Method for simultaneously measuring multicomponent gas based on cavity ring-down spectroscopy

An optical cavity ring-down spectroscopy and multi-component technology, which is applied in the field of simultaneous measurement of multi-component gases based on optical cavity ring-down spectroscopy technology, can solve the problems of insufficient precision, simultaneous measurement of difficult gas multi-components, etc., and achieve convenient data processing , easy to build and adjust, high-precision measurement effect

Active Publication Date: 2016-08-31
INST OF OPTICS & ELECTRONICS - CHINESE ACAD OF SCI
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Problems solved by technology

[0005] The technical problem to be solved by the present invention is: in view of the lack of precision of traditional multi-component gas detection instruments and the difficulty of performing multi-component simultaneous measurement of gases with broad-spectrum absorption characteri

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  • Method for simultaneously measuring multicomponent gas based on cavity ring-down spectroscopy
  • Method for simultaneously measuring multicomponent gas based on cavity ring-down spectroscopy

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Embodiment Construction

[0022] Attached below figure 1 The simultaneous measurement method of multiple groups of gases based on optical cavity ring-down spectroscopy technology of the present invention is described.

[0023] In this embodiment, high beam quality (TEM 00 Mode) wide tuned quantum cascade laser as light source 1, the tuning range is 2600-2725cm -1 , the minimum tuning step is 0.01cm -1 ; The ring-down cavity is composed of two identical plano-concave high-reflection mirrors (reflectivity greater than 99.9%) with concave surfaces coated with high-reflection film. The ring-down cavity is a stable cavity or a confocal cavity. The cavity length L satisfies 0

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Abstract

The invention discloses a method for simultaneously measuring multicomponent gas based on cavity ring-down spectroscopy. A broadly tunable light source outputs a light beam, and the light beam enters a gas cell with two ends provided with plano-concave high-reflectance endoscopes. The gas cell is filled with a multicomponent gas mixture having absorption spectrum within laser tuning range. Output wavelengths of the laser undergo tuning, ring-down signals are detected under different wavelengths, ring-down time under different wavelengths is obtained through single exponential fitting, and a relation curve of absorption coefficient and wavelength is further obtained. A spectral line of the measured gas mixture and a standard absorption line of each single gas in the database undergo fitting treatment, and concentrations of different gases in the gas mixture can be simultaneously calculated. By the utilization of the broadly tunable laser light source, a gas absorption spectrum with richer contents can be obtained, and multiple gases can be measured at real time. Macromolecules with wide spectrum absorption undergo concentration detection, and the detection result is not influenced by light source fluctuation.

Description

technical field [0001] The invention relates to the technical field of gas concentration detection, in particular to a method for simultaneously measuring multi-component gases based on optical cavity ring-down spectroscopy. Background technique [0002] Multi-component gas detection technology is an important detection method necessary for industrial production process control, environmental monitoring, national security and other fields. Especially in the detection of atmospheric environment, there are many types of common pollutant gases, and there is an urgent need for multi-component, high-sensitivity, real-time detection methods. The traditional measurement method is to use multiple electrochemical sensors to measure different gases, but the test accuracy of this method is limited, and it is difficult to meet the low-concentration target gas detection. [0003] At present, methods for gas detection using the infrared spectral characteristics of gases have been develop...

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Application Information

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IPC IPC(8): G01N21/39
CPCG01N21/39G01N2021/391
Inventor 李斌成周胜韩艳玲
Owner INST OF OPTICS & ELECTRONICS - CHINESE ACAD OF SCI
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