an agznps 4 Nonlinear optical crystal and its preparation method and nonlinear optical device
A technology of nonlinear optics and devices, applied in the direction of nonlinear optics, chemical instruments and methods, optics, etc., can solve the problems that have not been reported and pointed out, and achieve the effect of wide light transmission band, large effect, not easy to break and deliquescence
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Embodiment 1
[0034] Example 1, AgZnPS was prepared by high temperature melt spontaneous crystallization method 4 Crystal:
[0035] Weigh 2.479 g of Ag 2 S, 3.898 g ZnS and 2.220 g P 2 S 5 (i.e. Ag 2 S:ZnS:P 2 S 5 =0.01mol:0.02mol:0.01mol), after mixing evenly, put it into a quartz glass tube of Φ12mm×200mm, and evacuate to 10 -3 After that, it is packaged with an oxyhydrogen flame and placed in a tube growth furnace, slowly raised to 700°C, kept at a constant temperature for 72 hours, slowly cooled to room temperature at a rate of 1°C / h, and the tube growth furnace is closed; after the quartz tube is cooled Cut it open to get yellow AgZnPS 4 crystals.
Embodiment 2
[0036] Embodiment 2, using the crucible drop method to prepare AgZnPS 4 Crystal:
[0037] Weigh 4.957 g of Ag 2 S, 7.796 g ZnS and 4.440 g P 2 S 5 (Ag:Zn:P:S=0.04mol:0.04mol:0.04mol:0.16mol), after uniform mixing, put into a quartz glass tube of Φ25mm×200mm, and vacuumize to 10 -3 After that, it is packaged with an oxyhydrogen flame and placed in a crystal growth furnace, and slowly raised to 700°C to melt the raw material. After the raw material is completely melted, the growth device descends vertically at a speed of 0.1-10mm / hour; after the crystal growth is completed, the growth It took 50 hours for the device to cool down to room temperature, and a yellow AgZnPS was obtained 4 crystals.
[0038] After testing, the AgZnPS prepared in the above examples 1-2 4 Nonlinear optical crystals belong to the orthorhombic crystal system, and the space group is Pna2 1 , whose unit cell parameters are: α=γ=90°, β=108.70°, Z=4, With frequency doubling effect, the light transm...
Embodiment 3
[0040] The AgZnPS of embodiment 1-2 gained 4 The crystal is not easy to break, not easy to deliquescence, easy to cut, polish and store. The AgZnPS of embodiment 1-2 gained 4 crystal, placed in the attached figure 1 At the position marked 3 of the device shown, at room temperature, a Q-switched Ho:Tm:Cr:YAG laser is used as the light source, the incident wavelength is 2090nm infrared light, and the output wavelength is frequency-doubled light of 1045nm. The laser intensity is the same AgGaS 2 1.8 times.
[0041] attached figure 1 is to adopt AgZnPS of the present invention 4 The working principle diagram of a typical nonlinear optical device made of nonlinear optical crystal, in which 1 is the laser, 2 is the incident laser beam, and 3 is AgZnPS after crystal post-processing and optical processing 4 Nonlinear optical crystal, 4 is the outgoing laser beam generated, 5 is a filter; the incident laser beam 2 is emitted by the laser 1 and injected into AgZnPS 4 The output l...
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