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40results about How to "High electro-optic coefficient" patented technology

Sodium bismuth titanate-barium titanate lead-free transparent electro-optic ceramic and preparation method thereof

The invention relates to a sodium bismuth titanate-barium titanate lead-free transparent electro-optic ceramic and a preparation method thereof; the electro-optic ceramic has the chemical composition of (1-x)(Na0.5Bi0.5)TiO3-xBaTiO3, wherein 0.05<=x<=0.08; the preparation method includes the steps: batching Na2CO3, Bi2O3, TiO2 and BaCO3 as raw materials according to the stoichiometric ratio, carrying out ball milling, and mixing evenly to obtain a powder; carrying out heat preservation on the powder for 2-4 h at the temperature of 850-950 DEG C, and thus obtaining a synthetic material; crushing the synthetic material, sieving, carrying out ball milling, adding a binder, and carrying out press molding to obtain a blank; next, placing the blank in a sintering furnace, heating up from room temperature to 800 DEG C-850 DEG C at the speed of 200 DEG C-250 DEG C/h, and carrying out heat preservation for 0.5-1.5 h; and heating up at the speed of 100 DEG C/h and gradually pressurizing to 200-250 MPa, followed by keeping the pressure unchanged, heating up to 1000 DEG C-1050 DEG C, then carrying out heat preservation for 2 h, then heating up to 1100 DEG C-1200 DEG C at the speed of 50 DEG C/h, carrying out heat and pressure preservation for 8-24 h, then releasing the pressure, cooling to 900 DEG C at the speed of 100 DEG C/h, and cooling to room temperature along with a furnace, wherein oxygen is introduced with the flow quantity of 3-5 L/minute when the heating is started and introduction of oxygen is stopped when the pressure is released.
Owner:中国科学院上海硅酸盐研究所苏州研究院

Photoelectric AC/DC voltage transducer based on Pockels effect

The invention belongs to the technical field of electric power detection and provides a photoelectric AC / DC voltage transducer based on the Pockels effect. The photoelectric AC / DC voltage transducer is not affected by environment temperature change, measurement precision is high, signal transmission is convenient, safety performance is high, power supply is not needed at a measurement point, and optical fiber signal transmission is immune to electromagnetic interference. The photoelectric AC / DC voltage transducer comprises a laser source, a transducer component, transmission fiber, a photoelectric detector and a backward-stage signal processing system, wherein the transducer component comprises a laser collimator I, a polarizer, a 1 / 4 wave plate, a crystal, an analyzer and a laser collimator II which are arranged along an optical path in sequence, the crystal is a cuboid, the length direction of the crystal is the light passing direction, the upper surface and the lower surface, perpendicular to the light passing direction, of the crystal are plated with metal layers serving as detection electrodes, the metal layers are used for loading voltage to be measured, the voltage direction is perpendicular to the light passing direction, and the backward-stage signal processing system obtains the voltage to be measured through a signal output by the photoelectric detector.
Owner:CHONGQING UNIV

Rubidium lithium titanium germanate compound, rubidium lithium titanium germanate non-linear optical crystal and preparation methods and application thereof

The invention discloses a rubidium lithium titanium germanate compound, a rubidium lithium titanium germanate non-linear optical crystal and preparation methods and application thereof. A chemical formula of the rubidium lithium titanium germanate compound is Rb4Li2TiGe4O13; a chemical formula of the rubidium lithium titanium germanate non-linear optical crystal is Rb4Li2TiGe4O13; the rubidium lithium titanium germanate non-linear optical crystal is non-centrosymmetrical structure, belongs to the tetragonal system and has a space group P4nc, is prepared by adopting a co-solvent method. The invention further discloses the rubidium lithium titanium germanate non-linear optical crystal to application of a laser non-linear optical compound functional device, an electro-optical crystal device or a laser device. The rubidium lithium titanium germanate non-linear optical crystal provided by the invention has a relatively great non-linear optical effect, a high electro-optical coefficient anda wide transmission range, has good mechanical properties and does not deliquesce; the frequency-doubled effect is 3 to 5 times of KDP (potassium dihydrogen phosphate).
Owner:TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI

Poling method for relaxor ferroelectric single crystal as nonlinear optical material

The invention discloses a poling method for a relaxor ferroelectric single crystal as a nonlinear optical material. The method comprises an annealing process and a polarization process; the relaxor ferroelectric single crystal comprises a binary (1-x)Pb(Mg1 / 3Nb2 / 3)O(3-x)PbTiO3 system and a ternary (1-x-y)Pb(In1 / 2Nb1 / 2)O(3-x)Pb(Mg1 / 3Nb2 / 3)O(3-y)PbTiO3 system; according to the annealing process, the relaxor ferroelectric single crystal after grinding and polishing is subjected to annealing treatment in atmosphere, stress caused by machining is removed, and spontaneous strain produced in a ferroelectric phase forming process is released to the great degree through quite slow cooling, so that the probability of cracking caused by electrically induced domain rotation in the crystal poling process is reduced. Besides, after an electric field is removed, a remaining depolarization field can be induced to form a nanometer domain structure. In order to guarantee formation and stability of a single-domain structure, the remaining depolarization field can be compensated by bulk shielding effect formed through electrode injection, the relaxor ferroelectric single crystal with high poling performance and stable performance is obtained, and the material has the characteristics of small half-wave voltage, large photo damage threshold, large electro-optic coefficient and the like and is far better than BBO, KTP, LN and other materials.
Owner:XI AN JIAOTONG UNIV

Internally modulated terahertz source based on waveguide structure and its internal modulation method

The invention discloses an internal modulation terahertz source based on a waveguide structure and an internal modulation method thereof. The internal modulation terahertz source comprises a pumping source, a laser beam combiner, a coupler and a waveguide structure, all of which are sequentially arranged, wherein the pumping source is composed of two independent fiber lasers; the waveguide structure is formed by tightly adhering an organic electro-optical material cladding, a lithium niobate core layer and a quartz substrate from top to bottom through optical cement, a control circuit is arranged in the organic electro-optical material cladding, and a wedge-shaped structure is arranged on the outer side of the organic electro-optical material cladding. The refractive index of the organic electro-optical material cladding is modulated through the control circuit, so that waveguide structure internal modulation terahertz output is obtained; therefore, the higher core layer internal energy conversion efficiency is achieved, and the generated terahertz energy can be efficiently coupled and outputted. According to the internal modulation terahertz source based on the waveguide structure and the internal modulation method thereof, integrated optical modulated terahertz radiation with high efficiency and a simple and compact structure can be achieved, and the invention is suitable for subsequent application and research on the fields of wireless communication, imaging, radar and the like.
Owner:TIANJIN UNIV

Titanium rubidium lithium germanate compound, titanium rubidium lithium germanate nonlinear optical crystal, preparation method and application thereof

The invention discloses a rubidium lithium titanium germanate compound, a rubidium lithium titanium germanate non-linear optical crystal and preparation methods and application thereof. A chemical formula of the rubidium lithium titanium germanate compound is Rb4Li2TiGe4O13; a chemical formula of the rubidium lithium titanium germanate non-linear optical crystal is Rb4Li2TiGe4O13; the rubidium lithium titanium germanate non-linear optical crystal is non-centrosymmetrical structure, belongs to the tetragonal system and has a space group P4nc, is prepared by adopting a co-solvent method. The invention further discloses the rubidium lithium titanium germanate non-linear optical crystal to application of a laser non-linear optical compound functional device, an electro-optical crystal device or a laser device. The rubidium lithium titanium germanate non-linear optical crystal provided by the invention has a relatively great non-linear optical effect, a high electro-optical coefficient anda wide transmission range, has good mechanical properties and does not deliquesce; the frequency-doubled effect is 3 to 5 times of KDP (potassium dihydrogen phosphate).
Owner:TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI

Double chromophore complex system and its synthesis method and application

The present invention relates to an organic / polymer electro-optic material, and particularly relates to a double chromophore complex system and synthesis and application thereof. The double chromophore complex system is a mixture of a side chain type subject chromophore-containing main polymer or a Y type subject chromophore-containing main polymer and an object chromophore, wherein the molar ratio of subject chromophore to object chromophore is 1:1. The growth rate of the electro-optic coefficient of the double chromophore complex system in the molar ratio is obviously superior to the growth rate of the electro-optic coefficient of the double chromophore complex system in other molar ratio. In the optimum molar ratio, the electro-optic coefficient of the double chromophore complex system can be increased to the greatest degree, by dissolving the double chromophore complex system in an organic solvent and coating, the biggest electro-optic coefficient of a prepared polarized electro-optic polymer film is 160pm / v. Therefore, the prepared polarized electro-optic polymer film can be used as an optical material, and can be applied to an electro-optic modulator, an optical sensor, an optical converter, and information transmission and other aspects.
Owner:TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI

Transparent electro-optical ceramic material with high electro-optical coefficient and high temperature stability and preparation method thereof

ActiveCN114804873AHigh electro-optic coefficientMeet temperature stability requirementsRare-earth elementOptical coefficient
The invention relates to a transparent electro-optic ceramic material with high electro-optic coefficient and high temperature stability and a preparation method thereof. The element composition of the ceramic material is (Pb1-xLnx) [(Mg1 / 3Nb2 / 3) yTi1-y] 1-x / 4O3, Ln is a rare earth element, x is more than or equal to 0.01 and less than or equal to 0.05, y is more than or equal to 0.90 and less than or equal to 0.70, and x is more than or equal to 0.01 and less than or equal to 0.05. And the rare earth doping content in the ceramic material is in gradient distribution along the thickness direction of the ceramic material. The method comprises the following steps: firstly, synthesizing PMN-PT ceramic powder with different rare earth doping contents, sequentially stacking, filling and forming the different PMN-PT ceramic powder according to the doping contents, and carrying out hot pressed sintering in an oxygen atmosphere after glue discharging. Rare earth doping elements in the ceramic form component gradient through diffusion in the sintering process. Compared with the prior art, the method provided by the invention can be used for preparing the electro-optical ceramic with high electro-optical coefficient and high temperature stability, and can meet the requirement of an optical modulator on the temperature stability of an electro-optical material.
Owner:SHANGHAI RES INST OF MATERIALS CO LTD

Sodium bismuth titanate-barium titanate lead-free transparent electro-optic ceramics and preparation method thereof

The invention relates to a sodium bismuth titanate-barium titanate lead-free transparent electro-optic ceramic and a preparation method thereof; the electro-optic ceramic has the chemical composition of (1-x)(Na0.5Bi0.5)TiO3-xBaTiO3, wherein 0.05<=x<=0.08; the preparation method includes the steps: batching Na2CO3, Bi2O3, TiO2 and BaCO3 as raw materials according to the stoichiometric ratio, carrying out ball milling, and mixing evenly to obtain a powder; carrying out heat preservation on the powder for 2-4 h at the temperature of 850-950 DEG C, and thus obtaining a synthetic material; crushing the synthetic material, sieving, carrying out ball milling, adding a binder, and carrying out press molding to obtain a blank; next, placing the blank in a sintering furnace, heating up from room temperature to 800 DEG C-850 DEG C at the speed of 200 DEG C-250 DEG C / h, and carrying out heat preservation for 0.5-1.5 h; and heating up at the speed of 100 DEG C / h and gradually pressurizing to 200-250 MPa, followed by keeping the pressure unchanged, heating up to 1000 DEG C-1050 DEG C, then carrying out heat preservation for 2 h, then heating up to 1100 DEG C-1200 DEG C at the speed of 50 DEG C / h, carrying out heat and pressure preservation for 8-24 h, then releasing the pressure, cooling to 900 DEG C at the speed of 100 DEG C / h, and cooling to room temperature along with a furnace, wherein oxygen is introduced with the flow quantity of 3-5 L / minute when the heating is started and introduction of oxygen is stopped when the pressure is released.
Owner:江苏先进无机材料研究院
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