The invention discloses a separating unit of skin, pulp and leaves of a maize straw. The separating unit of the skin, the pulp and the leaves of the maize straw comprises a rack (30) and a power mechanism (1) arranged on the rack, a leaf-removing mechanism, a clamping conveying roller assembly (4), a cutting roller assembly (5), an unfolding roller assembly (6), a flattening roller assembly (7), a pulp-peeling roller assembly (8) and a skin output roller assembly (9) are sequentially arranged on the rack from front to back and are all in transmission connection with the power mechanism (1). The separating unit of the skin, the pulp and the leaves of the maize straw carries out leaf-removing and pulp-peeling operation especially for maize straws, achieves the functions of completely separating the leaves, the pulp and the skin of the maizestraw, and enables the leaves, the pulp and the skin of the maize straw to be effectively utilized respectively. The separating unit of the skin, the pulp and the leaves of the maize straw has the advantages of being low in mechanical vibration, low in noise, small in energy consumption, durable in use, not prone to being wound and stacked, strong in practicality, good in market prospect, and worthy of popularization and application.