Polymer composition and liquid crystal alignment film for in-plane-switching-type liquid crystal display element
A composition and polymer technology, applied in polyurea/polyurethane coatings, coatings, instruments, etc., can solve problems such as inability to achieve liquid crystal alignment, dust generation, and inability to evenly rub liquid crystal alignment films
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[0300] [Preparation of polymer composition]
[0301] It is preferable to prepare the polymer composition used for this invention in the form of a coating liquid, and to suitably form a liquid crystal aligning film. That is, the polymer composition used in the present invention is preferably prepared in the form of a solution in which a resin component for forming a resin coating is dissolved in an organic solvent. Here, the resin component refers to a resin component containing the above-mentioned photosensitive side chain type polymer capable of expressing liquid crystallinity. In this case, the content of the resin component is preferably 1% by mass to 20% by mass, more preferably 3% by mass to 15% by mass, particularly preferably 3% by mass to 10% by mass.
[0302] In the polymer composition of this embodiment, the above-mentioned resin components may all be the above-mentioned photosensitive side-chain polymers capable of exhibiting liquid crystallinity, and may be ...
Embodiment
[0435] Abbreviations used in Examples are as follows.
[0436]
[0437]
[0438] MA1 was synthesized by the synthesis method described in the patent document (WO2011-084546).
[0439] MA2 was synthesized by the synthesis method described in the patent document (Japanese Patent Laid-Open No. 9-118717).
[0440]
[0441] ISO1: Toluene-2,4-diisocyanate
[0442] ISO2: Isophorone diisocyanate
[0443]
[0444] Me-4APhA: N-methyl-2-(4-aminophenyl)ethylamine
[0445] DA-1MG: bis(4-aminophenoxy)methane
[0446] DA-2MG: 1,2-bis(4-aminophenoxy)ethane
[0447] DA-3MG: 1,3-bis(4-aminophenoxy)propane
[0448] BAPU: 1,3-bis[2-(4-aminophenyl)ethyl]urea
[0449] p-PDA: p-phenylenediamine
[0450] DDM: 4,4'-Diaminodiphenylmethane
[0451] 3AMPDA: 3,5-diamino-N-(pyridin-3-ylmethyl)benzamide
[0452] DADPA: 4,4’-Diaminodiphenylamine
[0453] Me-DADPA: 4,4'-Diaminodiphenyl(N-methyl)amine
[0454]
[0455]
[0456] CBDA: 1,2,3,...
Synthetic example 1
[0469]
[0470] MA1 (2.99 g, 9.0 mmol) and MA2 (1.83 g, 6.0 mmol) were dissolved in THF (44.57 g), and after degassing with a diaphragm pump, AIBN (0.12 g, 0.5 mmol) was added and degassed again. Then, it was made to react at 50 degreeC for 30 hours, and the polymer solution of the methacrylate was obtained. This polymer solution was added dropwise to diethyl ether (500 ml), and the resulting precipitate was filtered. This deposit was wash|cleaned with diethyl ether, and it dried under reduced pressure in the oven of 40 degreeC, and obtained the methacrylate polymer powder.
[0471] NMP36.0g was added to the obtained powder 4.0g, and it stirred at room temperature for 3 hours. A methacrylate polymer solution (M1) having a solid content concentration of 10.0% by weight was obtained. The polymer was completely dissolved at the end of stirring.
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