Fluorine-containing anti-fingerprint oil polymer and preparation thereof, and application of polymer in field of super-amphiphobic materials

A polymer, anti-fingerprint technology, applied in the coating and other directions, can solve the problems of weak super-amphiphobic surface adhesion, poor friction and washing resistance, etc., to achieve a simple post-processing process, reduce production costs, and improve durability. sexual effect

CN105693949AActive Publication Date: 2016-06-22国科广化(南雄)新材料研究院有限公司 +1
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Publication Date
2016-06-22

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Abstract

The invention belongs to the field of super-amphiphobic materials, and particularly relates to a fluorine-containing anti-fingerprint oil polymer and preparation thereof, and application of the polymer in the field of super-amphiphobic materials. The preparation method comprises the following steps: carrying out reaction on perfluoropolyether acyl fluorine and a reactant A to obtain a double-bond-containing perfluoropolyether monomer; carrying out copolymerization on the double-bond-containing perfluoropolyether monomer and a silane monomer to obtain the fluorine-containing anti-fingerprint oil polymer, wherein the structures of the perfluoropolyether acyl fluorine and silane monomer are respectively disclosed as Formula I and Formula II. The fluorine-containing anti-fingerprint oil polymer contains siloxy groups, and thus, the copolymer can be bonded with the matrix surface by utilizing the siloxy-hydroxy coupling characteristic, thereby constituting the super-amphiphobic surface. The super-amphiphobic surface prepared from the fluorine-containing polymer has the advantages of high bonding firmness with glass and friction resistance, and is suitable for industrial production and application.
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Description

technical field

[0001] The invention belongs to the field of super-amphiphobic materials, and in particular relates to a fluorine-containing anti-fingerprint oil polymer and its preparation and application in the field of super-amphiphobic materials. Background technique

[0002] With the development of the electronic industry, the application of touch screen is more and more extensive, from mobile phone, iPad, to ATM, industrial control equipment and display screen and TV. Due to the convenience and speed of the touch screen, we often leave fingerprints and oil stains on the surface of the touch screen during use. At the same time, it is not easy to clean, which will affect the normal use of the screen. Therefore, it has become the direction of many researchers to study and prepare a super amphiphobic anti-fingerprint oil that is waterproof, oil-proof and wear-resistant.

[0003] The C-F bond contained in the organic fluorine material has a large bond energy and a short bo...

Examples

Embodiment 1

[0068] (1) Preparation of perfluoropolyether allyl alcohol

[0069] Add 10g of perfluoropolyether acid fluoride (abbreviation: PFPE-COF, molecular weight 2041, structural formula as formula I, n=10) into a 50mL round bottom flask, then dissolve PFPE-COF with 15mL CFC, and then add 2.8457g Allyl alcohol and 0.9916g of triethylamine, the reaction system was stirred and dissolved, and then the polymerization reaction was carried out at room temperature 40°C under stirring conditions for 5h; after the stirring reaction was completed, the product was filtered, the solvent was removed by rotary evaporation, and the unreacted The substance, the product sinks in acetone, then washes with water, and finally uses anhydrous sodium sulfate to dry overnight to remove water to obtain the product perfluoropolyether allyl alcohol;

[0070] (2) Free radical copolymerization of perfluoropolyether allyl alcohol and 3-(acryloyloxy)propyltrimethoxysilane

[0071] Add 2g of perfluoropolyether ally...

Embodiment 2

[0073] (1) Preparation of perfluoropolyether allyl alcohol

[0074] Add 10g of perfluoropolyether acid fluoride (abbreviation: PFPE-COF, molecular weight 3347, structural formula as formula I, n=18) into a 50mL round bottom flask, then dissolve PFPE-COF with 15mL CFC, and then add 0.8676g Allyl alcohol and 0.3023g of triethylamine, the reaction system was stirred and dissolved, and then the polymerization reaction was carried out at room temperature 20°C under stirring conditions for 15 hours; after the stirring reaction was completed, the product was filtered, the solvent was removed by rotary evaporation, and the unreacted The substance, the product sinks in acetone, then washes with water, and finally uses anhydrous sodium sulfate to dry overnight to remove water to obtain the product perfluoropolyether allyl alcohol;

[0075] (2) Free radical copolymerization of perfluoropolyether allyl alcohol and 3-(acryloyloxy)propyltrimethoxysilane

[0076] Add 3g of perfluoropolyethe...

Embodiment 3

[0078] (1) Preparation of perfluoropolyether allyl alcohol

[0079] Add 10g of perfluoropolyether acid fluoride (abbreviation: PFPE-COF, molecular weight 4595, structural formula as formula I, n=25) into a 50mL round bottom flask, then dissolve PFPE-COF with 20mL CFC, and then add 0.126g 1.101g of allyl alcohol and 1.101g of triethylamine, the reaction system was stirred and dissolved, and then polymerized at 30°C for 14 hours; after the stirring reaction was completed, the product was filtered, the solvent was removed by rotary evaporation, and the unreacted The substance, the product sinks in acetone, then washes with water, and finally uses anhydrous sodium sulfate to dry overnight to remove water to obtain the product perfluoropolyether allyl alcohol;

[0080] (2) Free radical copolymerization of perfluoropolyether allyl alcohol and 3-(acryloyloxy)propyltrimethoxysilane

[0081] Add 4g of perfluoropolyether allyl alcohol prepared in step (1) into a 50mL round bottom flask...