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High-strength polysulfide waterproof structure adhesive and preparing method thereof

A waterproof structure, high-strength technology, applied in the direction of adhesives, epoxy resin glue, polymer adhesive additives, etc., can solve the problems of heat resistance, durability and flame retardancy to be improved

Active Publication Date: 2016-04-20
上海创益中空玻璃材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Polysulfide structural adhesive is widely used and is a very good bonding material. It has the advantages of very reliable bonding effect and convenient use, but there are also problems that heat resistance, durability and flame retardancy need to be improved.

Method used

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  • High-strength polysulfide waterproof structure adhesive and preparing method thereof
  • High-strength polysulfide waterproof structure adhesive and preparing method thereof

Examples

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preparation example Construction

[0049] The filler used in this application is not particularly limited, and may be a commercially available commercial product or experimentally synthesized, for example, calcium sulfate, hydrophilic silica or polyimide-coated silica composite particles, but Preferably, the filler is a polyimide-coated silica composite particle, and the preparation method of the polyimide-coated silica composite particle comprises:

[0050] (1) Preparation of naphthalene anhydride-terminated polyimide prepolymer

[0051] Add 0.8-0.98 moles of diamine and an appropriate amount of m-cresol into a completely dry three-necked flask, and stir under the protection of an inert gas. When the diamine is completely dissolved, add 1 mole of dianhydride and 2.0-4.0 moles of catalyst. After stirring at room temperature for 30 minutes, heat to 75-85°C, react for 3.5-4.5 hours, and then at 175-185°C, react for 3.5-4.5 hours; after the reaction, cool down to room temperature, pour the solution into methanol, ...

Embodiment 1

[0148] Component A: A1100 parts by weight, B110 parts by weight, C110 parts by weight, D120 parts by weight, E15 parts by weight and F11 parts by weight; put the above materials into the grinder and mix them thoroughly for 30 minutes;

[0149] Component B: G1100 parts by weight, H12 parts by weight, I110 parts by weight, J130 parts by weight, K12 parts by weight and L12 parts by weight; put the above materials into the grinder and mix them for 30 minutes;

[0150] When using, mix components A and B in a ratio of A:B=10:1, apply within 2 hours, and fully cure within 5 hours at room temperature.

Embodiment 2

[0152] Component A: A1100 parts by weight, B130 parts by weight, C130 parts by weight, D130 parts by weight, E115 parts by weight and F15 parts by weight; put the above materials into the grinder and mix them thoroughly for 30 minutes;

[0153] Component B: G1100 parts by weight, H110 parts by weight, I140 parts by weight, J150 parts by weight, K110 parts by weight and L110 parts by weight; put the above materials into the grinder and mix them for 30 minutes;

[0154] When using, mix components A and B in a ratio of A:B=10:1, apply within 2 hours, and fully cure within 5 hours at room temperature.

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Abstract

The invention discloses a high-strength polysulfide waterproof structure adhesive. The high-strength polysulfide waterproof structure adhesive comprises a component adhesive A and a component adhesive B, wherein the component adhesive A comprises liquid polysulfide rubber, E-51-type bisphenol A epoxy resin, butyl benzyl phthalate, padding, sulfur and coupling agent; the component adhesive B comprises manganese dioxide, vulcanizing accelerator, carbon black, amino-terminated polypyrrolone prepolymers, silane-modified hyperbranched polybenzimidazole and 2,2'-bis(4-carboxyphenoxy)benzidine. The invention further discloses a preparing method of the high-strength polysulfide waterproof structure adhesive.

Description

technical field [0001] The invention belongs to the technical field of polymer sealing materials, and more specifically, the invention relates to a high-strength polysulfide waterproof structural adhesive and a preparation method thereof. Background technique [0002] During building construction and reinforcement, a variety of bonding materials need to be used. Due to different application environments, the performance requirements for building waterproof structural adhesives are getting higher and higher. Such as building structural adhesives cured under water or high humidity conditions, heat-resistant adhesives with high temperature resistance, fast-curing anchor adhesives, high-temperature durable adhesives, low-temperature construction adhesives that can be constructed at -10°C, high-temperature adhesives that can withstand 150°C, Special glue for extension components, high-temperature-resistant high-modulus glue made of inorganic materials, water-emulsion low-viscosit...

Claims

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Application Information

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IPC IPC(8): C09J181/04C09J163/02C09J11/06C09J11/04C09J11/08C08G73/10C08G73/20C08G73/18
CPCC08G73/1082C08G73/18C08G73/20C08L2201/02C08L2201/08C08L2205/03C08L2205/035C09J11/04C09J11/06C09J11/08C09J181/04C08L63/00C08L79/04C08K13/06C08K9/10C08K3/36C08K13/02C08K5/12
Inventor 罗金
Owner 上海创益中空玻璃材料有限公司
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