Method for adopting aluminum or aluminum alloy to directly braze aluminum nitride ceramics

A technology of aluminum nitride ceramics and aluminum alloys, applied in the field of ceramic processing, can solve the problems of low bonding strength between Al and Al alloys and AlN ceramics, lower joint quality and performance, and unsatisfactory brazing joint strength, etc., to achieve high brazing The effect of transmittance

Inactive Publication Date: 2016-03-23
SHANGHAI DIANJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, since the wetting angle of aluminum melt to AlN can only be less than 90° above 850°C, the brazing temperature above 850°C will reduce the quality and performance of the joint due to severe overburning of the Al melt
[0004] A search of the prior art found that: Chinese patent [Method for connecting ceramics and metals, CN200910092748.8] discloses a method of coating a layer of micron-scale thick Al or Al alloy film on the surface of ceramics by hot-dip plating to realize ceramics Between ceramics and metal brazing connection method, the patent inventor in the paper "Aluminum and aluminum nit

Method used

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  • Method for adopting aluminum or aluminum alloy to directly braze aluminum nitride ceramics
  • Method for adopting aluminum or aluminum alloy to directly braze aluminum nitride ceramics
  • Method for adopting aluminum or aluminum alloy to directly braze aluminum nitride ceramics

Examples

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Effect test

Embodiment 1

[0038] A pure Al coating was plated on the AlN ceramic surface with a thickness of 7 μm. The heating temperature of vacuum brazing was 670° C. and kept for 10 minutes. The joint shear strength obtained after brazing of this coating is 104 MPa. The shear strength of brazed joints is measured by the national standard GB11363-89 "Test Method for Strength of Brazed Joints", the same below.

Embodiment 2

[0040] The Al-Cu coating is plated on the AlN ceramic surface. The structure of the coating is to first plate an Al layer with a thickness of 7 μm, and then plate a Cu layer with a thickness of 200 nm on the surface, so that the double-layer coating can be melted to obtain Al-3.8at.%Cu alloy solder, the heating temperature of vacuum brazing is 670°C and the temperature is kept for 10 minutes. The joint shear strength obtained after brazing is 165MPa.

Embodiment 3

[0042] Al-Cu coating is plated on the AlN ceramic surface. The structure of the coating is to plate a 100nm thick Al bottom layer first, and then plate a Cu layer with a thickness of 500nm, so that the multilayer coating can be melted to obtain Al-9.4at .% Cu alloy brazing filler metal, on the surface of the Cu layer, an Al layer with a thickness of 7 μm is plated, and the heating temperature for vacuum brazing is 670° C. and kept for 10 minutes. The joint shear strength obtained after brazing is 95MPa.

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Abstract

The invention provides a method for adopting aluminum or aluminum alloy to directly braze aluminum nitride ceramics. The method include the following steps that a pure Al or Al alloy coating serving as brazing filler metal is plated on the surfaces to be brazed of the AlN ceramics by adopting a physical vapor deposition coating method, then the two ceramics are arranged in the mode that the coated surfaces are oppositely attached, and after a pressing force is exerted, vacuum heating brazing is performed to obtain brazing connectors for using the Al or Al alloy to directly braze the AlN ceramics. According to the method, the Al or Al alloy is adopted to directly braze the AlN ceramics, the shortcoming that an existing brazing method needs to metallize the ceramics and accordingly transition layers are produced between a brazing seam and the ceramics is avoided, and the brazing connectors having high strength and high toughness are obtained. The method can perform brazing at lower vacuum degree, the very high brazing penetration rate of large-area planar brazing connectors is obtained, and the method can serve as a connecting technology to be used for machining and manufacturing of the AlN ceramics.

Description

technical field [0001] The invention relates to a brazing method for ceramic materials, in particular to a method for directly brazing AlN ceramics by using aluminum or aluminum alloy as brazing material, which is used in the field of ceramic processing. Background technique [0002] AlN and the most commonly used Al 2 o 3 They are all engineering ceramics with excellent performance. They not only have high strength and high temperature stability, but also have many excellent properties such as high insulation, dielectric properties, and corrosion resistance. They are widely used in modern industry and high-tech fields. Broad prospects for more applications. For example, in the electronics industry, since AlN has a higher 2 o 3 Nearly 10 times the thermal conductivity of metal Al and the thermal expansion coefficient matching with semiconductor materials such as Si, SiC, GaAs, etc., become a substitute for Al 2 o 3 An important substrate material for high-power integra...

Claims

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Application Information

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IPC IPC(8): C04B37/00
CPCC04B37/001C04B2237/12C04B2237/121
Inventor 尚海龙赵博文陈凡齐进艳石恺成李戈扬李荣斌王颖
Owner SHANGHAI DIANJI UNIV
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