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Treatment method of catalytic cracking oil slurry

A catalytic cracking oil slurry and treatment method technology, which is applied in the field of oil slurry raw material treatment, can solve the problems of aromatic oil with many mechanical impurities, difficult physical and chemical indicators, and low asphalt condensation degree, so as to reduce production cost and equipment investment , The effect of ease and controllability of operating conditions

Active Publication Date: 2018-01-05
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the aromatic hydrocarbon oil obtained by this technology has many mechanical impurities and needs further treatment. The economic value is not large. Difficult to pass

Method used

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  • Treatment method of catalytic cracking oil slurry
  • Treatment method of catalytic cracking oil slurry
  • Treatment method of catalytic cracking oil slurry

Examples

Experimental program
Comparison scheme
Effect test

Embodiment a

[0067] The present embodiment provides a kind of processing method of catalytic cracking oil slurry, and this method comprises:

[0068] 1) Add a peroxide crosslinking agent (dicumyl peroxide) to the catalytic cracking oil slurry (the oil slurry thrown out of the catalytic cracking unit), and the addition amount is 0.01% of the mass of the catalytic cracking oil slurry to form a mixed material;

[0069] 2) Use a tubular heating furnace to preheat the mixed material (50°C), and then heat it to 380°C;

[0070] 3) Pass the heated mixed material into the upper part of the reactor (empty cylinder reactor) to allow it to stay for staged cracking reaction. The staged cracking reaction was carried out at a reaction temperature of 460°C.

[0071] 4) The staged cracking reaction oil gas is discharged from the top of the reactor and then enters the fractionation tower to fractionate gas, gasoline, diesel oil and wax oil; the staged cracking reaction extracts the oil from the bottom of t...

Embodiment b

[0073] The present embodiment provides a kind of processing method of catalytic cracking oil slurry, and this method comprises:

[0074] 1) Add a peroxide crosslinking agent (dicumyl hydrogen peroxide) to the catalytic cracking oil slurry (the oil slurry thrown out of the catalytic cracking unit), and the addition amount is 0.09% of the mass of the catalytic cracking oil slurry to form a mixed material;

[0075] 2) Use a tubular heating furnace to preheat the mixed material (90°C), and then heat it to 420°C;

[0076] 3) Pass the heated mixed material into the upper part of the reactor (visbreaking reactor) to allow it to stay for staged cracking reaction. , and at a reaction temperature of 490° C., the staged cracking reaction is carried out.

[0077] 4) The staged cracking reaction oil gas is discharged from the top of the reactor and then enters the fractionation tower to fractionate gas, gasoline, diesel oil and wax oil; the staged cracking reaction extracts the oil from t...

Embodiment c

[0079] The present embodiment provides a kind of processing method of catalytic cracking oil slurry, and this method comprises:

[0080] 1) Add a peroxide crosslinking agent (benzoyl peroxide) in the catalytic cracking oil slurry (the oil slurry thrown out of the catalytic cracking unit), and the addition amount is 0.04% of the mass of the catalytic cracking oil slurry to form a mixed material;

[0081] 2) Use a tubular heating furnace to preheat the mixed material (65°C), and then heat it to 390°C;

[0082] 3) Pass the heated mixed material into the upper part of the reactor (circulatory bed reactor) to allow it to stay for staged cracking reaction. The staged cracking reaction was carried out at a reaction temperature of 470°C.

[0083] 4) The staged cracking reaction oil gas is discharged from the top of the reactor and then enters the fractionation tower to fractionate gas, gasoline, diesel oil and wax oil; the staged cracking reaction extracts the oil from the bottom of ...

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Abstract

The invention discloses a treatment method for catalytic cracking oil slurry. The method comprises the steps: adding a hyperoxide cross-linking agent into the catalytic cracking oil slurry so as to form a mixed material; preheating the mixed material, and heating the mixed material to the temperature of 380 DEG C to 420 DEG C; introducing the heated mixed material to the upper part of a reactor, and staying the mixed material for a staged cracking reaction; discharging oil gas of the staged cracking reaction from the top of the reactor; and extracting extract oil of the staged cracking reaction from the bottom of the reactor, carrying out filtering to remove coke, and blending decoked remaining oil with heavy-oil-residue oil so as to produce road asphalt. According to the method, the catalytic cracking oil slurry can be comprehensively treated by a relatively simple process in a low-cost manner, and the utilization benefit of the oil slurry is improved.

Description

technical field [0001] The invention relates to oil refining and petrochemical processing methods, in particular to a processing method for externally flung oil slurry raw materials of a catalytic cracking production device. Background technique [0002] The annual processing volume of catalytic cracking in my country exceeds 150 million tons, and the annual output of partial catalytic cracking slurry exceeds 7.5 million tons. Catalyst dust, colloids, asphaltenes, olefins and polycyclic aromatics in FCC slurry have brought many difficulties to the comprehensive utilization of FCC slurry. [0003] The oil slurry density of catalytic cracking oil slurry is high (965kg / m 3 ), high residual carbon value (6%), high aromatic content (45%), saturated content below 45%, and contains a certain amount of colloid, asphaltenes, and heavy metals such as S, Ni, and V; aromatic Among the hydrocarbons, the content of single- and double-ring aromatics is low, and the content of three- and ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L95/00C10G55/02
Inventor 赵广辉蔺爱国付兴国张艳梅卢竟蔓许倩刘银东侯经纬张璐瑶于志敏张东明
Owner PETROCHINA CO LTD