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Thermoplastic elastomer for frosted-sense wire and preparation method of thermoplastic elastomer

A technology of thermoplastic elastomer and matte feeling, applied in the field of polymer materials, can solve the problems of poor matte effect, poor tear strength, poor dispersion, etc., to avoid component migration, good matte matte surface, and appearance Good results

Active Publication Date: 2016-11-16
中广核高新核材集团(东莞)祈富新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] With the rise of Apple mobile phones, the demand for frosted mobile phone charger cables is increasing, but Apple mobile phone charger cables are usually made of thermoplastic polyester elastomer TPEE material, which has the disadvantages of high hardness, high price, and tearing. Poor strength, easy to absorb dust, etc. Thermoplastic elastomer (TPE) has the characteristics of good processing performance, delicate hand feeling, wide hardness range, and good flame retardancy. It is widely used in the field of consumer electronics, such as data cables, earphone cables, etc. Elastomer (TPE) used as a mobile phone charger cable has a smooth appearance, and no thermoplastic elastomer with a frosted feel has been reported so far.
[0003] In addition, the matte feeling of existing materials is often caused by adding additives such as sanding agents and sanding powders. The dispersion of particles in the main resin is not good, uneven, and the sanding effect is not good.

Method used

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  • Thermoplastic elastomer for frosted-sense wire and preparation method of thermoplastic elastomer
  • Thermoplastic elastomer for frosted-sense wire and preparation method of thermoplastic elastomer
  • Thermoplastic elastomer for frosted-sense wire and preparation method of thermoplastic elastomer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Embodiment 1: The thermoplastic elastomer for frosted electric wire provided in this embodiment, by weight percentage, includes:

[0026]

[0027] Among them, the flame retardant is composed of melamine cyanurate and organic hypophosphite in a mass ratio of 1:1, and the organic hypophosphite can be organic zinc hypophosphite; the antioxidant is antioxidant 1076 and antioxidant Agent 168 is compounded at a mass ratio of 2:1.

[0028] This embodiment also provides a preparation method of the above-mentioned thermoplastic elastomer for frosted electric wires, comprising the following steps:

[0029] S1: Weigh each raw material component according to weight percentage;

[0030] S2: Styrenic block copolymer, dynamic vulcanized rubber TPV, poly(1,4-cyclohexanedimethylene terephthalate) PCT, polyolefin, plasticizer, polymethyl methacrylate, polyoxymethylene acid Add vinyl ester, flame retardant and additives into the mixer, stir at high speed for 30 minutes and then stop ...

Embodiment 2

[0032] Example 2: The thermoplastic elastomer for frosted sensing wire and its preparation method provided in this example are basically the same as in Example 1, except that: a thermoplastic elastomer for frosted sensing wire, by weight percentage, includes :

[0033]

[0034]

[0035] Among them, the flame retardant is a compound of melamine cyanurate and organic hypophosphite in a mass ratio of 1:3; the antioxidant is a compound of antioxidant 1076 and antioxidant 168 in a mass ratio of 2:1 .

[0036] During its preparation process: mixing and stirring for 10 minutes, extrusion temperature at 220° C., and screw rotation speed at 300 rpm.

[0037] Others are the same as in Embodiment 1, and will not be redundant here.

Embodiment 3

[0038] Example 3: The thermoplastic elastomer for frosted electric wires provided in this example and its preparation method are basically the same as in Example 1, except that: a thermoplastic elastomer for frosted electric wires, by weight percentage, includes :

[0039]

[0040] Among them, the flame retardant is a compound of melamine cyanurate and organic hypophosphite in a mass ratio of 2:1; the antioxidant is a compound of antioxidant 1076 and antioxidant 168 in a mass ratio of 3:1 .

[0041] During its preparation process: mixing and stirring for 20 minutes, extrusion temperature at 180° C., and screw rotation speed at 600 rpm.

[0042] Others are the same as in Embodiment 1, and will not be redundant here.

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Abstract

The invention relates to the technical field of high polymer materials, and particularly discloses thermoplastic elastomer for a frosted-sense wire. The thermoplastic elastomer is prepared from, by weight, 15%-35% of styrene block copolymer, 10%-35% parts of dynamic vulcanized rubber TPV, 10%-25% of poly(ethylene-co-1,4-cyclohexylenedimethylene terephthalate) PCT, 6%-18% of polyolefin, 6%-14% of plasticizer, 5%-10% of polymethyl methacrylate, 5%-10% of poly aldehyde-acid vinyl ester, 3%-8% of fire retardant and 1%-3% of auxiliaries. The invention further discloses a preparation method of the thermoplastic elastomer for the frosted-sense wire. Compared with the prior art, the thermoplastic elastomer has the advantages of being good in frosted effect, good in resilience, low in cost, good in appearance, good in hand feeling and the like, and the comprehensive properties of good hardness, good strength, durability, shock resistance, tensile resistance and the like are achieved.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a thermoplastic elastomer for frosted electric wires and a preparation method thereof. Background technique [0002] With the rise of Apple mobile phones, the demand for frosted mobile phone charger cables is increasing, but Apple mobile phone charger cables are usually made of thermoplastic polyester elastomer TPEE material, which has the disadvantages of high hardness, high price, and tearing. Poor strength, easy to absorb dust, etc., thermoplastic elastomer (TPE) has the characteristics of good processing performance, delicate hand feeling, wide hardness range, good flame retardancy, etc. It is widely used in the field of consumer electronics, such as data cables, earphone cables, etc. Elastomer (TPE) used as a mobile phone charger cable has a smooth appearance, and no thermoplastic elastomer with a frosted feel has been reported so far. [0003] In addition, the ma...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L23/16C08L53/02C08L67/02C08L23/08C08L91/06C08L33/12C08L31/04C08K5/3492C08K5/5313C08K5/134C08K5/526
CPCC08L23/0815C08L23/12C08L23/16C08L53/025C08L2201/22C08L2203/20C08L2205/02C08L2205/035C08L67/02C08L91/06C08L33/12C08L31/04C08K5/34924C08K5/5313C08K5/1345C08K5/526
Inventor 伍春平
Owner 中广核高新核材集团(东莞)祈富新材料有限公司
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