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A kind of environment-friendly antibacterial material and preparation method thereof for 3D printing

An antibacterial material, 3D printing technology, applied in the direction of additive processing, etc., can solve the problems of limiting the choice of 3D printing materials, inapplicability, etc., and achieve high market application prospects, low cost, and good liquidity.

Inactive Publication Date: 2017-11-07
河南豫创增材制造技术研究院有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The invention utilizes composite oxide nano C u f e2 o 4 As a silver carrier to prepare an antibacterial agent, it can have strong antibacterial, antibacterial, and long-lasting effects. The antibacterial rate against Escherichia coli and Staphylococcus aureus can reach more than 90%, and the antibacterial time is long, but this invention is not applicable to 3D Print
[0006] With the rapid development of 3D printing technology, 3D printing materials, as an important part of 3D printing technology, have received more and more attention. However, there are very few 3D printing materials with environmental protection and antibacterial functions, which greatly limits the selection of 3D printing materials. Therefore, it is of great significance to develop a 3D printing material with environmental protection and antibacterial function suitable for 3D printing to promote the development of 3D printing and enrich 3D printing materials.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] An environmentally friendly antibacterial material for 3D printing:

[0030] (1) The porous calcium carbonate that is 15 parts by weight, the graphite that is 5.0 parts by weight, the chlorothalonil that is 1.5 parts by weight and the silane coupling agent that are 0.3 parts by weight are mixed and stirred at normal temperature in a high-speed mixer, and stirred Rotating speed 300rpm, stirring time 30 minutes, obtain modified porous calcium carbonate and graphite;

[0031] (2) Add the modified porous calcium carbonate and graphite obtained in step (1) to 85 parts by weight, and melt the linear low density polyethylene at a heating temperature of 240°C. Stir during the addition process, the stirring speed is 400rpm, and the stirring time 60 minutes to obtain a homogeneously mixed linear low density polyethylene composite material;

[0032] (3) Send the homogeneously mixed linear low-density polyethylene composite material obtained in step (2) into a twin-screw extruder ...

Embodiment 2

[0034] An environmentally friendly antibacterial material for 3D printing:

[0035] (1) The porous calcium carbonate that is 10 parts by weight, the graphite that is 3.0 parts by weight, the chlorothalonil that is 1.0 parts by weight and the silane coupling agent that are 0.2 parts by weight are mixed and stirred at normal temperature in a high-speed mixer, and stirred Rotating speed 240rpm, stirring time 30 minutes, obtain modified porous calcium carbonate and graphite;

[0036] (2) Add the modified porous calcium carbonate and graphite obtained in step (1) into 80 parts by weight, melted polypropylene and polyvinyl chloride at a heating temperature of 240°C, stir during the addition, and stir at a stirring speed of 300rpm. Time 45 minutes, obtain the homogeneously mixed polypropylene, polyvinyl chloride composite material;

[0037] (3) Send the homogeneously mixed polypropylene and polyvinyl chloride composite material obtained in step (2) into a twin-screw extruder with a ...

Embodiment 3

[0039] An environmentally friendly antibacterial material for 3D printing:

[0040](1) The porous calcium carbonate that is 13 parts by weight, the graphite that is 3.8 parts by weight, the chlorothalonil that is 1.2 parts by weight and the silane coupling agent that are 0.24 parts by weight are mixed and stirred at normal temperature in a high-speed mixer, and stirred Rotating speed 300rpm, stirring time 30 minutes, obtain modified porous calcium carbonate and graphite;

[0041] (2) Add the modified porous calcium carbonate and graphite obtained in step (1) into high-density polyethylene and polystyrene melted at a heating temperature of 240°C with a weight part of 82, and stir during the addition at a stirring speed of 360rpm , and the stirring time was 50 minutes to obtain a homogeneously mixed high-density polyethylene and polystyrene composite material;

[0042] (3) Send the homogeneously mixed high-density polyethylene and polystyrene composite material obtained in step...

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Abstract

The invention discloses an environment-friendly and antibacterial material for 3D printing. The environment-friendly and antibacterial material mainly comprises materials in parts by weight as follows: 80-85 parts of thermoplastic resin, 10-15 parts of porous calcium carbonate, 3.0-5.0 parts of graphite, 1.0-1.5 parts of chlorothalonil and 0.2-0.3 parts of a silane coupling agent. The prepared environment-friendly and antibacterial material for 3D printing has excellent environment protection and antibacterial performance, excellent flowability and excellent mechanical performance due to the flowability and high-efficient adsorption performance of porous calcium carbonate and excellent environment protection and antibacterial performance of chlorothalonil and is suitable for a 3D printing technique. The invention further discloses a preparation method of the environment-friendly and antibacterial material for 3D printing. The production process is simple, the cost is low, and the material is safe, environment-friendly and has market application prospect.

Description

technical field [0001] The invention belongs to the field of new materials, and in particular relates to an environment-friendly antibacterial material for 3D printing. Background technique [0002] 3D printing technology is a new type of printing technology. Strictly speaking, 3D printing technology is a kind of rapid prototyping technology. It originated from the patent on 3D printing declared by Scans E.M. and Cima M.J. of the Massachusetts Institute of Technology in 1991. The difference between this technology and two-dimensional printing is that two-dimensional printing prints a flat two-dimensional pattern such as a document or a photo, while three-dimensional printing prints a three-dimensional object. The two have similarities. For example, two-dimensional printing is to spray ink and other materials on the printing material. Generally, the thickness is not high, a few microns. And if the substrate is printed not only once, but many times, the thickness of the "ink...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/08C08L23/12C08L27/06C08L23/06C08L25/06C08K9/06C08K7/24C08K3/04C08K5/315B33Y70/00B29B9/06B29C47/92B29C48/92
CPCB29B9/06B29C48/92B29C2948/9258B29C2948/92704C08K3/04C08K5/315C08K7/24C08K9/06C08K2201/003C08L23/06C08L23/0815C08L23/12C08L25/06C08L27/06C08L2207/062C08L2207/066
Inventor 雷利宾高扬陈元亮张平
Owner 河南豫创增材制造技术研究院有限公司