Curable resin composition, article, and method for fabricating the same
A technology for hardening resin and forming products, applied in the field of hardening and forming products, their manufacture, and hardenable epoxy resin compositions, which can solve the problems of easy embrittlement, low thermal cracking temperature, poor toughness, etc.
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Embodiment 1
[0021] 20 parts by weight of pyromellitic dianhydride (manufactured and sold by Alfa Aesar), 1 part by weight of tin(II)2-ethylhexanoate (manufactured and sold by Alfa Aesar) ) and 0.1 parts by weight of 2-ethyl-4-methylimidazole (2-ethyl-4-methylimidazole) (with a product number of EMI-24, manufactured and sold by T.C.I) into a reaction bottle, and Tetrahydrofuran (THF) was added as a solvent. Then, after sufficient stirring, 100 parts by weight of epoxy resin (diglycidylether of bisphenol A) (having a product number of DER 383, manufactured and sold by Dow Chemical Company) was added to the in the reaction vial. After sufficient stirring, resin composition (I) was obtained. The resin composition (I) is formed into a coating and the coating is subjected to a heat treatment, wherein the process temperature of the heat treatment is 100°C. The coating formed from the resin composition (I) was completely cured within 40 minutes to obtain a cured product. Next, the thermal dec...
Embodiment 2
[0023] 20 parts by weight of pyromellitic dianhydride (manufactured and sold by Alfa Aesar), 1 part by weight of tin(II)2-ethylhexanoate (manufactured and sold by Alfa Aesar) ) and 0.1 parts by weight of 2-ethyl-4-methylimidazole (2-ethyl-4-methylimidazole) (with a product number of EMI-24, manufactured and sold by T.C.I) into a reaction bottle, and Tetrahydrofuran (THF) was added as a solvent. Then, after sufficient stirring, 100 parts by weight of epoxy resin (diglycidylether of bisphenol A) (having a product number of DER 383, manufactured and sold by Dow Chemical Company) was added to the in the reaction vial. After sufficient stirring, resin composition (II) was obtained. The resin composition (II) is formed into a coating and the coating is subjected to a heat treatment, wherein the process temperature of the heat treatment is 50°C. The coating formed from the resin composition (II) was completely cured within 24 hours to obtain a cured product. Next, the thermal dec...
Embodiment 3
[0025] 20 parts by weight of pyromellitic dianhydride (pyromellitic dianhydride) (manufactured and sold by Alfa Aesar), 0.5 parts by weight of tin (II) 2-ethylhexanoate (manufactured and sold by Alfa Aesar) ), and 0.3 parts by weight of 2-ethyl-4-methylimidazole (2-ethyl-4-methylimidazole) (with a product number of EMI-24, manufactured and sold by T.C.I) into a reaction bottle, and add Tetrahydrofuran (THF) was used as a solvent. Then, after sufficient stirring, 100 parts by weight of epoxy resin (diglycidylether of bisphenol A) (having a product number of DER 383, manufactured and sold by Dow Chemical Company) was added to the in the reaction vial. After sufficient stirring, resin composition (III) was obtained. Forming the resin composition (III) into a coating and performing a heat treatment on the coating, wherein the process temperature of the heat treatment is 100°C. The coating formed from the resin composition (III) was completely cured within 40 minutes to obtain a...
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