICT MINGCHENG TOWN NEW ENERGYNEW MATERIAL IND TECH INNOVATION CENT